• Bulletin of the Korean Chemical Society
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• 제16권5호
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• pp.454-458
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• 1995

Inhibiting action of semicarbazide, thiosemicarbazide, sym. diphenylcarbazide towards corrosion of zinc in hydrochloric acid has been investigated. The rate of corrosion depends on the nature of the inhibitor and its concentration. The values of inhibition efficiency from, weight loss, thermometric measurements are in good agreement with those obtained from polarization studies. From the polarization studies, the inhibitors used act as mixed absorption type inhibitors, increased adsorption resulting from an increase in the electron density at the reactive C=S and C=O groups and N-atoms. The thermodynamic parameters of adsorption obtained using Bockris-Swinkels adsorption isotherm reveal a strong interaction of these carbazides on zinc surface.

• 대한화학회지
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• 제58권2호
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• pp.160-168
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• 2014

The electrochemical behavior and corrosion inhibition of zinc in 0.5 M $H_2SO_4$ in the absence and presence of some chromones has been investigated using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. The presence of these investigated compounds in the corrosive solutions decrease the weight loss, the corrosion current density, and double layer capacitance but increases the charge transfer resistance. Polarization studies were carried out at room temperature, and showed that all the studied compounds act as mixed type inhibitors with a slight predominance of cathodic character. The effect of temperature on corrosion inhibition has been studied and the thermodynamic activation and adsorption parameters were determined and discussed. The adsorption of the investigated compounds on zinc was found to obey Langmuir adsorption isotherm.

• 전자공학회논문지D
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• 제34D권11호
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• pp.83-89
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• 1997

An optimize delectroabsorption modulator structure is designed for high speed optical communication systems considering the extinction efficiency, operating bandwidth, polarization loss, and wavelength chirping. the operating wavelength region is $1.55\mu\textrm{m}$ and the deep ridge structure is adapted for th eminimum polarization loss. Simulations show that the absorption layer thickness larger than $0.25\mu\textrm{m}$, and the modulator length shorter than $200\mu\textrm{m}$ are required for the bandwidth over 10GHz. To obtain the modulatiron efficiency over 10dB/V, a wavelength detuning needs to be determined less than 40meV.

• 한국안전학회지
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• 제6권4호
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• pp.5-12
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• 1991

The dielectric properties of natural rubbers for electric safety are very important to investigate the molecular structure. The electric safety characteristics of the dielectric absorption in aging vulcanized natural rubber were studied in the range of frequency from 1$\times$10$^3$［Hz］to 3.2$\times$10$^3$［Hz］l at the temperature of 23［$^{\circ}C$］. As the results, it has been confirmed that in the case of aging natural rubber of above 2 phr the specimens exhibit two kinds of dielectric losses due to the dipole polarization by impurities and sulfurs, and of raw rubber exhibit the kind of losses due to the dipole polarization. Rurthermore, dielectric loss maximum tansspectrum in high freguency region for electric safety, which removed to the low freguency according to increasing sulfur, depends greatly on sulfur.

• Progress in Superconductivity
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• 제3권2호
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• pp.178-182
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• 2002

Superconducting four-element patch array antenna was designed and fabricated using $high-T_{c}$ superconducting (HTS) thin film. The array antenna has single-feed circularly polarization and a resonance frequency of 11.85 GHz fur satellite communication system. To fabricate this antenna $YBa_2$$Cu_3$$O_{7-x}$(YBCO) superconducting thin films were deposited using rf-magnetron sputtering technique. Sequential rotation technique based on radiation elements($0^{\circ}$ , $90^{\circ}$, 1$80^{\circ}$, $270^{\circ}$ phase delay) was utilized to achieve circularly polarization. Simulated and measured results, the analysis on resonant frequency(fr), return loss, and bandwidth are presented. The results show that 10 dB return loss bandwidth of the array antenna is 11.04 GHz~12.59 GHz (13.15%) and 3dB axial ratio bandwidth is 11.42~12.52 GHz (9.2%).).).

