• Title/Summary/Keyword: Poly vinyl alcohol fiber

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Characteristic rheological responses of PVA solutions in water-containing solvents

  • Song, Song-Ie;Kim, Byoung-Chul
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.181-182
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    • 2003
  • Poly(vinyl alcohol) (PVA) is a semicrystalline polymer whose hydroxyl groups produce inter-and intramolecular hydrogen bonding. The extent of hydrogen bonding is greatly affected by stereoregularity of hydroxyl groups, so-called tacticity, of PVA[1-3]. Hydrogen bonding has a profound effect on the rheological and mechanical properties of the polymer, which is largely determined by the density and spatial arrangement of hydroxyl groups. (omitted)

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PREPARATION OF POLY(ETHYLENE-CO-VINYL ALCOHOL) MEMBRANE VIA THERMALLY INDUCED PHASE SEPARATION

  • Matsuyama, Hideto;Shang, Mengxian;Teramoto, Masaaki
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.74-77
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    • 2004
  • Porous membranes were prepared via thermally induced phase separation (TIPS) of (ethylene-co-vinyl alcohol) (EVOH)/glycerol mixtures. The liquid-liquid (L-L) phase boundaries are shifted to higher temperature when the ethylene contents in EVOH increase. Moreover, the kinetic study proved that the growth of droplets formed by the general liquid-liquid (L-L) phase separation obeyed a power-law scaling relationship in the later stage of spinodal decomposition (SD). A new phase separation mechanism was presented, in which the L-L phase separation could be resulted from the crystallization. The hollow fiber membranes were prepared. The membranes showed asymmetric structures with skin layer near the outer surface, the larger pores just below the skin layer and the smaller pores near the inner surface. The effect of ethylene content (EC) in EVOH, cooling water bath temperature and take-up speed on membrane performance was investigated.

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Control of Shrinkage Cracking of Cement Composites with Different Length Mixture of PVA Fibers (서로 다른 길이의 PVA 섬유 혼합에 따른 시멘트 복합체의 균열제어 특성)

  • Won, Jong-Pil;Kim, Myung-Kyun;Park, Chan-Gi;Kim, Wan-Young;Park, Kyoung-Hoon;Jang, Chang-Il
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.405-408
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    • 2006
  • The purpose of this study was to determine the optimum length distribution of hybrid PVA(Poly vinyl alcohol) fiber. To produce blended PVA fiber length, first the length distribution of PVA fiber in the cement composites were identified in an experimental study based on simplex lattice design. Among the different length distributions investigated, fiber length was found to have statistically significant effect on plastic shrinkage cracking of cement composites. Subsequently, Complex analysis techniques were used to devise an experimental program that helped determine the optimum combinations of the selected fiber length distribution based on plastic shrinkage crack. The optimum blended PVA length ratio was 0.0146% 4mm fiber, 0.0060% 6-mm fiber, 0.0285% 8-mm fiber, and 0.0209% 12-mm fiber.

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Improvement of Mechanical and Electrical Properties of Poly(ethylene glycol) and Cyanoresin Based Polymer Electrolytes

  • Oh Kyung-Wha;Choi Ji-Hyoung;Kim Seong-Hun
    • Fibers and Polymers
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    • v.7 no.2
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    • pp.89-94
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    • 2006
  • Ionic conductivity and mechanical properties of a mixed polymer matrix consisting of poly(ethylene glycol) (PEG) and cyanoresin type M (CRM) with various lithium salts and plasticizer were examined. The CRM used was a copolymer of cyanoethyl pullulan and cyanoethyl poly(vinyl alcohol) with a molar ratio of 1:1, mixed plasticizer was ethylene carbonate (EC) and propylene carbonate (PC) at a volume ratio of 1:1. The conductive behavior of polymer electrolytes in the temperature range of $298{\sim}338\;K$ was investigated. The $PEG/LiClO_4$ complexes exhibited the highest ionic conductivity of ${\sim}10^{-5}S/cm$ at $25^{\circ}C$ with the salt concentration of 1.5 M. In addition, the plasticized $PEG/LiClO_4$ complexes exhibited improvement of ionic conductivity. However, their complexes showed decreased mechanical properties. The improvement of ionic conductivity and mechanical properties could be obtained from the polymer electrolytes by using CRM. The highest ionic conductivity of PEG/CRM/$LiClO_4$/(EC-PC) was $5.33{\time}10^{-4}S/cm$ at $25^{\circ}C$.

Study for Field Application of Nylon Fiber Reinforced Concrete for Plastic Shringage Crack Reduction (소성수축균열 저감을 위한 나일론 섬유보강 콘크리트의 현장적용에 관한 연구)

  • Kwon, Yong-Joo;Kim, Kwang-Ryeon;Kang, Dong-Soo;Park, Sung-Woo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.661-664
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    • 2006
  • Recently, various concrete reinforcing fibers have been used to reduce the plastic shrinkage cracking which occurs before the concrete hardens. In this study, the physical properties of nylon fiber reinforced concrete such as slump, air content, compressive strength and tensile strength were investigated. In addition, the performance of nylon fiber in the plastic shrinkage cracking reduction of concrete has been estimated in comparison with polypropylene, poly vinyl alcohol fiber and cellulose fiber. Nylon fiber showed considerable advantages in terms of the workability of concrete and the plastic shrinkage cracking reduction of concrete compared with polypropylene fiber and cellulose fiber.

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Enhanced Durability Performance of Rock-Filled-Dam Face-Slab Concrete using Fly Ash and Blended PVA Fiber (플라이애시와 PVA 섬유를 혼입한 댐 표면 차수벽 콘크리트의 내구성능 평가)

  • Woo, Sang-Kyun;Won, Jong-Pil;Bae, Doo-San;Chu, In-Yeop
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.3
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    • pp.140-148
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    • 2016
  • This study examined the durability of face-slab concrete in Concrete-Faced Rock-filled Dams(CFRDs). The durability of face-slab concrete can be improved by optimizing the amount of fly ash in the cement mixture. Durability tests including plastic shrinkage, permeability, abrasion resistance, and repeated freezing and thawing were done on face-slab concrete specimens with different amounts of fly ash and blended PVA(Poly Vinyl Alcohol) fibre. When the effect of the fly ash content on concrete durability was evaluated, the results showed that a 15% fly ash content and 0.1% blended PVA fiber yielded the optimum durability level for concrete-faced rock-filled dams.

A Study on the Preparation and Properties of Cellulose-EVOH Fibers (Cellulose-EVOH 섬유의 제조와 물성에 관한 연구)

  • 문병화;임상규;손태원;김삼수
    • Textile Coloration and Finishing
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    • v.10 no.5
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    • pp.19-23
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    • 1998
  • In this study, Cellulose-Poly(Ethylene-Co-Vinyl Alcohol) (EVOH) fibers from MMNO(N-me-thylmorpholine-N-oxide) /water/cellulose/EVOH were prepared according to changes of EVOH content(wt%), which is main factors to dry-jet wet spinning. The mechanical properties and morphology of produced fibers were investigated. The resultant fibers had tensile strength of 3.7∼4.5g/d, elongation of 3.3∼7.5% and exhibited lower density than the density of pure cellulose fiber.

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