• Proceedings of the KIEE Conference
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• 1994.07b
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• pp.1229-1232
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• 1994

The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li secondary battery. This paper describes the effects of lithium salts, plasticizer addition and temperature dependence of conductivity of PEO electrolytes. Polyethylene oxide(PEO) based polymer electrolyte films were prepared by solution casting an acetonitrile solution of preweighed PEO and Li salt. After solvent evaporation, the electrolyte films were vacuum-dried at $60^{\circ}C$ for 48h, the thickness of the films were $90{\sim}110{\mu}m$. The conductivity properties of prepared PEO electrolytes are summarized as follows. PEO electrolyte complexed with $LiClO_4$ shows the better conductivity of the others. $PEO-LiClO_4$ electrolyte when $EO/Li^+$ ratio is 8, showed the best conductivity. Optimum operating temperature of PEO electrolyte is $60^{\circ}C$. By adding propylene carbonate and ethylene carbonate to $PEO-LiClO_4$ electrolyte, its conductivity was higher than $PEO-LiClO_4$ without those. Also $PEO_8LiClO_4$ electrolyte remains static up to 4.5V vs. $Li/Li^+$.

• Journal of the Korean Applied Science and Technology
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• v.23 no.2
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• pp.147-152
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• 2006

The accidents occurred by unstable material which is easily exploded or burnt up were caused by heat and collision under the condition of relatively low temperature without oxygen, have been reported frequently. However, the amount of the unstable material is getting higher by development of fine ceramic research area even though its dangerous characteristic is disregarded. This research studied a heat stability and measured boiling point of various carpet material. Carpet has been used in home as well as general indoor usage. Now a day, carpet material which is hardly burnt has been on commercial, but its detailed unstable conditions is not mentioned. This research reports the measurement of the initial temperature of generation heat and heat-radiation change on differential scanning calorimeter (DSC). The DSC data of nylon bulked continuous filament (N-BCF) yam 100%, nylon (NY), poly propylene (PP), and a new material named polytrimethylene terephthalate (PTT) are studied and researched about the effect of them using TGA, furnace, and direct-burning experiment.

• Macromolecular Research
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• v.10 no.2
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• pp.80-84
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• 2002

Silver species other than the silver ion were formed by UV irradiation on polymer electrolyte membranes containing silver salts and their effect on complexation behavior between the silver and olefin was investigated through the separation performance of olefin/paraffin mixtures. The ideal propylene/propane separation factor reached 350 and the separation coefficient was ca.15 due to the high loading amount of silver ions into poly(2-ethyl-2-oxazoline) (POZ) without UV irradiation. On UV irradiation either in air or under nitrogen, the silver-POZ membranes became yellow-brown initially due to the formation of colloidal silver particles, and finally black and metal-like luster. Even when Ag$^{+}$ was converted, to some extent, to Ag$^{\circ}$ by UV irradiation in air at the early stage, the separation coefficient of olefin/paraffin mixtures was maintained. This suggests that silver species other than the silver ion is active for olefin carrier for facilitated transport. Meanwhile the steady decrease of the separation coefficient was observed in the silver/POZ membranes irradiated under $N_2$. It is suggested that the reduction of silver ions in POZ goes through a different photoreduction mechanism with UV irradiation depending on the environment.t.

• Carbon letters
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• v.20
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• pp.39-46
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• 2016

In this work, the effects of maleic anhydride (MA) content on mechanical properties of chopped carbon fibers (CFs)-reinforced MA-grafted-polypropylene (MAPP) matrix composites. A direct oxyfluorination on CF surfaces was applied to increase the interfacial strength between the CFs and MAPP matrix. The mechanical properties of the CFs/MAPP composites are likely to be different in terms of MA content. Surface characteristics were observed by scanning electron microscope, Fourier transform infrared spectroscopy, and single fiber contact angle method. The mechanical properties of the composites were also measured by a critical stress intensity factor (K_IC). From the K_IC test results, the K_IC values were increased to a maximum value of 3.4 MPa with the 0.1 % of MA in the PP, and then decreased with higher MA content.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.20 no.5
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• pp.564-569
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• 2011

The current establishment of city gas piping polyethylene (PE) tube used as bonding state or part of the health or safety of fusion is very important. A part of these fusion methods to determine the soundness of the short-term trials and long-term tests can be largely classified. Typical tests include short-term strength, tensile strength, impact strength, compressive strength, resiliency and compression. Polyethylene (PE) pipes installed in the domestic terms of overall penetration rate of 45% has been used. However, polyethylene (PE) pipes have reliability problems, and these occurs mostly in part by defective welding. Therefore, the test is necessary for safety. Non-destructive methods (ultrasonic testing) are difficult to be used. Therefore, Polypropylene copolymer (PP-C), polypropylene homopolymer (PP-H), and polyethylene (PE) pipe are used. Fusion of these materials is necessary in these field however, its technical, and basic research has not been studied well. In this research, short-term strength of welding parts, its tensile strength, hardness, fatigue, and microstructure have been analyzed to find the optimum process conditions to improve mechanical properties.

