• Title/Summary/Keyword: Polarization of water

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Corrosion Resistance of Blended Concrete and Its Application to Crack Healing (혼합 콘크리트의 부식 저항성과 균열 치유 적용)

  • Lee, Chang-Hong;Kim, Tae-Sang;Song, Ha-Won
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.689-696
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    • 2009
  • In this study, electro-deposition method was applied to heal cracks in various blended concrete. The performance of the method was indirectly monitored by measuring impressed voltage, electrolyte, galvanic current monitoring, linear polarization resistance, and directly by image analysis of the cracks. The indirect and direct monitoring values are compared to develop guidelines for relating the indirect measures to actual crack healing. As a result, It was found that impressed voltage was convergence to 2.9V after 20000 minutes. From the galvanic current test results of artificial crack healing, the corrosion resistance showed that the order of 0.4 $>$ 0.6 $>$ 0.5 water to cement ratio. Furthermore, in view of binder, the corrosion resistance order was calculated OPC $>$ 60%GGBS $>$ 10%SF $>$ 30%PFA. Finally, It was found that 76.47% of healed crack surface calculated from the artificial crack healing technique using electrochemical deposition method.

Growth and characteristics of calcite single crystals using polarized device with amorphous calcium carbonate (비정질 탄산칼슘을 애용한 편광소자용 Calcite 단결정의 성장 및 특성평가)

  • Park, Chun-Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.3
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    • pp.93-98
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    • 2005
  • The crystal growth of calcite at a low temperature range was carried out by the hydrothermal method using amorphous calcium carbonate which has excellent solubility in water. Amorphous calcium carbonate was prepared by the wet chemical reaction of a stoichiometric mixture of $CaCl_2\;and\;Na_2CO_3$. An important factor was the reaction temperature and time taken in preparation of the amorphous calcium carbonate. From the solubility results calculated by the weight loss method, $NH_4NO_3$ solutions were found to be the most promising solvents to grow calcite single crystals. The hydrothermal conditions for high growth rates of calcite single crystals were as follows: starting material: amorphous calcium carbonate, solvent: 0.01 m $NH_4NO_3$, temperature: $180^{\circ}C$, duration: 30 days. And properties of calcite single crystals were follows: dislocation density: $10^6{\sim}10cm^{-2}$, UV-visible transmittance: about 80% from 190 to 400 nm and birefringence: $0.17{\sim}0.18$. Also, it can be known from the FT-IR results that the absorption peak by injection of $HCO_3^-\;and\;OH^-$ ions was not shown.

Flux Model of One-shaft Rotary Disc UF Module for the Separation of Oil Emulsion (1축 회전판형 UF 모듈의 투과모델 및 Oil Emulsion 분리 특성)

  • 김제우;노수홍
    • Membrane Journal
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    • v.6 no.2
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    • pp.86-95
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    • 1996
  • Rotary disc ultrafiltration module(RDM) was developed for the separation of oil e$$\mu$sions. This module was devised to reduce the gel polarization phenomenon by decoupling the operation pressure and the surface velocity of solution in ultrafiltration(UF) processes. The rotary disc membrane consists of 3mm-thick ABS plate covered with UF membrane (UOP, U.S.A.). When the angular velocity($\omega$) was increased, the pure water flux was slightly decreased due to pressure drop caused by centrifugal force and slip flow at the surface of membrane. The pressure drop was proportional to the square of linear velocity(${\omega}r$). When the angular velocity was changed from 52.36rad/s to 2.62rad/s, the flux decline for 5% cutting oil in one-shaft RDM at $25^{\circ}C$ and 0.1MPa was 30.16%. In the lower concentrations, angular velocity tends to give less effect on the flux. Flux(J; $kg/m^{2} \cdot s$) in a rotating disc module is mainly a function of the bulk concentration($C_{B}$; %), the linear velocity(${\omega}r$; m/s) and the effective transmembrane pressure($\Delta P_{T}$ ; Pa). Using a modified resistance-in-series model, the flux data of cutting oil experiments were fitted to give the following equation.

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Preparation and Characteristics of High Performance Cathode for Anode-Supported Solid Oxide Fuel Cell (연료극 지지체식 고체산화물 연료전지용 고성능 공기극 제조 및 특성 연구)

  • Song, Rak-Hyun
    • Journal of the Korean Electrochemical Society
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    • v.8 no.2
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    • pp.88-93
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    • 2005
  • Anode-supported solid oxide fuel cell (SOFC) was investigated to increase the cell power density at intermediate temperature through control of the cathode structure. The anode-supported SOFC cell were fabricated by wet process, in which the electrolyte of $8mol\%\;Y_2O_3-stabilized\;ZrO_2 (YSZ)$ was coated on the surface of anode support of Ni/YSA and then the cathode was coated. The cathode has two- or three- layered structure composed of $(La_{0.85}Sr_{0.15})_{0.9}MnO_{3-x}(LSM),\;LSM/YS$ composite (LY), and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3{LSCF)$ with different thickness. Their single cells with different cathode structures were characterized by measuring the cell performance and ac impedance in the temperature range of 600 to $800^{\circ}C$ in humidified hydrogen with $3\%$ water and air. The cell with $LY\;9{\mu}m/LSM\;9{\mu}m/LSCF\;17{\mu}m$ showed best performance of $590mW/cm^2$, which was attributed to low polarization resistance due to LY and to low interfacial resistance due to LSCF.

