• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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• pp.137-144
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• 2006

Oil-fired power plants usually use several burners and the combustion air is supplied to each burner through the complicated duct which is called windbox. A windbox should be designed to supply combustion air to each burner evenly but, due to the complicated duct shape, flow distribution in the windbox is unbalanced and uneven supplies of combustion air to each burner are induced by these unbalanced flow distribution in the windbox. These flow patterns tend to make flame unstable, increase the formation of pollutants and lower the overall combustion efficiency. To prevent these disadvantages, flow patterns in the windbox should be investigated for the uniform flow distribution. In this study, computational simulation method was used to investigate the flow distribution in the windbox and measured the velocities at the exit of burners in the real windbox to compare with CFD results. The results show two significant flow patterns. One is that the flow rates of each burner are different from each other and this means that all burners operate in different conditions of air to fuel ratio. The other is that the flow distribution at the exit of each burner is not axi-symmetric although the burner shape is axi-symmetric and this increases the pollutant products like CO.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2001년도 추계학술발표대회
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• pp.77-80
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• 2001

Groundwater, contaminated predominantly with aromatic compounds and chlorinated ethylene, could be biologically treated in a fluidized-bed reactor with immobilized cells. The decomposition efficiency for the aromatics was over 90% at the retention time of 2.5 h. The chlorinated ethylenes, especially trichloroethylene (TCE) and cis-dichloroethylene (DCE), could be decomposed only insufficiently. No anaerobic methane formation was observed for this groundwater even at a very low dissolved oxygen (DO) concentration of 0.75 mg/L. The variation of DO concentration resulted in an optimal value of 1.5 mg/L. The recycle of air waste could increase the utilization of oxygen. The amount of low boiling pollutants stripped out remained constant with the recycle, while for the higher boiling pollutants the stripping slightly increased. Using air instead of oxygen increases the flow rate of air waste, which is connected to a higher stripping of pollutants. In this investigation, the pollutant concentration in the air waste remained constant. The stripping of main pollutants did not exceed 0.3 %.

• 한국환경과학회지
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• 제10권6호
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• pp.393-399
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• 2001

This study was carried out to evaluate the pollutant removal efficiencies of the advanced drinking water treatment using ozonation. for raw water, Nakdong River was used. By conducting batch ozonation test, the following results were obtained. when ozone dosage of 5mg/$\ell$was used, preozonation of raw water reduced turbidity, KMnO$_4$consumption, DOC(dissolved organic carbon), UV254 absorbance, THMFP(trihalomethane formation potential) as much as 3.9NTU, 5.5mg/$\ell$, 1.15mg/$\ell$, 0.112 and 0.065mg/$\ell$, respectively. In case of postozonation of sand filtered water, water quality was also improved with decrease in turbidity, KMnO$_4$consumption, DOC, UV254 absorbance and THMFP at the amount of 0.08NTU, 2.6mg/$\ell$, 0.88mg/$\ell$, 0.042 and 0.018mg/$\ell$, respectively. On the other hand, contents of dissolved oxygen increased at the level of 1.3mg/$\ell$ after preozonation process and 1.0mg/$\ell$ after postozonation process. The effect of ozone dosage was higher than that of its contact time for the removal of the pollutants.

• 한국환경과학회지
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• 제18권5호
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• pp.517-525
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• 2009

We measured ambient concentrations of hazardous air pollutants such as volatile organic compounds (VOCs) and aldehydes in residential areas nearby small and medium scale shipbuilding companies. The VOC concentrations were higher during the normal operation periods than vacation at which almost all operations were shutdown. Concentrations of VOCs was higher, as the sampling site was nearer from shipbuilding companies. The major components of VOCs were m,p-xylene, ethylbenzene, o-xylene, toluene, and 1,3,5-trimethylbenzene which had been found as major VOC compounds emitted from painting processes of shipbuilding in the previous studies. The major components of aldehydes analyzed were benzaldehyde, acrolein, formaldehyde, and acetaldehyde. The concentration of aldehydes was highest at the furthest sampling point from shipbuilding companies because the formation of aldehyde compounds could be occurred by the secondary chemical reactions of VOCs. The results of this study shows a proper counterplan need to be established for the reduction of hazardous air pollutants emitted from small and medium scale shipping companies.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2005년도 제31회 KOSCO SYMPOSIUM 논문집
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• pp.85-92
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• 2005

Oil-fired power plants usually use several burners and the combustion air is supplied to each burner through the complicated duct which is called windbox. A windbox should be designed to supply combustion air to each burner evenly but, due to the complicated duct shape, flow distribution in the windbox is unbalanced and uneven supplies of combustion air to each burner are induced by these unbalanced flow distribution in the windbox. These flow patterns tend to make flame unstable, increase the formation of pollutants and lower the overall combustion efficiency. To prevent these disadvantages, flow patterns in the windbox should be investigated for the uniform flow distribution. In this study, computational simulation method was used to investigate the flow distribution in the windbox and measured the velocities at the exit of burners in the real windbox to compare with CFD results. The results show two significant flow patterns. One is that the flow rates of each burner are different from each other and this means that all burners operate in different conditions of air to fuel ratio. The other is that the flow distribution at the exit of each burner is not axi-symmetric although the burner shape is axi-symmetric and this increases the pollutant products like CO.

