• Title/Summary/Keyword: Polarization and stability

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Stability Tests on Anion Exchange Membrane Water Electrolyzer under On-Off Cycling with Continuous Solution Feeding

  • Niaz, Atif Khan;Lim, Hyung-Tae
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.369-376
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    • 2022
  • In this study, the stability of an anion exchange membrane water electrolyzer (AEMWE) cell was evaluated in an on-off cycling operation with respect to an applied electric bias, i.e., a current density of 500 mA cm-2, and an open circuit. The ohmic and polarization resistances of the system were monitored during operation (~800 h) using electrochemical impedance spectra. Specific consideration was given to the ohmic resistance of the cell, especially that of the membrane under on-off cycling conditions, by consistently feeding the cell with KOH solution. Owing to an excess feed solution, a momentary increase in the polarization resistance was observed immediately after the open-circuit. The excess feed solution was mostly recovered by subjecting the cell to the applied electric bias. Stability tests on the AEMWE cell under on-off cycling with continuous feeding even under an open circuit can guarantee long-term stability by avoiding an irreversible increase in ohmic and polarization resistances.

Real-time Adaptive Polarization Control in a Non-PM Fiber Amplifier

  • Kyuhong, Choi;Jinju, Kim;Dal Yong, Lee;Changsu, Jun
    • Current Optics and Photonics
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    • v.7 no.1
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    • pp.33-37
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    • 2023
  • Real-time adaptive control of laser output polarization is presented in a 10-W-level non-polarization-maintaining (non-PM) fiber amplifier. While the output polarization from a non-PM fiber amplifier tends to be irregular, depending on output power, time, and perturbation, closed-loop polarization control can maintain the polarization extinction ratio at higher than 20 dB. Real-time polarization control can attain the target linear polarization mostly within 1.4-25 ms and shows stability against external perturbations. This approach can satisfy both linear polarization and high output power in a non-PM amplifier, and facilitates optimization of laser performance and maintenance-free operation.

Improvement of Corrosion Resistance for Copper Tube by Electrochemical Passivation (전기화학적 부동태화에 의한 동관의 내식성 개선 연구)

  • Min, Sung-Ki;Kim, Kyung-Tae;Hwang, Woon-Suk
    • Corrosion Science and Technology
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    • v.10 no.4
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    • pp.125-130
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    • 2011
  • This study was performed to improve the corrosion resistance and the stability of passive film on copper tube by potentiostatic polarization method in synthetic tap water. Formation of passive film was carried out by anodic potentiostatic polarization at various passivation potentials and passivation times in 0.1 M NaOH solution. Stability of passive film and corrosion resistance was evaluated by self-activation time, ${\tau}_0$ from passive state to active state on open-circuit state in 0.1 M NaOH solution. Addition of polyphosphate in NaOH solution prolonged the self-activation time and improved the corrosion resistance, and the addition of 5 ppm polyphosphate was most effective. It was also observed that better corrosion resistance was obtained by potentiostatic polarization at 1.0 V (vs. SCE) than at any other passivation potentials. Passivated copper tube showed perfect corrosion resistance for the immersion test in synthetic tap water showing that the anodic potentiostatic polarization treatment in 0.1 M NaOH with 5 ppm polyphosphate solution would be effective in improving the corrosion resistance and preventing the blue water problem.

Investigations of Ferroelectric Polarization Switching in Potassium Nitrate Composite Films

  • Kumar, Neeraj;Nath, Rabinder
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.2
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    • pp.60-65
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    • 2014
  • This article explains the experimental results of ferroelectric polarization switching (FPS) of potassium nitrate ($KNO_3$) with different polymers such as polyvinylidene fluoride (PVDF) and polyvinyl fluoride (PVF) using simple melt-press techniques. To analyze the ferroelectric polarization switching in potassium nitrate ($KNO_3$) composite films at room temperature, we applied the Ishibashi and Takagi theory (based on Avrami model) to the switching current transient. To investigate the dimensionality of domain growth, the ferroelectric polarization switching current (FPS current) was observed from the square - wave bipolar signals across a resistance of $0.1k{\Omega}$ in series with the composite films. The existence of a switching current transient pulse confirmed the ferroelectricity and indicated the stability of the ferroelectric phase (phase III) of $KNO_3$ at room temperature. Polarization hysteresis (P-E) characteristics supported the prominent features of ferroelectric polarization switching in the composite films at room temperature.

Thermal Stability of Polarized UV Exposed Polyimide Films for Liquid Crystal Display (편광 자외선이 조사된 액정 디스플레이용 폴리이미드 필름의 열 안정성)

  • 김일형;김욱수;하기룡
    • Polymer(Korea)
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    • v.26 no.4
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    • pp.431-438
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    • 2002
  • We studied the orientation behavior and thermal stability of polyimide (PI) molecules under irradiation of polarized UV (PUV) using polarized fourier transform infrared (FTIR) spectroscopy. In the case of PUV-exposed PI films, the remaining PI molecules after photo-degradation showed molecular orientation perpendicular to the irradiated PUV polarization direction predominantly, due to the preferential degradation of PI molecules parallel to the irradiated PUV Polarization direction. On the other hand, the rubbing of PI films induced reorientation of the PI molecules parallel to the rubbing direction. We also investigated the thermal stability of the alignment layers furled by rubbing and PUV irradiation on the PI films using Polarized FTIR. The thermal stability of the PUV irradiated PI alignment layer is lower than that of the rubbed PI layer due to the fragmentation reaction of the PI by PUV.

