• Bulletin of the Korean Chemical Society
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• 제9권4호
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• pp.202-206
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• 1988

In order to investigate the oligomerization state of the plasma membrane proteolipid apoprotein purified from the bovine kidney, fluorescence polarization experiment was carried out in the two different solvent systems, i.e., water and organic solvent(chloroform-methanol). The molecular volumes of the proteins estimated from the Perrin equation, were to be 45,258$A^3$ and 17,608$A^3$ in water and organic solvent, respectively. These values indicate that a trimerization is possibly occurring in the aqueous environment. As an auxiliary experiment for the calculation of the molecular volume using Perrin equation, fluorescence quenching constants ($K_q$) with the quencher acrylamide and fluorescence lifetimes (${\tau}_F$) of the intrinsic fluorophore tryptophan residue were estimated in the two different solvent systems. $K_q$ in water was 18.21$M^{-1}$ and it was 46.24$M^{-1}$ in organic solvent. Fluorescence lifetimes of tryptophan residue were calculated to be 2.80 nsec. in water and 3.81 nsec. in organic solvent, respectively.

• Membrane and Water Treatment
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• 제2권3호
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• pp.159-173
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• 2011

The air gap membrane distillation (AGMD) process was applied for water desalination. The main objective of the present work was to study the heat and mass transfer mechanism of the process. The experiments were performed on a flat sheet module using aqueous NaCl solutions as a feed. The membrane employed was hydrophobic PTFE of pore size 0.22 ${\mu}m$. A mathematical model is proposed to evaluate the membrane mass transfer coefficient, thermal boundary layers' heat transfer coefficients, membrane / liquid interface temperatures and the temperature polarization coefficients. The mass transfer model was validated by the experimentally and fitted well with the combined Knudsen and molecular diffusion mechanism. The mass transfer coefficient increased with an increase in feed bulk temperature. The experimental parameters such as, feed temperature, 313 to 333 K, feed velocity, 0.8 to 1.8 m/s (turbulent flow region) were analyzed. The permeation fluxes increased with feed temperature and velocity. The effect of feed bulk temperature on the boundary layers' heat transfer coefficients was shown and fairly discussed. The temperature polarization coefficient increased with feed velocity and decreased with temperature. The values obtained were 0.56 to 0.82, indicating the effective heat transfer of the system. The fouling was observed during the 90 h experimental run in the application of natural ground water and seawater. The time dependent fouling resistance can be added in the total transport resistance.

• 한국표면공학회지
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• 제44권6호
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• pp.277-283
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• 2011

In this study, the cavitation test and electrochemical experiments were conducted for ALBC3(Cu-Al) alloy that has an excellent corrosion resistance and cavitation characteristic in sea water. Based on the ASTMG32 regulation, the cavitation test was performed with the cavitation and cavitation erosion tester using piezoelectric effect. The electrochemical characteristics are evaluated with potentiostatic experiments in activation polarization potential range. As a result, cavitation damage is increased proportionally to temperature and time at $30{\mu}m$ amplitude. It is appeared that acceleration period in weight loss presented over 6 hours under the cavitation environment in sea water. In addition, corrosion damages were observed at the potential range of -3.2~-1.4 V as the result of potensiostatic experiments during 12 hours in activation polarization potential range.

• 한국자기공명학회논문지
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• 제21권4호
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• pp.114-118
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• 2017

Here, I report solid state Dynamic Nuclear Polarization (DNP) of $^1H$ nuclear spins at 0.3 T and 4.2 K. The DNP polarizer was developed based on a commercial X-band Electron Spin Resonance (ESR) modified for DNP, in combination with a NMR console and a liquid-Helium cryostat. By detuning magnetic field, DNP spectrum was measured to find the optimal condition. At +3 mT detuned from on-resonance field, $^1H$ NMR signal of 60:40 glycerol/water frozen solution doped with 20 mM perdeuterated-Tempone was amplified 43 times. The $^1H$ spin polarization obtained at 4.2 K is over 3100 times higher than that at 300 K. The width of the DNP spectrum, which is five times broader than ESR spectrum, is inconsistent with solid effect or thermal mixing, and presumably suggests a different DNP mechanism.

• International Journal of Ocean System Engineering
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• 제3권1호
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• pp.33-37
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• 2013

Reinforced concrete structures have been increasingly widely used in numerous industrial fields. These structures are often exposed to severely corrosive environments such as seawater, contaminated water, acid rain, and the seashore. Thus, the corrosion problems that occur with the steel bars embedded in concrete are very important from the safety and economic points of view. In this study, the effects of the cover thickness on the corrosion properties of reinforced steel bars embedded in multiple mortar test specimens immersed in seawater for 5 years were investigated using electrochemical methods such as the corrosion potentials, polarization curves, cyclic voltammograms, galvanostat, and potentiostat. The corrosion potentials shifted in the noble direction, and the value of the AC impedance also exhibited a higher value with increasing cover thickness. Furthermore, the polarization resistance increased with increasing cover thickness, which means that the oxide film that is deposited on the surface of a steel bar surrounded by alkali environment exhibits better corrosion resistance because the water, chloride ions and dissolved oxygen have difficulty penerating to the surface of the steel bar with increasing cover thickness. Consequently, it is considered that the corrosion resistance of reinforced steel can be improved by increasing the cover thickness. However, the corrosion resistance values of a steel bar estimated by measuring the corrosion potential, impedance and polarization resistance were not in good agreement with its corrosion resistance obtained by polarization curves.

