• 제목/요약/키워드: Polarity index

검색결과 38건 처리시간 0.025초

역상 액체크로마토그래피에서 벤젠 일치환체들의 머무름 메카니즘에 관한 연구 (제 2 보) (A Study of the Retention Mechanism of the Monosubstituted Benzenes in Reversed-phase Liquid Chromatography (II))

  • 이대운;최용욱;이완
    • 대한화학회지
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    • 제32권2호
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    • pp.135-143
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    • 1988
  • 역상 액체크로마토그래피에서 벤젠 일치환체들의 머무름 메카니즘과 머무름예측을 연구하기 위하여 크로마토 그래피 파라미터로 극성지표(P') 분자량(MW), 치환기 상수(${\pi}$ ) 및 분자간 연결지수$(^1{\chi}^{\nu})$를 머무름 데이터와 관련지어 상관관계를 조사하였다. 벤젠을 기존으로 하여 각 치환체의 크기인자와 비인 상대적 머무름$(log k'_S/k'_B)$과 각 치환체의 극성의비 $(P'_S/P'_B)$ 사이에는 상관관계가 있다. 치환기가 극성인 치환체들은 상관관계가 비교적 좋았으나 비극성 치환기를 갖는 치환체들은 분자량을 함께 고려함으로써 좋은 상관관계를 얻을 수 있다. 또한 상대적 머무름과 극성인자 및 분자량의 상관관계를 다변수 회귀분석으로 구하였다. 문헌적 머무름 자료와 소수성 파라미터로부터 유도된 치환기 상수(${\pi}$)와 분자간 연결지수$(^1{\chi}^{\nu})$ 간에는 메탄올의 이동상에서 가장 좋은 상관관계를 얻었다. $C_{18}$ 컬럼의 미반응된 실란올 기를 끝막음(end capping) 시키지 않은 컬럼에서는 이러한 상관관계가 감소되었다. 벤젠 일치환체들의 머무름과 관련지어 고려할 수 있는 파라미터는${\pi}$, P', $(^1{\chi}^{\nu})$ 및 MW 순으로 그 관련성이 감소됨을 알았다.

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Sparkover Voltage Estimation of Standard Sphere Gaps for Negative Polarity by Calculation of Ionization Index

  • Nishikori, Yasuo;Kojima, Soji;Kouno, Teruya
    • KIEE International Transactions on Electrophysics and Applications
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    • 제4C권2호
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    • pp.45-50
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    • 2004
  • The field utilization factor (equation omitted) (the mean electric field / the maximum electric field) of standard sphere gaps was calculated by the charge simulation method, taking into account the ground plane and shanks. n changes mainly with g/r and slightly with 1$_1$, 1$_2$ and 1, where D=2r is the sphere diameter, g is the gap length, 1$_1$ and 1$_2$, respectively, are the lengths of the upper and lower shank, and t is the shank diameter. Generally, (equation omitted) increases as 1$_1$,1$_2$ and t each becomes larger. IEC standard 60052(2002) limits t$\leq$0.2D 1$_1$$\geq$1D and prescribes A=1$_2$+D+g where A is the height of the spark point on the upper sphere. Therefore, (equation omitted) is the largest when A=9D and the smallest when A=3D. The simple equation of a straight line, (equation omitted)=1- (g/3r), can generally be used as a representative value of (equation omitted) for a wide variety of sphere diameters that are permitted by the IEC standard. The maximum electric field E$_{m}$ at sparkover of standard air gaps has also been calculated by the relation E$_{m}$=V/(equation omitted)g). E$_{m}$ describes a U-curve for g/r, up to the sphere diameter of 1 m. Moreover, for 1.5-m and 2-m diameters and especially .for negative polarity, sparkover voltages have been calculated by integration of the ionization index.index.

Study on the Formation of SiOC Films and the Appropriate Annealing Temperature

  • Oh, Teresa
    • Journal of information and communication convergence engineering
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    • 제9권2호
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    • pp.217-219
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    • 2011
  • As silicon devices shrink and their density increases, the low dielectric constant materials instead of $SiO_2$ film is required. SiOC film as low-k films was deposited by the capacitively coupled plasma chemical vapor deposition and then annealed at $300{\sim}500^{\circ}C$ to find out the properties of the dependence on the temperature and polarity. This study researched the dielectric constant using by the structure of the metal/SiOC film/p-Si, chemical shift, thickness, refractive index and hardness. The trend of reflective index was inverse proportioned the thickness, but the dielectric constant was proportioned it. The dielectric constant decreased with decreasing the thickness and the increment of the refractive index.

Investigation of anti-wear additives for synthetic esters; Amine salts of phosphonic acid

  • Hasegawa, T.;Minami, I.;Kidera, Y.;Hirao, K.;Memita, M.
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.269-270
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    • 2002
  • Antiwear(AW) properties of phoshphonic acid derivatives for trimethylolpropane (TMP) esters were investigated under boundary conditions. AW effect of dialkyl phosphonates depends on polarity of base fluid. They provide good AW performance in less polar TMP esters, whereas their AW effect is not sufficient in polar TMP esters. Amine salts of phosphonic acid were developed as new AW additiνe system for TMP esters. They provide excellent AW performance even in polar TMP esters.

