• 제목/요약/키워드: Polarity value

검색결과 107건 처리시간 0.03초

Solvent Effects on the Solvatochromism of 7-Aminocoumarin Derivatives in Neat and Binary Solvent Mixtures: Correlation of the Electronic Transition Energies with the Solvent Polarity Parameters

  • Choi, Jin-Yeong;Park, Eun-Ju;Chang, Seung-Hyun;Kang, Tai-Jong
    • Bulletin of the Korean Chemical Society
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    • 제30권7호
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    • pp.1452-1458
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    • 2009
  • The change in the electronic absorption and emission energy of 7-aminocoumarin derivatives in binary solvent mixtures has been studied. The electronic transition energy along with the Stokes' shift is correlated with the orientation polarizability of the solvent as well as the empirical solvent polarity parameters $E_T$ (30). It is observed that the emission peak shift traces the change of $E_T$ (30) value very closely in binary solvent mixtures. The emission transition more strongly depends on the solvent polarity than the absorption, which indicates the dipole moment gets larger on excitation. From the dependence of the Stokes’ shift of 7-aminocoumarins with the solvent polarity parameters and the ground state dipole moment obtained by the semi-empirical calculations, the excited state dipole moment was estimated. The fluorescence lifetime change of 7-aminocoumarins in binary solvent mixtures was measured and the results are explained in terms of molecular conformation and solvent polarity. The study indicates the empirical solvent polarity $E_T$ (30) is a good measure of microscopic solvent polarity and it probes in general the non-specific solvent interactions.

Extracting Multiword Sentiment Expressions by Using a Domain-Specific Corpus and a Seed Lexicon

  • Lee, Kong-Joo;Kim, Jee-Eun;Yun, Bo-Hyun
    • ETRI Journal
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    • 제35권5호
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    • pp.838-848
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    • 2013
  • This paper presents a novel approach to automatically generate Korean multiword sentiment expressions by using a seed sentiment lexicon and a large-scale domain-specific corpus. A multiword sentiment expression consists of a seed sentiment word and its contextual words occurring adjacent to the seed word. The multiword sentiment expressions that are the focus of our study have a different polarity from that of the seed sentiment word. The automatically extracted multiword sentiment expressions show that 1) the contextual words should be defined as a part of a multiword sentiment expression in addition to their corresponding seed sentiment word, 2) the identified multiword sentiment expressions contain various indicators for polarity shift that have rarely been recognized before, and 3) the newly recognized shifters contribute to assigning a more accurate polarity value. The empirical result shows that the proposed approach achieves improved performance of the sentiment analysis system that uses an automatically generated lexicon.

Compositional rules of Korean auxiliary predicates for sentiment analysis

  • Lee, Kong Joo
    • Journal of Advanced Marine Engineering and Technology
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    • 제37권3호
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    • pp.291-299
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    • 2013
  • Most sentiment analysis systems count the number of occurrences of sentiment expressions in a text, and evaluate the text by summing polarity values of extracted sentiment expressions. However, linguistic contexts of the expressions should be taken into account in order to analyze sentimental orientation of the text meticulously. Korean auxiliary predicates affect meaning of the main verb or adjective in some ways while attached to it in their usage. In this paper, we introduce a new approach that handles Korean auxiliary predicates in the light of sentiment analysis. We classify the auxiliary predicates according to their strength of impact on sentiment polarity values. We also define compositional rules of auxiliary predicates to update polarity values when the predicates appear along with sentiment expressions. This approach is implemented to a sentiment analysis system to extract opinions about a specific individual from review documents which were collected from various web sites. An experimental result shows approximately 72.6% precision and 52.7% recall for correctly detecting sentiment expressions from a text.