• Environmental Engineering Research
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• 제25권2호
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• pp.186-196
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• 2020

Pillared clays with Zr and Fe/Cu/Zr polycations have been prepared from natural clays found in large deposits of Kazakhstan and assessed as catalysts for the catalytic wet peroxide oxidation (CWPO), using 4-nitrophenol (4-NP) as model compound. The performance of the catalysts was followed by measuring the concentration of 4-NP, H₂O₂ and the total organic carbon (TOC), considering C_4-NP = 5 g L^-1, $C_{H_2O_2}$ = 17.8 g L^-1, C_cat = 2.5 g L^-1, initial pH = 3.0 and T = 50℃. At those selected conditions, the pillared clays showed higher activity than natural clays in the CWPO of 4-NP. The conversion of the model pollutant was complete when Fe/Cu/Zr-PILCs were used, with the TOC removal reaching 78.4% after 24 h with the best Fe/Cu/Zr-PILC. The H₂O₂, 4-NP and TOC time-evolution was well described by a kinetic model based on TOC lumps in three blocks, considering the initial TOC (corresponding to 4-NP), the production of oxidizable intermediates and the formation of refractory products.

• Environmental Engineering Research
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• 제25권2호
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• pp.147-162
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• 2020

The main objective of this study is to estimate the levels of pollution to which the community is presently exposed and to model the regimes of local air quality. Diurnal, daily, and monthly variations of NO, NO₂, SO₂, and O₃ were thoroughly investigated in three areas; namely, residential, industrial, and terminal in Ras Al-Khafji. There is obvious diurnal variation in the concentration of these pollutants that clearly follows the diurnal variation of atmospheric temperature and main anthropogenic and industrial activities. Correlation analysis showed that meteorological conditions play a vital role in shaping the pattern and transportation of air pollutants and photochemical processes affecting O₃ formation and destruction. Bivariate polar plots, an effective graphical tool that utilizes air pollutant concentrations' dependence on wind speed and wind direction, were used to identify prevailing emission sources. Non-buoyant ground-level sources like domestic heating and street transport emissions, various industrial stacks, and airport-related activities were considered dominant emission sources in observatory sites. This study offers valuable and detailed information on the status of air quality, which has considerable, quantifiable, and important public health benefits.

• Journal of Korean Society for Atmospheric Environment
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• 제17권E1호
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• pp.25-33
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• 2001

This paper presents an overview of the UK Hydrocarbon Monitoring Network and summarises some of the lessons learnt from running and automated VOC monitoring network in th UK. The paper will describe the operation of the network and the Quality Control and Quality Assurance (QA/QC) procedures used to ensure that the data qality objectives are met. The provision of accurate measurements of ambient air pollutant concentrations is a valuable and high-profile service of Governments, assisting policy decisions and allowing members of the public to be well-informed. The need for such measurements has been increased in the UK by the National Air Quality Strategy and European Air Quality Directives, with the National Networks playing a central role in delivering the information. The Hydrocarbon Network provides measurements directly in support of monitoring requirements for benzene and 1,3-butadiene, and of 23 other hydrocarbon species important for their role in ozone and secondary particulate formation.

• 한국대기환경학회지
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• 제18권5호
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• pp.355-362
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• 2002

There has been relatively a few studies that focused on evaluation of uncertainty for standard methods by which criteria pollutants are analyzed in ambient air. Especially, uncertainty evaluation has not been made yet for sampling and analysis of airborne NO$_2$. Ambient NO$_2$ has been thought to be a major criteria pollutant worldwide because of the potential of ozone formation as well as of its own toxicity. In this study, we tried to assess uncertainties associated with the every step of sampling and of analytical procedure of Griess-Saltzman method. Quality assurance (QA) and quality control (QC) were also emphasized with the uncertainty characterization. The use of Griess-Saltzman method for ambient NO$_2$ analysis showed very uniform daily concentration distribution with the mean of 10.8 ppb and the standard deviation of 1.08ppb during the sampling period. However, seven daily samples collected at the same sampling time and place exhibited highly different concentration distribution. Therefore, we evaluated uncertainties associated with sampling and analysis through the precise application of ISO Guide. Estimates of expanded uncertainties for a total of 62 samples fell in a relatively broad range of 5.17% to 11.85%. On the other hand. the expanded uncertainties were smaller for the high concentration range of greater than 15ppb.

• 공업화학
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• 제23권1호
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• pp.42-46
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• 2012

본 연구에서는 메조기공 탄소(CMK-3)를 KOH로 활성화 하여 실내공기 오염물질인 포름알데히드 흡착에 사용하였다. 활성화는 KOH 처리한 CMK-3를 $700^{\circ}C$의 반응기에서 질소분위기로 수행하였다. 활성화된 시료의 특성은 BET, XRD, XPS, FT-IR을 통해 분석하였다. 포름알데히드의 흡착능은 활성화에 의해 향상되었으며, 이는 활성화에 의해 메조기공 탄소의 산소작용기와 질소 작용기의 생성에 기인하는 것으로 판단된다.