• Journal of the Korean Chemical Society
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• v.6 no.1
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• pp.14-18
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• 1962

Solution to the diffusion layer for the first order reaction at a droping mercury electrode (D.M.E.) is presented. Equations are derived for polarographic currents for the reactions at the D.M.E. A factor which is applicable to the D.M.E. is derived, when we use the equations of the polarographic currents for the reactions at a plane electrode(P.E.), and the rate constants of the backward reactions are negligibly small. Polarographic currents from a combination of diffusions and reactions are obtained at the D.M.E. with special approximation. Rate constant for the reaction of ferrous ion with hydrogen-peroxide is determined at the D.M.E.,using the data of Kolthoff and Perry. The agreement of the equation with the data of Kolthoff and Perry for the kinetic current of ferric ion in the presence of hydrogen-peroxide is good. Ratios of diffusion layer at the D.M.E. to the diffusion layer at the P.E. are discussed and show that, when the rate constants of the backward reactions for the first order reactions are larger than 1/0.05 sec-1. and drop-time about 3 sec., these ratioes are about one.

• Proceedings of the KIEE Conference
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• 1994.07b
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• pp.1286-1288
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• 1994

Methods are described for the design and fabrication of the sensor circuits on the polarographic oxygen sensing electrodes. The discussion includes: a method for the +5V single-supply driving for the sensor circuits, a method of low power comsumption for the front-end electronics. Typical polarograms for the commercial DO probes using this sensor circuits are presented. High accuracy of the I to V conversion using the circuits is verified.

• Journal of the Korean Chemical Society
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• v.6 no.1
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• pp.10-13
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• 1962

Titanium in solution of EDTA (Ethylenediaminetetraacetic acid) yield well-defined, reversible polarographic waves. In this report, a polarographic method for rapid determination of titanium in the Korean ilmenite was proposed, This polarographic method is based on the measurement of polarogram in the supporting electrolyte of EDTA. As the pH is increased the wave become more irreversible the diffusion current are diminished, and the half wave potential become more negative. In spite of the complication arising from numerous titanium species, in 0.2 M of EDTA, pH 6.3, the titanium waves are reproducible and analytically useful. In this medium titanium ion give well-defined reduction wave, and the half wave potential were -0.61V vs S.C.E. at pH 6.3. At the same time, the wave had a linear relationship between the concentration of titanium ion and the wave height. The Korean ilmenites were analyzed by this method and satisfactory results were obtained.

• Journal of the Korean Chemical Society
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• v.53 no.6
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• pp.749-754
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• 2009

HEMA (2-hydroxyethyl methacrylate) is a hydrophilic material which is broadly used for ophthalmologic purposes and especially in the manufacture of soft contact lenses. Also, the oxygen transmissibility (Dk/t) is a very important physical characteristic in the evaluation of a material’s adequacy to be used to produce contact lenses. This study used HEMA (2-hydroxyethyl methacrylate), MMA (methylmethacrylate), NVP (Nvinyl-pyrrolidone), the cross-linker EGDMA (ethylene glycol dimethacrylate) for copolymerization, and measured the oxygen transmissibility of the central and peripheral areas of the manufactured general and color contact lenses using the polarographic method. The measurement showed that the decreased amount of oxygen transmissibility of the central and peripheral areas of the contact lenses measured using the polarographic method range between 40.77% and 49.13%, and the oxygen transmissibility of the color contact lens showed a larger decrease due to the effects of the coloring materials.

• Journal of the Korean Chemical Society
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• v.26 no.6
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• pp.389-395
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• 1982

The polarographic behavior of 4-(2-pyridylazo)-resorcinol(PAR) in acetonitrile solution was studied. In order to investigate the type of reduction current at every reduction step, dependence of limiting current on the height of mercury head, solution temperature, and concentration of PAR have been examined. The results were shown that the reduction current was controlled by diffusion. And the effect of proton donor such as water and phenol on DC polarograms of PAR and the reversibility of every reduction wave have been evaluated. Based on the experimental results, the polarographic reduction of PAR in acetonitrile solution occurred in two one-electron steps.

• Journal of the Korean Chemical Society
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• v.9 no.3
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• pp.121-123
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• 1965

Polarographic studies of Ni(II) ion complexed with monoethanolamine, MEA, in aqueous solution have been carried out using sodium perchlorate as a supporting electrolyte. With use of D. C. and A. C. polarograms polarographic behaviors of the complex have been discussed. The wave obtained from basic solutions are found to be well defined and reversible, while reduction of the complex at pH smaller than 8.8 seems to be kinetic controlled with different complex species. Reducing species of the complex on the mercury electrode is determined to be $Ni(MEA)_3OH$ instead of $Ni(MEA)_2(OH)_2$ which is reported by other workers. Overall stability constant of $Ni(MEA)_3OH$ is obtained to be $10^{20}.$

• Proceedings of the PSK Conference
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• 2000.10a
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• pp.252.3-253
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• 2000

• Journal of the Korean Chemical Society
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• v.28 no.2
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• pp.130-134
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• 1984

The polarographic behavior of benzeneazoresorcinol (BAR) in acetonitrile as an aprotic solvent has been investigated by direct current polarography and controlled-potential coulometry. The reduction of BAR in $1.0{\times}10^{-2}$M tetraethylammonium perchrolate solution proceeds along four one-electron steps to give the corresponding amine compounds. Each reduction wave was considerably diffusion-controlled and not completely reversible.

• Journal of the Korean Chemical Society
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• v.27 no.1
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• pp.24-30
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• 1983

The polarographic behavior of 1-(2-pyridylazo)-2-naphthol (PAN) in acetonitrile as an aprotic solvent has been investigated. The reduction of PAN in $10^{-2}$ molarity of tetraethyl-ammonium perchlorate acetonitrile solution proceeds along two one-electron steps to give the corresponding hydrazo compound. Every reduction wave was diffusion controlled and considerably reversible. The reduction mechanism of PAN in acetonitrile is estimated as follows;

• Journal of Environmental Science International
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• v.13 no.9
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• pp.835-843
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• 2004

N,N-bis(2-salicylaldehyde)dipropylenetriamine(5- Hsaldipn), N,N-bis( 5-bromosalicyl-aldehyde) dipropylenetriamine (5-Brsaldipn), N,N-bis(5-chlorosalicy laldehyde )dipropylene-triamine(5-Clsaldipn), N,N-bis(2-hydroxy- $5-methoxy-benzaldehyde)dipropylenetriamine(5-OCH_3saldipn)$ and N,N-bis (2-hydroxy-5-nitrobenzaldehyde)dipropylenetriamine $(5-NO_2saldipn)$ were synthesized and characterized by elemental analysis, infrared spectrometry, NMR spectrometry and mass spectrometry. Their proton dissociation constants were determined in 70% dioxane/30% water solution by potentiometric. Stability constants of the complexes between these ligands and the metal ions such as Cu(II), Ni(II) and Zn(II) were measured in dimethyl sulfoxide by a polarographic method. Stability constants for the ligands were in the order of $5-OCH_3$ > 5-H > 5-Br > 5-Cl > $5-NO_2$ saldipn. Enthalpy and entropy changes were obtained in negative values.