플라스틱 필름에 대한 유기 용매의 전이 특성에 관한 연구 (Studies on the Migration behavior of various Printing Ink solvents of plastic films)

  • 안덕준
    • 한국포장학회지
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    • 제6권1호
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    • pp.19-23
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    • 2000
  • The increasing use of plastics in food packaging materials has led to the issue of food-packaging mutual interactions from residues in the plastics. Plastic films are commonly printed by using solvent-based ink to decorate the packaged food for consumer attention. However, the residual solvents can not be completely removed and they can migrate into the contained food which lead to undesirable off-flavors. Partitioning (Kp) of printing ink solvents was studied in two types of plastic films with different chemical structure and polarity. At $25^{\circ}C$, Kp of toluene is higher than that of isopropanol in PP, but isopropanol showed higher Kp value than toluene in EVOH. This showed that polarity had a significant effect on the partitioning of printing ink solvents into the plastic films. Printing solvents had a higher affinity to the polymer with similar polarity than it did to the different one.

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Current Limiting Characteristics of a Flux-Lock Type SFCL for a Single-Line-to-Ground Fault

  • Oh, Geum-Kon;Jun, Hyung-Seok;Lee, Na-Young;Choi, Hyo-Sang;Nam, Gueng-Hyun
    • 조명전기설비학회논문지
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    • 제20권9호
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    • pp.70-77
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    • 2006
  • We have fabricated an integrated three-phase flux-lock type SFCL, which consists of an YBCO($YB_a2Cu_3O_7$) thin film and a flux-lock reactor wound around an iron core of each phase. In order to apply the SFCL in a real power system, fault analyses for the three-phase system are essential. The short-circuit currents were effectively limited by adjusting the numbers of winding of each secondary coil and their winding directions. The flux flow generated in the iron core cancelled out under the normal operation due to the parallel connection between primary and secondary windings. However, the flux-lock type SFCL with same iron core was operated just after the fault due to the flux generating in the iron core. To analyze the current limiting characteristics, the additive polarity winding was compared with the subtractive one in the flux lock reactor. Whenever a single line-to-ground fault occurred in any phase, the peak value of the line current of the fault phase in the additive polarity winding increased up to about 12.87 times during the first-half cycle. On the other hand, the peak value in the subtractive polarity winding increased up to about 34.07 times under the same conditions. This is because the current flow between the primary and the secondary windings changed to additive or subtractive status according to the winding direction. We confirmed that the current limiting behavior in the additive polarity winding was more effective for a single-line-to-ground fault

지구 회전 각속도를 이용한 자이로센서의 방향코사인행렬 극성검증 (Polarity Verification of Direction Cosine Matrix of Gyro Sensor Using The Earth Rotational Rate)

  • 오시환;김진희
    • 항공우주기술
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    • 제10권2호
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    • pp.49-55
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    • 2011
  • 인공위성에 사용되는 센서들의 장착 방향은 보통 방향코사인행렬로 구현되어 있다. 이 방향코사인행렬의 극성검증을 위해서는 센서에 알고 있는 외부 자극을 인가하여 출력되는 응답을 확인하는 방법이 사용된다. 그러나 자이로 센서의 경우에는 인위적인 외부 자극 없이 지구 자전에 의한 회전각속도가 방향코사인행렬의 극성검증을 위한 입력으로 사용될 수 있다. 본 연구에서는 인공위성의 조립 및 시험 단계에서 여러 번 수행되는 자이로 센서의 상태점검 시험결과를 이용하여 자이로 센서의 방향코사인행렬 극성검증을 수행하였다.

정서 단어 부정어가 정서가의 극성 전환 및 약화에 미치는 영향 (The effect of negated emotional words on polarity reversal and weakening value in valence)

  • 이신영;함준석;김미선;방그린;고일주
    • 인지과학
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    • 제23권1호
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    • pp.97-107
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    • 2012
  • 오피니언 마이닝과 정서 분석에 대한 기존 연구에서는 정서 단어에 부정어를 붙일 경우 긍정, 부정의 극성과 값이 뒤바뀐다고 가정하고 부정어를 처리하였다. 그러나 지금까지 정서 단어에 부정어가 발생했을 때 극성이 어느 정도 바뀌는지에 대한 정량적 연구는 없었다. 따라서 본 논문에서는 한국어 정서 단어와 그 부정형에 대해서 정서가와 각성 차원을 측정하였다. 결과, 정서 단어에 부정형이 올 경우 정서가와 각성 차원의 중간 수준을 기준으로 극성을 뒤바꾸고 값은 약 30~50% 약화되었다. 이 결과를 오피니언 마이닝과 정서 분석 연구에서 부정어를 처리하는 기준으로 제시하였다.

