• Journal of Korean Society on Water Environment
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• v.23 no.2
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• pp.244-250
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• 2007

This study was carried out to obtain the optimum design factors for an eletrolytric flotation reactor. When the effluent of the leachate treatment facility was treated under the condition of 10 volts, 30 minutes, at the Al-Al electrode system; COD removal efficiency was 45%, and total phosphorus removal efficiency was 98%. The high removal efficiency was caused by the fact that phosphate was removed by leaching $Al^{3+}$ from two electrodes. The leachate containing high ammonium nitrogen concentration was treated by a batch test under the condition of 60 minutes reaction time and added chloride ion; ammonium nitrogen removal efficiency was 89%. This high efficiency was affected by added chloride ion to wastewater. To find the optimum current density and voltage of the leachate containing chloride ion (ratio of $Cl^-/NH_4-N$ is 11) a electrochemical polarization curve was used. These values were found to be $4.5mA/cm^2$ and about 2.1 V, respectively. When C-Al electrode system was used at a batch test, the total nitrogen removal efficiency was increased by 1.8 to 3.3 times, compared to Al-Al electrode system due to high $Cl_2$ gas production.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.8
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• pp.1117-1122
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• 2012

In order to study to apply the fuel cell, the study about the power system design and the load control is needed. However, to experiment the fuel cell need the auxiliary device and the complex control technology. For this reason the simulator is needed and such study is in progress actively. In this paper, the PEMFC (Polymer Electrolyte Membrane Fuel Cell) that is applied the vehicle, the small sized ship was simulated based on LabVIEW. The characteristic of fuel cell simulator was implemented based on a simulation data using the programmable power supply. The I-V characteristic according to various factors and the polarization curve of fuel cell were analysed.

• Journal of the Korean Society for Precision Engineering
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• v.19 no.8
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• pp.77-83
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• 2002

This research aimed at from the establishment of theory on micro electrochemical machining mechanism to the implementation of a practical fabrication system of micro parts. In detail, the mechanism of micro-ECM was investigated with potentiodynamic method and the optimal condition for micro-ECM was selected by voltage-current-time curve with potentiostatic method. From the experimental result, the micro part which has extremely fine surface could be fabricated by use of micro-ECM with point electrode method.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.325-330
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• 2004

Recently, the request for the high strength of material is more and more increased in the area of industrial environment and machinery. To accomplish the high strength of materials, carbonizing treatment, nitrifying treatment, shot-peening method are representatively applied, however, shot-peening method is generally used among the surface processes. Shot peening is a cold working process used to impact Compressive residual stressed in the exposed surface layers. Benefits due to shot peening are increase in resistance to fatigue, stress corrosion cracking, fretting, galling, erosion and closing of pores. In this study, the influence of shot peening on the corrosion was investigated on spring steel immersed in 3.5% NaCl. The immersion test as performed on the two kinds of specimens. Corrsion potential, polarization curve, residual stress and etc, were investigated from experiment results. From test result the effect of shot peening on the corrosion was evaluated. The important results of the experimental study on the effects of shot peened on the environment corrosion of spring steels are as follows; In case of corrosion potential, shot peened specimen shows more activated negative direction as compared with parent mental. Surface of specimen, which is treated with the shot peened is placed as more activated state against inner base metal. It can cause t도 anti-corrosion effect on the base metal.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.06a
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• pp.395-400
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• 2005

The ship hull part is always exposed to severe corrosive environments. Therefore, it should be protected in appropriate ways to reduce corrosion problems. So there are two effective methods in order to protect the corrosion of ship hull. One is the paint coating as a barrier between steel and electrolyte (seawater) and the other is the cathodic protection(CP) supplying protection current. In the conventional design process of the cathodic protection system the required current densities of protected materials have been used. However, the anode position of field or laboratory experiment for obtaining the required current density for CP is significantly different from anode position for real structures. Therefore, the recent CP design must consider the optimum anode position for potential distribution equally over the ship hull. The CP design companies in the advanced countries can obtain the potential distribution results on the cathodic materials by using the computer analysis module. This study would show how to approach the potential analysis in the field of corrosion engineering. The computer program can predict the under protection area on the structure when the boundary condition and analysis procedure are reasonable. In this analysis the polarization curve is converted to the boundary condition in material data.

• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.1
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• pp.159-165
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• 2005

Shot peening can be defined as the process of work hardening of the surface of components by means of propelled stream of spherical shot. Benefits due to shot peening are increase in resistance to fatigue, stress corrosion cracking, fretting, galling, erosion and closing of pores. In this study, the influence of shot peening on the corrosion was investigated on spring steel immersed in $3.5\%\;NaCl$. The immersion test was performed on the two kinds of specimens. Corrosion potential, polarization curve, residual stress and etc. were investigated from experimental results. From test results, the effect of shot peening on the corrosion was evaluated. The important results of the experimental study on the effects of shot peened spring steels on the environment corrosion are as follows; In case of corrosion potential, shot peened specimen shows more activated negative direction as compared with parent metal. Surface of specimen, which is treated with the shot peened, is placed as more activated state against inner base metal. It can cause the anti-corrosion effect on the base metal.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.6 no.4
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• pp.648-662
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• 1996

Electrode surface reaction on glassy carbon and synthesized graphite (PVDF mixed graphite) in sulfuric acid solution is investigated by impedance spectroscopy at cyclic polarization. The redox peak, which may be due to the change of chemical adsorped functional group on electrode surface or oxidation and reduction of oxygen, is represented on glassy carbon and graphite electrode in potentio-dynamic current curve. The oxidation and reduction of these surface functional group on glassy carbon and PVDF mixed graphite have a major affect on the impedance spectrum and Faraday impedance parameter at cyclic polarization.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.10a
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• pp.585-588
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• 2005

The dissolution characteristic of metal shows the different tendency according to the applied electrical potential, the kind of electrolyte and pH value, etc. In the micro electrochemical machining (ECM), unfavorable oxide/passive layer formation and overall corrosion of electrodes must be prevented. The anodic polarization curve of nickel has distinct three dissolution regions, i.e. two active regions and the transpassive dissolution region. In this paper, the stable electrode potentials of workpiece and tool were determined in sulfuric acid and hydrochloric acid solution, respectively. In each solution, different machining property was shown and possible electrochemical reactions were discussed. On the basis of this experiment, the methodology to obtain the proper electrode potential was suggested.

• Journal of Advanced Marine Engineering and Technology
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• v.29 no.6
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• pp.654-661
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• 2005

Copper is a well known alloying element that is used to improve the resistance to general corrosion of stainless steel And also Cu cation have the anti-fouling effect to inhibit adhesion of the marine algae and shellfish to the surface of heat exchanger cooling pipe or outside wall of the ship, Therefore there are some anti-fouling methods such as anti-fouling Paint mixed with copper oxide or MGPS(Marine Growth Preventing System) by using Cu cation dissolved to the sea wather solution. Cu cation can be dissolved spontaneously by galvanic current due to Potential difference between Cu and cooling pipe of heat exchanger with Ti material, which may be one of the anti-fouling designs. In this study the effect of annealing heat treatment to galvanic current and Polarization behavior was investigated with a electrochemical points of view such as measurement of corrosion Potential, anodic polarization curve. cyclic voltammetric curve, galvanic current etc The grain size of the surface in annealed at $700^{\circ}C$ was the smallest than that of other annealing temperatures. and also the corrosion Potential showed more positive potential than other annealing temperatures. The galvanic current between Ti and Cu with annealed at $700^{\circ}C$ was the largest value in the case of static condition. However its value in the case of flow condition was the smallest than the other temperatures. Therefore in order to increase anti-fouling effect by Cu cation, the optimum annealing temperature in static condition of sea water is $700^{\circ}C$, however non- heat treated specimen in the case of flow condition may be desirable.

• Journal of Advanced Marine Engineering and Technology
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• v.29 no.5
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• pp.495-501
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• 2005

Al is a active metal that owes its resistance to a thin, protective, barrier oxide surface layer, which is stable in air and neutral aqueous solution. Thus Al alloys are widely used in architectural trim. cold & hot-water storage vessels and piping. However Al and most of its alloy may corrode with some forms such as pitting corrosion, intergranular corrosion and galvanic corrosion in the case of exposure to various industrial and marine atmosphere. Therefore a correct evaluation of corrosion resistance for their Al and Al alloys may be more important in a economical point of view. In this study. a relative evaluation of corrosion resistance for three kinds of Al alloys such as ALDC2, ALDC3, and ALDC8 series was carried out with electrochemical method. There is a tendency that corrosion potential is shifted to positive or negative direction by alloying components regardless of corrosion resistance. Moreover the data of corrosion properties obtained from cathodic Polarization curve, cyclic voltammogram and AC. DC impedance respectively showed a good correspondence each other against the corrosion resistance but variation of corrosion potential. passivity current density of anodic polarization curve and corrosion current density by Tafel extrapolation and Stern-Geary method didn't correspond with not only each other but also considerably the data of corrosion properties discussed above. Therefore it is suggested that an optimum electrochemical evaluation for corrosion resistance of Al alloy is to calculate the diffusion limiting current density of cathodic polarization curve, impedance of AC or DC and polarization resistance of cyclic voltammogram.