• 제목/요약/키워드: Platium

검색결과 9건 처리시간 0.027초

킬레이트 수지에 의한 몇가지 금속이온의 분리 농축에 관한 연구 (Separation and concentration of some ions by chelate resin)

  • 차기원;박찬일;유정숙;황화자;장병두
    • 분석과학
    • /
    • 제17권3호
    • /
    • pp.278-281
    • /
    • 2004
  • The separation and concentration method of gold(III) and platium(IV) ions from other ions has been investigated using chelate resin, Amberlite IRC 718 in the mixed solution. The adsorption and desorption capacity of ions on the chelate resin in mixed solution were measured at room temperature. Using the data, gold(III) and platium(IV) ions were separated and concentrated in the ions solution.

한국산 김중의 미량금속 함량 조사연구 (A Study of the Trace Elements in Sea-weed (Dried Laver))

  • 윤혜경;노영수
    • Environmental Analysis Health and Toxicology
    • /
    • 제12권3_4호
    • /
    • pp.67-73
    • /
    • 1997
  • This study was carried out to investigate the contents of heavy metals such as iron, copper, lead, cadmium, magnesium, platium in connection with water pollution in sea weed (dried laver) collected from the west, south, south- west, and east coasts of Korea. The results of the study are as follows; Iron was shown the highest value (1.280ppm) in the wild laver from the south coast. Copper was detected in larger qauntities (0.169 ppm) in green laver than in any other kinds of laver observed in this study. Lead was detected in larger quantities (0.195ppm) in the usual laver and green laver from the south-west coast as compared with the other coasts. Although cadmium and platium was also detected from every kind of laver, the concentrations were not over the allowance of the residual.

  • PDF

Spectrometer for the Study of Angle-and Energy-Resolved Reactive Ion Scattering at Surfaces

  • S-J. Han;C.-W. Lee;C.-H. Hwang;K.-H. Lee;M. C. Yang;H. Kang
    • Bulletin of the Korean Chemical Society
    • /
    • 제22권8호
    • /
    • pp.883-888
    • /
    • 2001
  • We describe an ion-surface scattering apparatus newly developed to investigate the reactive scattering process of low-energy alkali-metal ions at surfaces. The apparatus consists of an alkali-metal ion gun that is rotatable by 360°, a quadrupole mass spectrometer (QMS) with an ion energy analyzer, a sample manipulator with a heating-and-cooling stage, and an ultrahigh vacuum (UHV) chamber that houses these components. Preliminary experimental results obtained from the apparatus are presented on angular and energy distributions of the ions scattered from clean Pt(111) and water-adsorbed Pt surfaces.

폐연료전지로부터 회수된 희유금속에서 불순물 제거 특성 (Properties of Impurities Removal for Reclaiming Valuable Metal from Wasted Fuel cell)

  • 김영애;권현지;구정분;곽인섭;신장식
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
    • /
    • pp.198.1-198.1
    • /
    • 2010
  • 고분자전해질 연료전지(PEMFC)의 핵심부품인 스택의 MEA는 전극과 멤브레인 전해질, GDL(Gas Diffusion Layer)로 구성되며, 전극은 Anoth극과 Cathod극으로 나뉘어 각각의 전극 특성에 적합한 전극촉매를 적용하게 된다. Anoth극과 Cathod극은 탄소 지지체 위에 원하는 사양의 희유금속이 도포되어 존재하는데 이들 희유금속은 그 희귀성으로 인해 사용 후 반드시 재사용되어야 한다. 사용된 전극에서의 희유금속 회수는 산침출, 불순물제거, 추출, 탈거 공정으로 이루어지며, 산침출 시 산화제로 사용된 NaOCl로 인한 침출용액 내의 Na+ 이온의 증가는 불순물제거 공정에 의해 반드시 제거되어야 한다. 따라서 본 연구에서는 CCG 방식으로 전극촉매를 GDL에 코팅한 MEA로부터 백금족 희유금속을 회수 시 MEA에 포함되어 있는 소량의 불순물을 제거하고자 한다.

  • PDF

측온 저항체의 Pt 박막 특성 연구 (Study on Pt thin film property of Resistance Temperature Detect)

  • 박정호;지미정;최병현;이정민;주병권
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
    • /
    • pp.29-29
    • /
    • 2008
  • Platinum Thin films were deposited on $Al_2O_3$ by Rf magnetic Sputtering. The physical and electrical characteristics of these films were analyzed under various deposition conditions(Ar gas pressure, input power, substrate temperature.) and annealing condition. The deposition rate was increased with increasing the input power but not increased linear. In the other factor, The Pt thin films property was associated with resistance. so lower resistance had more and more good Pt thin films condition. For the purpose of this study, we will get the best Pt thin film characteristics.