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Formulating for efficacy

  • Johann W. Wiechers;Caroline L. Kelly;Trevor G. Blease;Chris Dederen
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 2003년도 IFSCC Conference Proceeding Book I
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    • pp.457-468
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    • 2003
  • Active ingredients have been around in cosmetics for a long time but have they really resulted in active cosmetic products\ulcorner In order to achieve this, the right active needs to be delivered to the right location at the right concentration for the correct period of time. And the extent (and therefore the concentration) of this delivery depends on the formulation. From a rather theoretical approach based on the polarity of the active ingredient, the stratum corneum and the oil phase, the Relative Polarity Index was established that enables the selection of a suitable emollient for ensuring skin penetration of the active ingredient. Practical examples subsequently show the validity of this approach that demonstrates that one can regulate the delivery of an active molecule (and therefore the efficacy of a cosmetic formulation) by selection and control of the emollient system. Cosmetic formulations are generally quite complex mixtures and subsequent experiments using different emulsifier systems indicated that this component of a cosmetic formulation could also have an impact on steering the active ingredient to the right layer of the skin, although it is too early to be able to derive general rules from this.

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텍스트 감정분석을 이용한 IT 서비스 품질요소 분석 (Analysis of IT Service Quality Elements Using Text Sentiment Analysis)

  • 김홍삼;김종수
    • 산업경영시스템학회지
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    • 제43권4호
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    • pp.33-40
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    • 2020
  • In order to satisfy customers, it is important to identify the quality elements that affect customers' satisfaction. The Kano model has been widely used in identifying multi-dimensional quality attributes in this purpose. However, the model suffers from various shortcomings and limitations, especially those related to survey practices such as the data amount, reply attitude and cost. In this research, a model based on the text sentiment analysis is proposed, which aims to substitute the survey-based data gathering process of Kano models with sentiment analysis. In this model, from the set of opinion text, quality elements for the research are extracted using the morpheme analysis. The opinions' polarity attributes are evaluated using text sentiment analysis, and those polarity text items are transformed into equivalent Kano survey questions. Replies for the transformed survey questions are generated based on the total score of the original data. Then, the question-reply set is analyzed using both the original Kano evaluation method and the satisfaction index method. The proposed research model has been tested using a large amount of data of public IT service project evaluations. The result shows that it can replace the existing practice and it promises advantages in terms of quality and cost of data gathering. The authors hope that the proposed model of this research may serve as a new quality analysis model for a wide range of areas.

Variation of Magnetic Field (By, Bz) Polarity and Statistical Analysis of Solar Wind Parameters during the Magnetic Storm Period

  • Moon, Ga-Hee
    • Journal of Astronomy and Space Sciences
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    • 제28권2호
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    • pp.123-132
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    • 2011
  • It is generally believed that the occurrence of a magnetic storm depends upon the solar wind conditions, particularly the southward interplanetary magnetic field (IMF) component. To understand the relationship between solar wind parameters and magnetic storms, variations in magnetic field polarity and solar wind parameters during magnetic storms are examined. A total of 156 storms during the period of 1997~2003 are used. According to the interplanetary driver, magnetic storms are divided into three types, which are coronal mass ejection (CME)-driven storms, co-rotating interaction region (CIR)-driven storms, and complicated type storms. Complicated types were not included in this study. For this purpose, the manner in which the direction change of IMF $B_y$ and $B_z$ components (in geocentric solar magnetospheric coordinate system coordinate) during the main phase is related with the development of the storm is examined. The time-integrated solar wind parameters are compared with the time-integrated disturbance storm time (Dst) index during the main phase of each magnetic storm. The time lag with the storm size is also investigated. Some results are worth noting: CME-driven storms, under steady conditions of $B_z$ < 0, represent more than half of the storms in number. That is, it is found that the average number of storms for negative sign of IMF $B_z$ (T1~T4) is high, at 56.4%, 53.0%, and 63.7% in each storm category, respectively. However, for the CIR-driven storms, the percentage of moderate storms is only 29.2%, while the number of intense storms is more than half (60.0%) under the $B_z$ < 0 condition. It is found that the correlation is highest between the time-integrated IMF $B_z$ and the time-integrated Dst index for the CME-driven storms. On the other hand, for the CIR-driven storms, a high correlation is found, with the correlation coefficient being 0.93, between time-integrated Dst index and time-integrated solar wind speed, while a low correlation, 0.51, is found between timeintegrated $B_z$ and time-integrated Dst index. The relationship between storm size and time lag in terms of hours from $B_z$ minimum to Dst minimum values is investigated. For the CME-driven storms, time lag of 26% of moderate storms is one hour, whereas time lag of 33% of moderate storms is two hours for the CIR-driven storms. The average values of solar wind parameters for the CME and CIR-driven storms are also examined. The average values of ${\mid}Dst_{min}{\mid}$ and ${\mid}B_{zmin}{\mid}$ for the CME-driven storms are higher than those of CIR-driven storms, while the average value of temperature is lower.

