• 제목/요약/키워드: Polarization coefficient

검색결과 178건 처리시간 0.021초

An adaptive approach for the chloride diffusivity of cement-based materials

  • Tran, Bao-Viet;Pham, Duc-Chinh;Loc, Mai-Dinh;Le, Minh-Cuong
    • Computers and Concrete
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    • 제23권2호
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    • pp.145-153
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    • 2019
  • Adaptive schemes are constructed in this paper for modeling the effective chloride diffusion coefficient of cement-based materials (paste and concrete). Based on the polarization approximations for the effective conductivity of isotropic multicomponent materials, we develop some fitting procedures to include more information about the materials, to improve the accuracy of the scheme. The variable reference parameter of the approximation involves a few free scalars, which are determined through the available numerical or experimental values of the macroscopic chloride diffusion coefficient of cement paste or concrete at some volume proportions of the component materials. The various factors that affect the chloride diffusivity of cement-based material (porous material structure, uncertainty of value of the chloride diffusion coefficient in water-saturated pore spaces, etc.) may be accounted to make the predictions more accurate. Illustrations of applications are provided in a number of examples to show the usefulness of the approach.

Comparison with Polarization Characteristic of Polymers

  • Choi, Chil-Nam;Yabg, Hyo-Kyung
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2001년도 가을 학술발표회 발표논문집
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    • pp.188-190
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    • 2001
  • We carried out to measure the variations of potential with current density polymers. The results were particularly examined to identify the influences on corrosion potential and corrosion rate of various factors including temperature and pH. The Tafel slope for anodic dissolution was determined by the polarization effect depending on these conditions. The optimum conditions were established for each case. The second anodic current density peak and maximum passive current density were designated as the relative corrosion sensitivity($I_{r}I_{f}$). The mass transfer coefficient value (${\alpha}$) was determined with the Tafel slope for anodic dissolution based on the polarization effect with optimum conditions.

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Polarization behavior of polyvinylidene fluoride films with the addition of reduced graphene oxide

  • Lee, Junwoo;Lim, Sangwoo
    • Journal of Industrial and Engineering Chemistry
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    • 제67권
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    • pp.478-485
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    • 2018
  • The effect of reduced graphene oxide (RGO) addition on the dielectric and piezoelectric behavior of the polyvinylidene fluoride (PVDF) films was studied. Dielectric constant increased by four times and piezoelectric coefficient also increased twice by the addition of RGO in the PVDF films. Based on capacitance-voltage and ellipsometry measurements and the Kramers-Kronig transformation, it is concluded that the enhanced dielectric and piezoelectric properties of the PVDF/RGO films resulted from the increased orientational polarization due to a phase transition from nonpolar crystalline ${\alpha}$ phase to polar crystalline ${\beta}$ phase in the PVDF structure.

Pyroelectricity of Drawn Poly(vinylidenefluoride) Films

  • 조재환;김상용
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1988년도 학술발표초록집
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    • pp.34-34
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    • 1988
  • The pyroelectricity of poly(vinylidenefluoride) films prepared by varying the draw ratio and the poling field was investigated. As the draw ratio and the electric field on poling of the drawn samples increased, so did the pyroelectric coefficient. But the effect of electric field on the pyroelectricity was greater than that of draw ratio. The pyroelectric and piezoelectric activities could be explained by the polarization using the thermally stimulated current. The relation between pyroelectric coefficient and piezoelectric stress constant showed a good linearity.

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무정형 고분자 재료의 비선형 유전특성(II) (Nonlinear Dielectric Properties of Amorphous copolymers(II))

  • 강대하;노일수;이상욱
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 C
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    • pp.1617-1619
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    • 2000
  • In this study the nonlinear dielectric properties of amorphous copolymers were analyzed by the related nonlinear dielectric theory. The theory is related to the cooperated dipoles and the number of the dipoles. The relation between the polarization coefficient $R_p$ and the nonlinear coefficient $R_s$ was deduced under the assumption of isotropic media.

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X-밴드 이중편파레이더에서 관측된 채프에코의 특성 (Characteristics of Chaff Echoes Observed by X-band Dual Polarization Radar)