Estimation of Soybean Growth Using Polarimetric Discrimination Ratio by Radar Scatterometer (레이더 산란계 편파 차이율을 이용한 콩 생육 추정)

  • Kim, Yi-Hyun;Hong, Suk-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.5
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    • pp.878-886
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    • 2011
  • The soybean is one of the oldest cultivated crops in the world. Microwave remote sensing is an important tool because it can penetrate into cloud independent of weather and it can acquire day or night time data. Especially a ground-based polarimetric scatterometer has advantages of monitoring crop conditions continuously with full polarization and different frequencies. In this study, soybean growth parameters and soil moisture were estimated using polarimetric discrimination ratio (PDR) by radar scatterometer. A ground-based polarimetric scatterometer operating at multiple frequencies was used to continuously monitor the soybean growth condition and soil moisture change. It was set up to obtain data automatically every 10 minutes. The temporal trend of the PDR for all bands agreed with the soybean growth data such as fresh weight, Leaf Area Index, Vegetation Water Content, plant height; i.e., increased until about DOY 271 and decreased afterward. Soil moisture lowly related with PDR in all bands during whole growth stage. In contrast, PDR is relative correlated with soil moisture during below LAI 2. We also analyzed the relationship between the PDR of each band and growth data. It was found that L-band PDR is the most correlated with fresh weight (r=0.96), LAI (r=0.91), vegetation water content (r=0.94) and soil moisture (r=0.86). In addition, the relationship between C-, X-band PDR and growth data were moderately correlated ($r{\geq}0.83$) with the exception of the soil moisture. Based on the analysis of the relation between the PDR at L, C, X-band and soybean growth parameters, we predicted the growth parameters and soil moisture using L-band PDR. Overall good agreement has been observed between retrieved growth data and observed growth data. Results from this study show that PDR appear effective to estimate soybean growth parameters and soil moisture.

A Scientific Study of Roof Tiles in Joseon Dynasty from Dongdaemoon Stadium (동대문운동장유적 출토 조선시대 기와의 특성 연구)

  • Chung, Kwang-Yong
    • Korean Journal of Heritage: History & Science
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    • v.45 no.3
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    • pp.160-173
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    • 2012
  • Roofing tile research conducted in Korea so far is mostly related to studies on roofing tile patterns excavation report on the roof tile klin site in the aspects of archeology architecture and history of art. There have been continuous studies on kiln ground and manufacture techniques of roofing tiles. However it is difficult to find roofing tiles research based on scientific experiments. The research on this paper performs physical and chemical experimental study to understand order, manufacturing techniques and other characteristics of Chosun Dynasty roofing tiles excavated in Dongdaemun stadium. As for physical experimental study water absorption, specific gravity, whole-rock Magnetic susceptibility rate and Differential Thermal Analysis are conducted. As for chemical experimental study, neutron activation analysis(NAA), microstructure observation, X-ray diffractometry(XRD) analysis are conducted. Result of neutron activation analysis and statistical analysis on piece of roof tile 22 samples clearly show that the roofing tile samples are from different time line and places. It also shows different composition when compare average value of rare earth resources per findspots. It means roofing tiles were manufactured from clay mineral from several places. Close inspection using XRD and polarization microscope reveals that main components of roofing tiles are quartz and felspar. Mica and Illite are found partially. XRD analysis shows mullite mineral composition which occurs when roofing tile is calcined around $1000^{\circ}C$. Differential thermal analysis shows gradual exothermic peak near $900^{\circ}C$. Based on these results, it is assumed that roofing tile is made at $900{\sim}1000^{\circ}C$. result of XRD analysis shows mullite were made near $1000^{\circ}C$. in Differential Thermal Analysis shows gradual exothermic peak near $900^{\circ}C$. this results shows that roof tiles were made near 900~1000 near $1000^{\circ}C$ mean value of whole-rock Magnetic susceptibility rate. When performed comparative analysis using whole-rock Magnetic susceptibility rate average value, findspots provided no certain classification to arrange. Nonetheless low whole-rock Magnetic susceptibility rate 0.2~0.78(${\times}103$ SI unit) is found when roofing tile patterns are Pasangmun, Taesangmun, Eosangmun, Kyukjamun, Heongsunmun. Overall absorptivity is 14~21%. It is similar to 14~18% of roofing tile from Chosun Dynasty. There is only 1.4~2.5g/cm3 of roof tile sample specific gravity. The analysis finds no difference in specific gravity by findspots.