  • PDF

촉매에 의한 가솔린 기관배기중 CO와 HC 농도저감에 관한 실험적 연구 (Experimental study on the reduction of CO and HC concentrations in the exhaust gas of gasoline engine by catalysts)

  • 조진호;서정일;조종철
    • 오토저널
    • /
    • 제4권1호
    • /
    • pp.46-55
    • /
    • 1982
  • When an oxidizing catalytic converter which makes use of platium as a catalyst is employed by means if emission control of CO and HC gasoline engine, the effects of important factors for the purification efficiency, i.e engine speed and secondary air rate, on the reduction of CO and HC concentrations in the exhaust gas are studied experimentally. In the experiment, gasoline and LPG are used as a fuel, and the purification efficiency is examined and the results of both cases are compared with each other. The experimental results showed that the purification efficiency in the case of LPG is usually higher than that of gasoline, and the optimum values of engin speed and secondary air rate for maximum purification efficiency exist in common on both cases.

  • PDF

상대전극을 스퍼터링 증착한 염료 감응형 태양전지의 새로운 디자인 (The New Design of Dye-Sensitized Solar Cell Adopted by Sputter Deposition of Counter Electrode)

  • 김희제;송건주;전진안;이동윤;김휘영;최진영
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2006년도 춘계학술대회
    • /
    • pp.154-157
    • /
    • 2006
  • The counter electrode widely used in DSCs (Dye-sensitized Solar Cells) is constructed of conducting glass substrates coated with Pt films, where the platium acts as a catalyst. Pt counter electrodes in DSCs are one important component. It is expected that characteristics of Pt electrodes strongly depend on fabrication process and its surface condition. In this study, Pt counter electrode surface of DSC is deposited by reactive RF magnetron sputtering under the conditions of Ar 5mtorr, RF power of 120w and substrate temperature of $100^{\circ}C$. Surface morphology of Pt electrodes was investigated by FE-SEM and AFM. And this paper shows our recent results and technology to fabricate the new designed cell with Pt electrodes deposited by sputtering method. We have achieved fill factor 65% and photoelectric conversion efficiency around 2.6% as the best results of new designed DSCs structure.

  • PDF

물아닌 용매속에서의 요오드의 전기화학적 환원 (Electrochemical Reduction of Iodine in Non-aqueous Solvents)

  • 박두원;최원형
    • 대한화학회지
    • /
    • 제19권2호
    • /
    • pp.104-115
    • /
    • 1975
  • 요오드의 전기화학적 환원과정을 여러가지 특성을 가진 물아닌 용매 속에서 polarography, chronopotentiometry, cyclic voltammetry, controlled potential coulometry 등의 전기분석적 방법을 이용하여 적하수은전극, 백금, 금 및 백금아말감전극등을 사용하여 상세히 조사하였다. 메탄올, 에탄올, 이소프로판올 및 피리딘과 같은 양쪽성 용매 속에서는 $I_2{\longrightarrow}I^-$의 I단계 환원과정을 거치며 아세톤, 디메틸포름아미드, 메틸에틸케톤, 디메틸술폭시드, 아세토니릴과 같은 반양성자 용매속에서는 $I_2{\longrightarrow}I_3^-{\longrightarrow}I^-$의 2단계 환원과정을 거쳤다. 적하수은전극, 고인 수은전극, 백금, 금 그리고 백금아말감전극등 전극조건을 다르게 하였을 때에도 $^'I_2$의 환원과정은 같았으며 사용한 모든 전극에서 확산지배적이었다. 반양성자용매에 물을 첨가하여 그 영향을 걸토한 결과 물의 첨가량이 약 $50v/v{\%}$ 이상일때 2단계의 환원과정이 1단계의 환원과정으로 줄어들었다. 또 chronopotentiometric data와 Send의 식으로부터 계산한 각 용매 속에서의 요오드의 확산계수는 $D_{I2}^{AN}=5.96{\times}10^{-6}cm^2/sec,\;D_{13-}^{AN}=9.63{\times}10^{-6}cm^2/sec,\;D_{I2}^{MeOH}=5.30{\times}10^{-6}cm^2/sec$이였다. 전기화학적 환원과정의 stoichiometry를 알아 보고저 controlled potential coulometry로 使用하였으며, 얻은 생성물은 은법적정으로 확인 및 정량하였다.

  • PDF