뉴스와 주가 : 빅데이터 감성분석을 통한 지능형 투자의사결정모형 (Stock-Index Invest Model Using News Big Data Opinion Mining)

  • 김유신;김남규;정승렬
    • 지능정보연구
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    • 제18권2호
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    • pp.143-156
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    • 2012
  • 누구나 뉴스와 주가 사이에는 밀접한 관계를 있을 것이라 생각한다. 그래서 뉴스를 통해 투자기회를 찾고, 투자이익을 얻을 수 있을 것으로 기대한다. 그렇지만 너무나 많은 뉴스들이 실시간으로 생성 전파되며, 정작 어떤 뉴스가 중요한지, 뉴스가 주가에 미치는 영향은 얼마나 되는지를 알아내기는 쉽지 않다. 본 연구는 이러한 뉴스들을 수집 분석하여 주가와 어떠한 관련이 있는지 분석하였다. 뉴스는 그 속성상 특정한 양식을 갖지 않는 비정형 텍스트로 구성되어있다. 이러한 뉴스 컨텐츠를 분석하기 위해 오피니언 마이닝이라는 빅데이터 감성분석 기법을 적용하였고, 이를 통해 주가지수의 등락을 예측하는 지능형 투자의사결정 모형을 제시하였다. 그리고, 모형의 유효성을 검증하기 위하여 마이닝 결과와 주가지수 등락 간의 관계를 통계 분석하였다. 그 결과 뉴스 컨텐츠의 감성분석 결과값과 주가지수 등락과는 유의한 관계를 가지고 있었으며, 좀 더 세부적으로는 주식시장 개장 전 뉴스들과 주가지수의 등락과의 관계 또한 통계적으로 유의하여, 뉴스의 감성분석 결과를 이용해 주가지수의 변동성 예측이 가능할 것으로 판단되었다. 이렇게 도출된 투자의사결정 모형은 여러 유형의 뉴스 중에서 시황 전망 해외 뉴스가 주가지수 변동을 가장 잘 예측하는 것으로 나타났고 로지스틱 회귀분석결과 분류정확도는 주가하락 시 70.0%, 주가상승 시 78.8%이며 전체평균은 74.6%로 나타났다.

TBDMS 유도체로서 수용액 시료중의 유기산 미량분석 연구 (Trace Analysis as TBDMS Derivatives of Organic Acids in Aqueous Samples)

  • 김경례;김정한;박형국
    • 대한화학회지
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    • 제34권4호
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    • pp.352-359
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    • 1990
  • 생화학적으로 주요한 유기산들을 신속히 분석 확인할 수 있는 효율적인 가스크로마토그래피 분석법을 개발하였다. 본 방법에서는 고형흡착제로서 Chromosorb P와 용출용매로서 diethyl ether를 사용하여 수용성 시료로부터 유기산을 고체상 추출한 후 triethylamine으로 처리하였다. 생성된 유기산들의 triethylammonium염을 직접 tert-butyldimethylsiyl 유도체로 전환시킨 후 극성이 다른 DB-5와 DB-1701 두 capillary column 분석 후 측정된 각 유기산들의 retention index (RI)와 area ratio (AR)값을 가지고 컴퓨터 RI library조사와 AR 비교를 하였을 때 신속히 유기산을 동정할 수 있었다. 본 방법은 다양한 복합 시료들의 유기산 분석을 하는데 응용될 수 있을 것이다.

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Nonconstant modulus 신호의 적응 등화를 위한 SE-MMA와 QE-MMA 알고리즘 성능 비교 (Performance Comparison of SE-MMA and QE-MMA for Adaptive Equalization in Nonconstant modulus signal)

  • 임승각
    • 한국인터넷방송통신학회논문지
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    • 제17권2호
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    • pp.105-111
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    • 2017
  • 본 논문은 16-QAM과 같은 스펙트럼 효율적인 nonconstant modulus 신호 전송에서 채널에 의한 부호간 간섭을 보상하기 위한 SE-MMA (Signed Error-Multiple Modulus Algorithm)와 QE-MMA (Quantized Error-Multiple Modulus Algorithm) 적응 등화 알고리즘의 성능을 비교하였다. 기존 MMA 적응 등화기의 탭 계수 갱신시 오차 신호가 필요하게 되는데, SE-MMA는 연산량을 줄이기 위해 오차 신호의 극성만을 이용하며, QE-MMA는 오차 신호의 극성에 유한 비트의 2의 승수 양자화 성분까지 고려하게 되므로 이로 인하여 서로 상이한 등화 성능을 갖게 된다. 이들의 성능을 비교하기 위하여 동일한 채널과 환경에서 등화기 출력 성상도, 잔류 isi, 최대 찌그러짐과 MSE, SER을 적용하여 컴퓨터 시뮬레이션을 수행하였으며, 결과 모든 성능 지수에서 QE-MMA가 SE-MMA보다 우월함을 확인하였다.