• 한국토양비료학회지
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• 제47권2호
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• pp.85-91
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• 2014

Ground-based polarimetric scatterometers have been effective tools to monitor the growth of crop with multi-polarization and frequencies and various incident angles. An important advantage of these systems that can be exploited is temporal observation of a specific crop target. Polarimetric backscatter data at L-, C- and X-bands were acquired every 10 minutes. We analyzed the relationships between L-, C- and X-band signatures, biophysical measurements over the whole corn growth period. The Vertical transmit and Vertical receive polarization (VV) backscattering coefficients for all bands were greater than those of the Horizontal transmit and Horizontal receive polarization (HH) until early-July, and then thereafter HH-polarization was greater than VV-polarization or Horizontal transmit and Vertical receive polarization (HV) until the harvesting stage (Day Of Year, DOY 240). The results of correlation analysis between the backscattering coefficients for all bands and corn growth data showed that L-band HH-polarization (L-HH) was the most suited for monitoring the fresh weight ($r=0.95^{***}$), dry weight ($r=0.95^{***}$), leaf area index ($r=0.86^{**}$), and vegetation water content ($r=0.93^{***}$). Retrieval equations were developed for estimating corn growth parameters using L-HH. The results indicated that L-HH could be used for estimating the vegetation biophysical parameters considered here with high accuracy. Those results can be useful in determining frequency and polarization of satellite Synthetic Aperture Radar stem and in designing a future ground-based microwave system for a long-term monitoring of corn.

• 전기전자학회논문지
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• 제27권4호
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• pp.512-517
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• 2023

본 연구에서는 액정에 인가되는 전압을 조절하여 편광을 조절할 수 있는 액정 기반 편광 조절 기술을 폐쇄회로 텔레비전(CCTV)에 적용하여 사용자가 원하는 각도의 편광만을 투과시킬 수 있는 시스템을 제안한다. 기존의 편광필름이 적용된 CCTV는 역광 보정 기능에 치중되어 있기 때문에 편광을 제어할 수 없어 수면에서 반사된 빛이나 차량에서 반사된 하이라이트가 피사체 식별을 방해한다. 그러나 Vertical Alignment 모드를 사용하면 전기적으로 편광을 조절할 수 있기 때문에 사용자가 원하는 각도의 편광만 투과시켜 반사되는 하이라이트를 제거할 수 있다. 이 기술을 사용하여 얻은 이미지들은 컴퓨터 소프트웨어에 의해 최적의 이미지로 도출하였다. 편광 각도와 투과율, 편광 속도를 전기적으로 제어할 수 있는 액정 편광 패널을 편광 폐쇄회로 텔레비전에 적용하여 기존 CCTV에서의 피사체 식별을 개선하였다.

• Nuclear Engineering and Technology
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• 제53권1호
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• pp.172-177
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• 2021

The microstructure and texture of three 316L foils of 25 ㎛ thickness, which were subjected to different manufacturing process, were systematically characterized using advance analytical techniques. Then, the electrochemical property of the 316L foils in simulated pressurized water reactor (PWR) solution was analyzed using potentiodynamic polarization. The results showed that final rolling strain and annealing temperature had evident effect on grain size, fraction of recrystallization, grain boundary type and texture distribution. It was suggested that large final rolling strain could transfer Brass texture to Copper texture; low annealing temperature could limit the formation of preferable orientations in the rolling process to reduce anisotropy. Potentiodynamic polarization test showed that all samples exhibited good corrosion performance in the simulated primary PWR solution.

• 수산해양교육연구
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• 제18권1호
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• pp.58-64
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• 2006

In order to examine the effect of humidity on hydrogen embrittlement of STS 444 weld zone for boiler with dry and wet welding conditions, this paper was carried out the accelerated hydrogen osmosis test and the electrochemical Tafel polarization test. In 0.5M $H_2SO_4$ + 0.01M $As_20_3$ solution, this test is added to load of $1400kg/cm^2$ together with hydrogen osmosis by current of $50 {mA/cm^2}$ for 60 min.. The electrochemical Tafel polarization test was carried out in 0.5M $H_2SO_4$ + 0.01M $As_20_3$ solution. Therefore, the effect of humidity on hydrogen embrittlement of STS 444 was considered. The main results are as following: On the basis of hydrogen embrittlement mechanism, that is, integrated electrochemical polarization characteristics with the established mechanism of hydrogen embrittlement, the reduction rate of corrosion current density of weld zone in the wet weld condition is larger than in the dry condition. We can nondestructively predict the degree of hydrogen embrittlement of STS 444 weld zone for boiler through the reduction rate of electrochemical corrosion current density.

• Environmental Engineering Research
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• 제23권2호
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• pp.164-174
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• 2018

Corrosion of copper alloys (copper, bronze and brass) in soil was evaluated at ambient temperature using various methods such as electrochemical impedance spectroscopy (EIS), polarization curves and Scanning Electron Microscopy (SEM) coupled with Energy Dispersive Spectroscopy microanalysis measurements. Three equivalent circuits were separately used to interpret the obtained impedance spectra. The EIS measurements indicated that the polarization resistance of all electrodes increases with increasing the immersion time. SEM showed a presence of three layers of corrosion products with various composition and morphology covering each electrode. In addition, it was found that at 20% of moisture content the $R_p$ values and the current density of all electrodes in the studied soil give the following order: copper > bronze > brass. Good consistency between the data obtained from EIS and PP measurements was observed.