• Title/Summary/Keyword: Polarization and stability

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Development of Metallic Bipolar Plate Material with W-addition in Austenitic Stainless Steel for PEMFC Environment

  • Kim, Kwang Min;Koh, Sung Ung;Kim, Kyoo Young
    • Corrosion Science and Technology
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    • v.5 no.5
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    • pp.153-159
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    • 2006
  • Austenitic stainless steels with addition of various amounts of Mo and W were evaluated in terms of corrosion and contact resistance to determine optimum alloy composition of metallic bipolar plate for PEMFC. The corrosion property was evaluated by both acid fume exposure test at $130^{\circ}C$ and by electrochemical polarization tests in $H_3PO_4$ solution at $80^{\circ}C$. Austenitic stainless steel with proper amount of Mo and W demonstrated not only good corrosion resistance but also low contact resistance. Analyses on the passive film show that partial substitution of Mo by W enhances passive film stability and repassivation property. Test results suggest that austenitic stainless steel with 2 wt%Mo and 4 wt%W has optimum composition for metallic bipolar plate used in PEMFC.

Study of Operation Strategy for Hybrid PEM Fuel Cell and Supercapacitor (고분자 전해질 연료전지와 슈퍼캐패시터 하이브리드 시스템의 운전 전략에 관한 연구)

  • Park Kwang-Jin;Ji Hyun-Jin;Bae Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.8 s.251
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    • pp.756-763
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    • 2006
  • PEMFC has several technical problems such as water management, long term stability and performance degradation as. PEMFC has been studied not only to solve water management, but also to generate power in stable manner to system by using a hybrid system with auxiliary energy storage device. The purpose of this study is to couple PEMFC with supercapacitor to make a hybrid system and to design and test control strategies for stable power generation in case of changing output power. The polarization curve and dynamic behaviors while changing power were investigated to find out characteristics of PEMFC stack. A DC/DC converter was fabricated in order to increase fuel cell and supercapacitor voltage and to charge supercapacitor. We found that the operation strategy 2 was recommended to the system because of solving water management problem and increasing the dynamic behavior.

Study on the Frictional Behavior, Wear and Corrosion Resistance of Textured TiN Coated Layers (집합조직이 존재하는 TiN 코팅 층의 마찰, 마멸, 내부식 특성에 관한 연구)

  • 김희동;김인수;성동영;이민구
    • Transactions of Materials Processing
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    • v.12 no.4
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    • pp.394-400
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    • 2003
  • TiN coated films exhibit excellent mechanical properties such as high wear, erosion and corrosion resistances and a high thermal stability. Therefore, they are widely applied to a coating material in tools, ornaments, parts and semiconductors. However, the fracture of TiN coated films frequently occurs. The distribution of preferred orientations, i.e., texture, of TiN coated films strongly influences the fracture behavior of these films. In the present study. various TiN coating layers having different textures were prepared by the reactive ion physical vapor deposition and the texture dependence of friction coefficient, erosion and corrosion in these coating layers was investigated. The sample depicting the (115) texture parallel to the coating layer normal displayed a flatter surface than that observed from the sample having the (111) texture. The friction coefficient of TiN thin films was hardly dependent on the texture of coated samples. The samples having (115) texture displayed higher wear, erosion and corrosion resistances than the samples having (111) texture.

A Study on the Corrosion Properties of Underwater Wet Arc Welds Using the SM 41 (선체용 압연 강판의 습식 수중 아크 용접부의 부식특성에 관한 연구)

  • Kwak, H.H.;Ki., C.G.;Kim, M.N.;Hwang, S.H.
    • Journal of Power System Engineering
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    • v.9 no.4
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    • pp.110-117
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    • 2005
  • Underwater wet arc welds were experimentally performed on 11mm thick KR-RA steel plate using six different types of flux coated electrodes of 4.0mm diameter, KSKR, KSKT, USBL, JPUW, UWEA and UWEB. From analysis of bead appearance, detachability of weld slag, spatter occurrence and arc stability, JPUW gives the best result, and UWEB is superior to KSKR and KSKT. By experimental result of hardness distribution on the weld bonds, UWEB weld has the narrowest bond structure which is probable condition to get the best mechanical properties of weld. UWEB and JPUW welds have more even hardness distribution across weld deposit and base metal. Upon polarization test to measure the respondency of corrosion, the electrode of UWEB shows the most excellent degree due to the low open circuit potential difference.

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A Study on the Corrosion Properties of Underwater Wet Arc Welds using the SM 41 (선체용 압연 강판의 습식 수중 아크 용접부의 부식특성에 관한 연구)

  • Kwak, H.H.;Kim, C.G.;Kim, M.N.;Hwang, S.H.
    • Journal of Power System Engineering
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    • v.10 no.4
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    • pp.111-118
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    • 2006
  • Underwater wet arc welds were experimentally performed on 11mm thick KR-RA steel plate using six different types of flux coated electrodes of 4.0mm diameter, KSKR, KSKT, USBL, JPUW, UWEA and UWEB. From analysis of bead appearance, detachability of weld slag, spatter occurrence and arc stability, JPUW gives the best result, and UWEB is superior to KSKR and KSKT. By experimental result of hardness distribution on the weld bonds, UWEB weld has the narrowest bond structure which is probable condition to get the best mechanical properties of weld. UWEB and JPUW welds have more even hardness distribution across weld deposit and base metal. Upon polarization test to measure the respondency of corrosion, the electrode of UWEB shows the most excellent degree due to the low open circuit potential difference.