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직류 접지극의 전식보호 방법 연구 (Research on Protection Method for Ground Electrode of DC Systems from Corrosion)

  • 정우용;김효성
    • 전력전자학회논문지
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    • 제26권2호
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    • pp.90-95
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    • 2021
  • In contrast to AC grounding systems, the ground electrode in DC systems continuously maintains positive or negative polarity. Ground electrodes with (+) polarity proceeds by oxidation reaction. Thus, the DC current should flow opposite to the polarity of the leakage current flowing through the (+) ground electrode by using a compensation electrode, and the current flowing through the (+) ground electrode can be 0A. However, according to protecting the (+) ground electrode, the compensation electrode corrodes and gets damaged. Thus, the (+) ground electrode must be protected from corrosion, and the service life of the compensation electrode must be extended. As an alternative, the average value of the current flowing through the compensation electrode should be equal with the value of the leakage current flowing through the (+) ground electrode by using the square waveform. Throughout the experiment, the degree of corrosion on the compensation electrode is analyzed by the frequency of the compensation electrode for a certain time. In the experiment, the frequencies of the square waveform are considered for 0.1, 1, 10, 20, 50, 100 Hz, and 1 kHz. Through experiments and analysis, the optimal frequency for reducing the electrolytic damage of the (+) electrode and compensation electrode in an LVDC grounding environment is determined.

폴리에틸렌-n-헥산-벤젠계에 대한 투과속도와 용해도 파라메타 사이의 관계 (The Relationship Between the Permeation Rate and the Solubility Parameter for Polyethylene-n-Hexane-Benzene System in Pervaporation)

  • Rhim, Ji-Won
    • 멤브레인
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    • 제3권3호
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    • pp.136-139
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    • 1993
  • It is well known that the membrane permeation in pervaporation is governed by both the chemical nature of the membrane material and the physical structure of the membrane and also the separation can be achieved by differences in either solubility, size or shape. The solubility of the penerrant in the polymeric membrane can be described qualitively by applying the Hildebrand relation [1] which relates the energy of mixing of the penerrant and the polymer material. Froehling et al. have tried to predict the swelling behavior of polymers for the systems of polyvinylchloride(PVC)-toluene-methanol, PVC-trichloroethylene-nitromethane and PVC-n-butylacetate-nitromethane[2]. The former two systems which do not show the donor/acceptor interactions upon mixing showed the successful results[2]. In addition to this technique, there are several other possible approaches to predict the swelling behaviors of polymers, such as the surface thermodynamic approach[3, 4], the comparison of the membrane polarity with the solvent polarity in terms of Dimroth's solvent polarity value[5].

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Bidirectional Quasi-Cuk DC/DC Converter with Reduced Voltage Stress on Capacitor and Capability of Changing the Output Polarity

  • Asl, Elias Shokati;Sabahi, Mehran
    • Journal of Electrical Engineering and Technology
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    • 제12권3호
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    • pp.1108-1113
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    • 2017
  • In this paper, a bidirectional topology for quasi-Cuk dc/dc converter with capability of zero-voltage and zero-current-switching (ZVZCS) is proposed. The bidirectional quasi-Cuk (BQ-Cuk) converter has different voltage and current transfer ratio, reduced voltage stress on capacitor and capability of changing the output polarity in comparison with conventional bidirectional Cuk converter. In this paper, steady-state analysis of the quasi-Cuk converter with capability of ZVZCS in turn-on is presented. Then, critical inductances for transient from this operation to two new operations are calculated. Next, besides values designing of used elements, maximum and minimum value of their current and voltage are calculated. Finally, experimental results to verify the accuracy of the proposed converter in different operating modes are presented.