• Applied Biological Chemistry
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• 제1권
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• pp.26-33
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• 1960

Organic mercurial fungicides, for seed treatments and dust formulations, has been increasingly used by farmers. Evaluation of the purity of organic mercurial fungicides has been performed by precipitation method at this laboratory. There are several methods for the an alyses of organic mercuric formulation, among which are (1) Precipitation met hod, (2) Volatilization method, (3) Volumetric method, and (4) Dithizon method. These methods, however, show some deffects in specificity (differentiation of organic form) and quantitativity. Polarography applied for the estimation of phenyl mercuric acetate was found to be simple, rapid and accurate. Tile fundamental method of polarography arid accuracy of analysis are discussed statistically and a satisfactory results was obtained.

• 분석과학
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• 제5권1호
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• pp.17-24
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• 1992

Catechol의 유도체인 3, 4-dihydroxybenzoic acid, 3, 4-dihydroxybenzaldehyde, 그리고 adrenaline을 사용하여 게르마늄과 착물을 형성시킨 후 Anodic Stripping Polarography로 정량한 후, 천연물 중의 게르마늄 정량에 적용시켜 분석한 결과 인삼에서 $300{\mu}g/L$, 광천수에서 $210{\mu}g/L$를 검출할 수 있었다.

• Archives of Pharmacal Research
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• 제23권3호
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• pp.197-201
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• 2000

In an aqueous piperacillin sodium solution, a well-defined single wave or single peak was observed by direct current(DC) polarography or differential pulse polarography(DPP). The peak potential change per pH unit was -54 mV in the phosphate buffer at $18^{\circ}C$, which indicated that protons were involved in the electrochemical reduction of the 2,3-dioxopiperazine moiety of piperacillin sodium with a $H^{+}e^{-}$ ratio of one. Using a phosphate buffer of pH 4.3, the $1.0{times}10^{-7}$ M piperacillin sodium single peak could be determined by DPP with relative standard deviation of 1.6 %(n=3). Piperacillin sodium could be analyzed with-out interference from penicillin G-potassium, which enabled the employment of DPP as a fast and simple technique for monitoring the synthetic process of the antibiotic.

• 디지털산업정보학회논문지
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• 제5권4호
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• pp.11-17
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• 2009

Polarography is a subclass of voltammetry where the working electrode is a dropping mercury electrode. More, I developed the experiment for raising up mercury electrode. In Voltammetry, information about an analyte is obtained by measuring the current as the potential is varied at oxidation-reduction reaction. A plot of current vs. potential in a polarography experiment shows the current oscillations correspoding to the drops of Hg falling from the capillary. The drops growth causes capacitive and faradic current. These changing current effects combined with experiments where the potential is continuously changed can result in noisy traces. The raising up type improved upon the method of dropping in hardware. In reduction of the noise, moving average smoothing method have been used. But the other procedure is introduced based on Fourier transformation. So FFT and IFFT engine was implemented and installed in my experiment. However, after experimentation, peak height as the measuring parameter gave a good linear relationship to concentration. The resolution of potential peaks of various kinds, using Zn and Cu as the example, was improved using the smoothing method.

• 대한화학회지
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• 제10권4호
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• pp.175-180
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• 1966

Polarography에 의한 反應速度測定法 은 여러가지가 있고 또 많이 硏究되어 왔다. 그러나 그의 應用은 그렇게 많지 않으며, 본 실本 實驗에서는 Delabay의 圖解法과 Koutecky式을 利用하여 몇 가지 ion의 陰極反應速度를 求하고 이들 Data를 써서 簡易速度式을 檢討하였다.

• 한국환경보건학회지
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• 제12권2호
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• pp.11-15
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• 1986

Hydroxlamine effect on the determination of dissolved oxygen by the azide-modified Winkder method and polarography has been studied. It was found that hydroxylamine interference on the dissolved oxygen by the azide-modified Winklet method can be eliminated completely by using permanganate. An inexpensive and convenient polarograph device was constructed. Dissolved oxygen in an air-saturated 0.1 F KCl solution undergoes, independent of hydroxylamine concentrations a two-step irreversible reduction at the dropping electrode the $H_2O_2$ produced in the first step is reduced to $H_2$O in the second. Two waves of equal size result, the first with a half-wave potential (E1/2) at about -0.13 V and the second at about -0.91 V (vs. SCE).

• 분석과학
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• 제8권4호
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• pp.691-698
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• 1995

The complexation of platinum and palladium with synthetic polyelectrolytes was studied. The successive and overall stability constants of Pd(II) with PEI and 2PVP were obtained by potentiometric titration. Because of the slow equilibrium time, the potentiometric titrations were performed using the home-made automatic titrator in order to analyze the complexations according to the modified Bjerrum method. The complex formation constant of Pt(IV) with 2PVP, measured by differential pulse polarography, was calculated from the peak currents that were obtained in non-complexing media and in solution containing 2PVP.

• 분석과학
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• 제8권4호
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• pp.655-661
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• 1995

The electrochemical reduction of coumarin derivatives in 0.1M TEAP acetonitrile solution was investigated by the direct current, differential pulse polarography, cyclic voltammetry and controlled potential coulometry. The electrochemical reduction of 7-acetoxy-4-bromomethyl-coumarin(ABMC) was proceeded as an irreversible three steps(-0.58, -1.63 and -2.25 volts) of electrochemical transfer before chemical reaction. The solution color turned to yellow after the carboxyl group was reduced at 2nd step(-1.63 volts vs. Ag-AgCl) and the change in color was independant to the bromo group. Upon the basis of the results on the products analysis and the interpretaton of polarograms, a possible electrochemical reaction mechanism was suggested.

• 대한화학회지
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• 제11권4호
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• pp.138-142
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• 1967

Zn, Ni 및 Co ion의 陰極反應速度를 Polarograph로써 몇 가지 支持電解液과 溫度에서 Randles法으로 測定하였다. Zn의 速度値는 Randles들의 測定値와 20% 誤差內에서 一致하였다. Ni 와 Co ion에 對한 값은 文獻에 나타나 있지 않으나 前報의 다른 方法에 依한 値와 比較하면 適當한 값이라고 볼 수 있다. Randles法에 依한 速度値를 써서 Kambara들이 提案한 Parameter x,y(z)를 求하고 이들 사이의 關係을 考察하였으며 log y vs. log z 사이에 一種의 曲線關係가 있음을 發見하였다.

• 대한화학회지
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• 제18권5호
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• pp.341-353
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• 1974

Triphenylphosphine phenylimide의 비수용액에서의 전기화학적인 환원반응을 polarography, cyclic voltammetry, controlled-potential coulometry 및 electron spin resonance 법을 써서 고찰하였다. 이 유기인화합물은 one-electon transfer에 따라서 anion radical이 형성되나 순간일 뿐이고 protonation과 재차 one-electon reduction 결과 인과 질소사이의 이중결합이 끊어진다. 그 결과 아닐린이 주요 반응생성물로서 발견되었다. 또 한편 동반하는 화학반응결과 생긴 주산물의 하나인 triphenylposphine oxide의 환원결과 인과 페닐 사이의 단일결합이 끊어지는 것도 관찰할 수 있었다.