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Personality Correlates of Political Support: Evidence from South Korea

  • Ha, Shang E.
    • Asian Journal for Public Opinion Research
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    • v.7 no.4
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    • pp.207-225
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    • 2019
  • Despite a vast amount of research on the relationship between personality traits and political attitudes, little is known about the effects of personality on individuals' support for the political system of their own country. Using three nationally representative datasets from South Korea, the present study shows that the personality dimensions - particularly, Agreeableness - are positively associated with political support, which encompasses confidence in the presidency, confidence in the government, and national pride. These findings suggest that two facets of Agreeableness - trust and compliance - are activated in expressing individuals' support for their political system. Thus, mobilizing citizens who score high on Agreeableness is essential to maintain political stability and legitimacy, but such a task appears to be difficult, given that ideological polarization discourages them from being politically active due to their propensity to conflict avoidance.

The Effect of Y Doping on Electrochemical Behavior of Spherical $Li_4Ti_5O_{12}$ for Li-ion Batteries

  • Ji, Mi-Jeong;Choe, Byeong-Hyeon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.31.1-31.1
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    • 2011
  • $Li_4Ti_5O_{12}$ is emerging as a promising material with its good structure stability and little volume change during the electrochemical reaction. However, its electrochemical performance is significantly limited by low electronic or ionic conductivity. In addition, high tap density is needed forim proving its volumetric energy density and commercialization. To enhance these properties, the spherical-like $Li_4Ti_5O_{12}$ particles were synthesized and carried out doping with yttrium. Prepared Y-doped $Li_4Ti_5O_{12}$ as a anode material showed great capacity retention rate of 92% (5C/0.2C), compared with no dope done. Consequently, it was found that Y doping into $Li_4Ti_5O_{12}$ matrix reduces the polarization and resistance on SEI layer during the electrochemical reaction.

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Stabilization of Fiber-optic Current Sensor Using a Faraday Rotator Mirror (Faraday 반사경을 이용한 광섬유형 전류센서의 안정화)

  • 김기혁;송민호
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.17 no.6
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    • pp.72-76
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    • 2003
  • We developed a polarimetric fiber-optic current sensor using a length of twisted fiber and a Faraday rotator mirror which was used to suppress the linear birefringence effect. A gold coated mirror was also used as the sensor coil reflector, and the results were compared with the case of FRM. From the experimental results, it is clear that the FRM greatly enhances the stability of the fiber optic current sensor output..

A study on the piezoelectric characteristic of 0.02PYW-0.98PZT system piezoelectric ceramics dopped with NiO, $Cr_2O_3$ (NiO 및 $Cr_2O_3$를 첨가한 0.02PYW-0.98PZT계 세라믹의 압전특성에 관한 연구)

  • Kim, Jean-Shop;Kim, Hyun-Chul;Woon, Hyen-Sang;Bae, Seon-Gi
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1789-1791
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    • 1999
  • In consideration of piezoelectric characteristic and Temperature stability, 3-element system dopped with NiO, $Cr_2O_3$ well-known as Hardner and Stabilizer whose primary element is PZT was eximanated its structure, piezoelectric characteristics, dopping with Nio, $Cr_2O_3$. We think that piezoelectric Characteristic is developed, remenent polarization and $E_c$ can developed in specimens by dopping with NiO, $Cr_2O_3$ additive. also, electromechanical quality factor largely showed tendency of decrement. According to dopping NiO, $Cr_2O_3$ more.

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Temperature-dependent studies on catalytic hydrosilation of polyalkylsiloxane using NMR

  • Sul, Hyewon;Lee, Tae Hee;Lim, Eunsoo;Rho, Yecheol;Kim, Chong-Hyeak;Kim, Jeongkwon
    • Analytical Science and Technology
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    • v.30 no.4
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    • pp.213-219
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    • 2017
  • Polyalkylsiloxane has been spotlighted in pressure-sensitive adhesive (PSA) application due to excellent physical properties and good biocompatibility. Thermal behaviour of polyalkylsiloxane mixtures, such as thermal stability and heat flow, were studied using TG-DTA during catalytic hydrosilation. To understand reaction kinetics of cross-linking, catalytic hydrosilation of polyalkylsiloxane was monitored using variable temperature nuclear magnetic resonance (VT-NMR) as increased temperature. The formation of cross-linking bond $Si-CH_2-CH_2-Si$ was directly observed using distortionless enhanced by polarization transfer (DEPT) technique. Successfully polyalkylsiloxane PSA samples exhibited excellent adhesion properties by cross-linking reaction.