• Journal of the Korean Applied Science and Technology
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• v.31 no.4
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• pp.711-718
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• 2014

In this paper, the mechanical property change was investigated by adding 1,4-butanediol as chain extender of polyurethane dispersion for leather coating. Reagents for the synthesis were polypropylene glycol(PPG), isoporon diisocyanate(IPDI), dimethylolpropionic acid(DMPA) and 1,4-BD. All samples showed good solvent resistance and flexibility by different content of the 1,4-BD. As results, samples which contains a lot of 1,4-BD showed good properties whth strength of $1.80kg_f/mm^2$ and abrasion test measurement of 49.54 mg.loss. According to elongation test, the sample which contains low amount of 1,4-BD was good property as 364 %.

• Environmental Engineering Research
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• v.25 no.4
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• pp.554-560
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• 2020

This study focuses on nitrification through a biological aerated filter (BAF) that is filled with a zeolite medium at low concentrations of ammonia. The zeolite medium consists of natural zeolite powder. The BAF is operated under two types of media, which are a ball-type zeolite medium and expanded poly propylene (EPP) medium. Nitrification occurred in the zeolite BAF (ZBAF) when the influent concentration of ammonia nitrogen was 3 mg L-1, but the BAF that was filled with an EPP medium did not experience nitrification. The ammonia nitrogen removal efficiency of ZBAF was 63.38% and the average nitrate nitrogen concentration was 1.746 mg/L. The ZBAF was tested again after a comparison experiment to treat pond water, and municipal wastewater mixed pond water. The ZBAF showed remarkable ammonia-nitrogen treatment at low concentration and low temperature. During this period, the average ammonia nitrogen removal efficiency was 64.56%. Especially, when water temperature decreased to 4.7℃, ammonia nitrogen removal efficiency remained 79%. On the other hand, the chemical-oxygen demand (COD) and phosphorus-removal trends were different. The COD and phosphorus did not show as efficient treatment as the ammonia-nitrogen treatment.

• International Journal of Aeronautical and Space Sciences
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• v.9 no.1
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• pp.137-146
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• 2008

Proper amount of entrained air and nip force should be also considered to minimize ballooning phenomenon since tight contact between a roller and web is required. In this paper, various web materials, PET(Polyester) and OPP(Oriented Poly Propylene) have been selected and investigated to satisfy high-speed printing requirement. Several web speeds, web tensions, and temperature conditions are imposed on each web materials and the pressure and gap profiles as well as nip force have been calculated. Increase of both the winding roller radius and the incoming wrap angle is considered under proper taper tension at 500 m/min of rewinding roller. By solving coupled Reynolds equation and web deflection equation simultaneously, the fluid-structure interaction process has been developed and is applied to the rewinding roller to investigate the ballooning phenomenon which causes guiding problems in high-speed printing performance conditions. By adjusting the linear taper tension, stress distribution between rewinding webs can be remarkably reduced and stable pressure and gap profile with ignorable ballooning phenomenon have been found.

• Membrane Journal
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• v.13 no.2
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• pp.125-129
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• 2003

A remarkable separation performance of olefin/paraffin mixtures has been observed through facilitated olefin transport membranes consisting of silver ions dissolved in polymer matrices. In this research, valine, an amino acid, was introduced in poly (2-ethyl-2-oxazoline) (POZ)/$AgBF_4$ membranes to increase the separation performance. FT-IR spectra show that the cationic sites ($-NH_3^+$) of valine interact with the counter anion of the silver salt, resulting in the enhanced activity of the silver ions and consequently improved separation perfornance. Therefore, the $POZ/AgBF_4$ membranes containing valines exhibit the higher permeance as well as the higher selectivity of propylene/propane than those without valine.

• Journal of Korea Society of Digital Industry and Information Management
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• v.14 no.4
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• pp.9-16
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• 2018

This study described partial discharge(PD) distribution analysis between the XLPE(Cross-Linked PolyEthylene)and EPDM(Ethylene Propylene Diene Monomer) interface with unsupervised classification. The ${\phi}-q-n$ patterns were analyzed using phase resolved partial discharge(PRPD). K-means cluster analysis forms a cluster based on similarities and distances among scattered individuals, and analyzes the characteristics of the formed clusters, dividing the multivariate data into several groups according to the similarity of each characteristic, Is a statistical analysis that makes it easier to navigate. It was confirmed that the phase angle of the cluster with the maximum discharge charge was concentrated around $0^{\circ}$ and $180^{\circ}$ at 30 kV after the initial phase distribution localized around $90^{\circ}$ and $300^{\circ}$ expanded to the whole phase angle according to the voltage rise. The Euclidean distance between the center of gravity and the discharge charge in the ${\Phi}-q$ cluster increased with increasing applied voltage.