  • 서은경;박소라;남경엽;허솔잎
    • 한국지구과학회지
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    • 제34권1호
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    • pp.1-12
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    • 2013
  • 채프에코는 기상레이더 영상에서 강수에코로 자주 오인된다. 본 연구에서는 채프에코를 효과적으로 제거하기 위하여 국립기상연구소 X-밴드 이중편파레이더에서 관측한 자료를 활용하여 채프에코의 반사도와 각각의 이중편파변수의 관계성을 분석하였다. 특히 본 연구는 채프에코 사례의 입체관측자료 영상에서 채프에코가 발생한 영역만을 선별하여 이중편파변수 자료들을 수집하였다. 전반적으로 이중편파변수(반사도, 차등반사도, 교차상관계수, 차등반사도 표준편차와 비차등위상차)에 대해 채프에코의 변수 값이 강수에코보다 넓은 범위를 차지하며, 채프 섬유의 공간적 배치는 레이더빔에 대해 수평적으로 놓여있는 경향이 나타났다. 일부 강수에코의 교차상관계수는 0.8 이하의 값을 갖고 있기 때문에 채프에코 값과 상당한 중첩이 나타났다. 일반적으로 교차상관계수는 강수에코와 채프에코를 효과적으로 분리하는데 좋은 변수로 고려되고 있지만, 이 연구는 교차상관계수만을 이용하여 채프에코를 제거할 경우에 일부 강수에코가 제거될 가능성이 있음을 시사한다.

Study on the heat and mass transfer in ultrasonic assisting vacuum membrane distillation

  • Guo, Hao;Peng, Changsheng;Ma, Weifang;Yuan, Hetao;Yang, Ke
    • Membrane and Water Treatment
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    • 제8권3호
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    • pp.293-310
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    • 2017
  • An ultrasonic assisting vacuum membrane distillation (VMD) system was designed to promote the heat and mass transfer in membrane distillation (MD) process. Both the effects of operating conditions and ultrasonic parameters to permeation flux in this process were investigated; the heat and mass transfer mechanism was also being discussed in this paper. The results showed that the performance of VMD process was improved significantly by ultrasonic assisting. The permeation flux was boosted at a certain feed solution temperature, pressure at permeate side and feed solution velocity whether or not to PP and PTFE. The results also indicated that ultrasonic power and frequency also was the key factor affecting the mass and transfer efficiencies. The feed side transfer coefficient ($K_f$), corresponding to ultrasonic power ($K_f=4.406-0.026{\times}P+7.824{\times}10^{-5}{\times}P^2$) and ultrasonic frequency ($K_f=0.941+0.598{\times}f-0.012{\times}f^2+6.283{\times}10^{-5}f^3$), was obtained and employed in the modeling of ultrasonic assisting VMD process. The modeling results showed that the calculated value of $K_f$ aligned with experimental results well. Both variations of temperature polarization coefficient (TPC) and concentration polarization coefficient (CPC) were studied based on the obtained data. The results showed that both TPC and CPC were improved obviously by the ultrasonic parameters.

Relationship between RADARSAT backscatter coefficient and rice growth

  • Hong, Suk-Young;Hong, Sang-Hoon;Rim, Sang-Kyu
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 1999년도 Proceedings of International Symposium on Remote Sensing
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    • pp.468-473
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    • 1999
  • This study was carried out to assess the use of RADARSAT data which is C-band with HH polarization for the rice growth monitoring in Korea. Nine time-series data were taken by shallow incidence angle (standard beam mode 5 or 6) during rice growing season. And then, backscatter coefficient ($\sigma$$^{\circ}$) were extracted by calibration process for comparing with rice growth parameters such as plant height leaf area index(LAI), and fresh and dry biomass. Field experimental data concerned with rice growth were collected 8 times for the ground truth at the study area, Tangjin, Chungnam, Korea. At the maximum vegetative stage of rice, backscatter coefficients were the highest at the flooded rice field ranging from -4.4dB~-3.1dB. The temporal variation of backscatter coefficient($\sigma$$^{\circ}$) in rice field was significant in this study Backscatter coefficient ($\sigma$$^{\circ}$) of rice field was a little bit lower again after heading stage. This results show RADARSTA data is promising for rice monitoring.

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Electrochemical Impedance Spectroscopy and Cyclic Voltammetry Methods for Monitoring SmCl3 Concentration in Molten Eutectic LiCl-KCl

  • Shaltry, Michael R.;Allahar, Kerry N.;Butt, Darryl P.;Simpson, Michael F.;Phongikaroon, Supathorn
    • 방사성폐기물학회지
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    • 제18권1호
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    • pp.1-18
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    • 2020
  • Molten salt solutions consisting of eutectic LiCl-KCl and concentrations of samarium chloride (0.5 to 3.0 wt%) at 500℃ were analyzed using both cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The CV technique gave the average diffusion coefficient for Sm3+ over the concentration range. Equipped with Sm3+ diffusion coefficient, the Randles-Sevcik equation predicted Sm3+ concentration values that agree with the given experimental values. From CV measurements; the anodic, cathodic, and half-peak potentials were identified and subsequently used as a parameter to acquire EIS spectra. A six-element Voigt model was used to model the EIS data in terms of resistance-time constant pairs. The lowest resistances were observed at the half-peak potential with the associated resistance-time constant pairs characterizing the reversible reaction between Sm3+ and Sm2+. By extrapolation, the Voigt model estimated the polarization resistance and established a polarization resistance-concentration relationship.