Thermal stability analysis of interferometric snapshot spectro-polarimeter (간섭기반 스냅샷 분광편광위상측정의 열 안정성 분석)

  • Choi, Inho;Dembele, Vamara;Paul, Madhan Jayakumar;Choi, Sukhyun;Kim, Junho;Baek, Byung-Joon;Kim, Daesuk
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.3
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    • pp.70-74
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    • 2018
  • In typical spectroscopic ellipsometry, the optical and geometrical properties of thin film and nano pattern can be obtained by measuring the polarization state of light reflected/transmitted from the object by rotating a analyzer or a compensator. We proposed a snapshot spectroscopic ellipsometric system based on a modified Michelson interferometer to overcome the time-consuring measurement principle due to rotating part. The proposed system provides spectral ellipsometric parameters (psi, delta) in real time by using a single spectral interference signal generated in the interferometric polarization module. However, it has a long-term stability problem resulting in delta(k) drift. In this paper, it is experimentally proved that the drift problem is caused by anisotropic refractive index change of the beam intersection layer in beam splitter of interferometer.

Characterization of an all fiber optic gyroscope constructed with polarization maintaining fiber; (편광유지 광섬유 자이로스코프 제작 및 특성 측정)

  • 전민용
    • Korean Journal of Optics and Photonics
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    • v.4 no.4
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    • pp.487-492
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    • 1993
  • A polarization maintaining fiber optic gyroscope was constructed having an optical loss of about 25 dB. Using the earth rotation rate as a reference, the long term stability of better than $3^{\circ}/hr$ and the rms short term noise of $0.6^{\circ}/hr/{\sqrt{Hz}}$ were obtained.

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The Anodicc PolarizationBehavior of Fe-Cr-Ni-W alloy in 1N HCI Solution (1N 염산 용액에서 Fe-Cr-Ni-W 합금의 양분극 거동에 관한 연구)

  • 윤재돈;강성군
    • Journal of the Korean institute of surface engineering
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    • v.21 no.4
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    • pp.176-182
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    • 1988
  • Effects of Cr, Ni and W on the anodic polarization behavior were investigated for Fe-Cr-Ni-W alloys in deaerated 1N HCI solution. Surface films formed on the polarization were analysed using AES, SEM and EDAX. A higerconcentration of tungten was found in the surface oxide film compared to the matrix. It played an importanet role on incresing the stability of the passive film. The presence of an adequate amount of Cr was essential to increase the pitting resistance of the alloys in acid chloride media. Under 12 wt%cr,alloys containing 6wt%W did not exhidit any passivity at all. The main role of Ni was to control the microstructure rather than to modify the corrosion resistance. In 23 cr-14Ni-^W alloy, the duplex microstructure of ferrite($\delta$-phase) in an austenic matrix was developed. The reson why proferred pitting appeared in austenite and ferrite/austenite interface was that ferrite had more amount of Cr and W than austenite.

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Long-term Stability Optimization of Dynamic Spectroscopic Ellipsometery based on Dual-wavelength Calibration (이중 파장 보정방법 기반 다이나믹 분광타원편광계의 안정도 최적화)

  • Choi, Inho;Kheiryzadehkhanghah, Saeid;Choi, Sukhyun;Hwang, Gukhyeon;Shim, Junbo;Kim, Daesuk
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.3
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    • pp.178-183
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    • 2021
  • This paper describes a dynamic spectroscopic ellipsometry based on dual-wavelength calibration. DSE provides ellipsometric parameters at rates above 20 Hz, but the interferometer's sensitivity to temperature makes it difficult for that proposed system to maintain stable 𝜟k over long periods of time. To solve this problem, we set up an additional path in the DSE to perform simulations of the polarization phase calibration method using dual wavelengths. Through simulation, we were able to eliminate most of the polarization phase error and maintain a stable 𝜟k in the long-term stability experiment for 10 hours. This is the result that the 𝜟k stability of the proposed system is improved tens of times compared to the existing system.

Effects of Godulbaegi Extracts on the Stability and Fluidity of Phospholipid Liposomal Membranes (고들빼기 추출물이 인지질막 Liposome의 안정성 및 유동성에 미치는 영향)

  • 배송자;노승배;정복미
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.3
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    • pp.508-517
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    • 1998
  • We investigated the effects of godulbaegi extracts on the physiochemical properties of biological membranes as membrane stability and fluidity employing the phospholipid liposomal membrances as a biomembrane-mimetic system. The addition of the godulbaegi extracts to the phospholipid exterted great effects stagbilized the barrier function of the liposomal membranes in proportion to the concentration of the additive and significantly increased the membranes fluidity. The values of the fluorescence polarization of 1,6-diphenyl 1,3,5-hexatriene (DPH) decreased gradually as the temperature increased, and decreased abruptly near the phase transition temperature (Tm) of the liposome from gel to liquid crystalline state as usual. These results suggest that the activities of the godulbaegi extracts to enhance the stability and fluidity of the liposomal membranes have implication in their biological activities.

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