• 한국전기전자재료학회논문지
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• 제18권11호
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• pp.1038-1042
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• 2005

We have investigated dielectric properties depending on bias voltage in organic light-emitting diodes using 8-hydroxyquinoline aluminum $(Alq_3)$ as an electron transport and emissive material. We analyzed the dielectric properties of organic light-emitting diodes using impedance of characteristics. Impedance characteristics was measured complex impedance Z and phase $\theta$ in the frequency range of 40 Hz to $10^8$ Hz. We obtained complex electrical conductivity, dielectric constant, and loss tangent $(tan\delta)$ of the device at room temperature. From these analyses, we are able to interpret a conduction mechanism and dielectric properties contributed by an interfacial and orientational polarization.

• 대한화학회지
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• 제57권6호
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• pp.672-676
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• 2013

The corrosion inhibition nature of Ginger affinale extract for the corrosion of mild steel in 0.5N $H_2SO_4$ was investigated using weight loss, electrochemical impedance and potentiodynamic polarization methods. The results revealed that Ginger affinale extract acts as a good corrosion inhibitor in 0.5N $H_2SO_4$ medium. The inhibition efficiency increased with an increase in inhibitor concentration. The inhibition could be attributed to the adsorption of the inhibitor on the steel surface.

• Journal of the Optical Society of Korea
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• 제15권3호
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• pp.289-292
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• 2011

Reactive mesogen (RM) is an organic liquid crystal molecule that can be self-aligned to have an optic axis of birefringence when coated over a polyimide alignment film. A free-standing optical wave-plate film consisting of RM and low-loss optical polymers was fabricated in this work, and the film was inserted across the polymer waveguide to form an integrated optical polarization converter. For convenient evaluation of the polarization converters, a waveguide polarizer and analyzer were fabricated in series. The polarization conversion efficiency was measured to be 25 dB for the wavelength range from 1520 to 1580 nm. The wave plate exhibited a temperature-dependent retardation of $4.5^{\circ}$ for a temperature change from 25 to $100^{\circ}C$.

• 한국세라믹학회지
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• 제48권1호
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• pp.110-115
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• 2011

$Gd_2O_3$-doped $CeO_2$ (GDC) and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ (LSCF) composite cathode materials were prepared in order to be applied to intermediate-temperature solid oxide fuel cells. The electrochemical polarization was evaluated using ac impedance spectroscopy involving geometric restriction at the interface between an ionic electrolyte and a mixed-conducting cathode. In order to optimize the cathode composites applicable to a GDC electrolyte, the cathode composites were evaluated in terms of polarization losses with regard to a given electrolyte, i.e., GDC electrolyte. The polarization increased significantly with decreasing temperature and was critically dependent on the compositions of the composite cathodes. The optimized cathode composite was found to consist of GDC 50 wt% and LSCF 50 wt%; the corresponding normalized polarization loss was calculated to be 0.64 at $650^{\circ}C$.

• Journal of Advanced Marine Engineering and Technology
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• 제24권4호
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• pp.460-469
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• 2000

A study on the corrosion behavior of RE36 steel for marine structure was investigated with parameters such as micro-Vickers hardness, corrosion potential and corrosion current density measurement of weld metal(WM), base metal (BM) and heat affected zone(HAZ), Al anode generating current and Al anode weight loss quantity in case of cathodic protection. And we carried out slow strain rate test(SSRT) in order to research mechanical properties such as stress at maximum load, percent strain, time to fracture and strain to failure ratio etc and to find out limiting cathodic polarization potential for hydrogen embrittlement with applied cathodic polarization potential. Hardness of HAZ part was the highest among those three parts and also galvanic corrosion susceptibility was the highest in HAZ part among those three parts due to the lowest corrosion potential than other parts. However corrosion current density was the highest in WM part among those three parts. And the optimum cathodic polarization potential showing the best mechanical properties obtained by SSRT method with applied constant cathodic potential was from - 770mV to - 875mV(SCE). However it is suggested that limiting cathodic polarization potential indicating hydrogen embrittlement on the mechanical properties was under - 900mV(SCE).