• Title/Summary/Keyword: Platinum Electrode

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The Improvement of Sensing Performance of ISFET Glucose and Sucrose Sensors by Using Platinum Electrode and Photo-crosslinkable Polymers (백금전극과 감광성 고분자를 이용한 ISFET 포도당 및 자당센서의 감지성능 개선)

  • Cho, Byung-Woog;Jang, Won-Duk;Kim, Chang-Soo;Park, Lee-Soon;Sohn, Byung-Ki
    • Journal of Sensor Science and Technology
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    • v.4 no.4
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    • pp.23-28
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    • 1995
  • The ISFET glucose and sucrose sensors containing platinum electrode and photopolymeric enzyme membrane were fabricated. The platinum working electrode was used for the electrolysis of hydrogen peroxide, which was the other product of the enzyme reaction, to improve sensing characteristics of the sensors. In order to improve response time, photo-crosslinkable polymer(PVA-SbQ) was used to the matrix for the enzyme immobilized membrane. The characteristics of glucose and sucrose sensors were investigated according to the variation of platinum electrode area. The response time was about $3{\sim}5$ minutes and determinations of glucose and sucrose in the range of about $30{\sim}300mg/dl$ could be possible.

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Comparative properties for serial-parallel connection of DSC with CNT and pt counter electrodes (CNT와 Pt 상대전극을 가지는 염료감응형 태양전지의 직렬 ${\cdot}$ 병렬 연결에 따른 특성비교)

  • Choi, Jin-Young;Hong, Ji-Tae;Kim, Mi-Jeong;Lee, Yong-Chul;Kim, Hee-Je
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.335-338
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    • 2007
  • Cost effectiveness is an important parameter for producing DSSCs as compared to the widely used conventional silicon based solar cells. A fluorine-doped tin oxide (FTO) substrate coated with a catalytic amount of platinum is used as counter electrode in dye-sensitized solar cell. Carbonaceous materials are quite attractive to replace platinum due to their high electronic conductivity, corrosion resistance towards $I_{2}$, good catalytic effect and low cost. In this paper, the unit DSSCs with Pt and CNT as a counter electrode were connected in series-parallel externally, then the current-voltage curves were investigated to find out the connection characteristics of the DSSC with CNT counter electrode. The connection characteristics of the DSSC with CNT counter electrode is superior to that of the DSSC with Pt counter electrode. And a parallel connection of the DSSC with CNT counter electrode has higher efficiency than a series connection of that.

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Comparison of Antimicrobial Activity of Electrolyzed Water Using Various Electrodes against Biofilm of Oral Pathogens

  • Yoo, Yun S;Shin, Hyun-Seung;Lee, Sung-Hoon
    • International Journal of Oral Biology
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    • v.40 no.3
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    • pp.135-141
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    • 2015
  • Biofilms of oral microbes can cause various diseases in the oral cavity, such as dental caries, periodontitis and mucosal disease. Electrolyzed water generated by an electric current passed via water using a metal electrode has an antimicrobial effect on pathogenic bacteria which cause food poisoning. This study investigated the antimicrobial activity of electrolyzed waters using various metal electrodes on the floatage and biofilms of oral microbes. The electrolyzed water was generated by passing electric current using copper, silver and platinum electrodes. The electrolyzed water has a neutral pH. Streptococcus mutans, Porphyromonas gingivalis and Tannerella forsythia were cultured, and were used to form a biofilm using specific media. The floatage and biofilm of the microbes were then treated with the electrolyzed water. The electrolyzed water using platinum electrode (EWP) exhibited strong antimicrobial activity against the floatage and biofilm of the oral microbes. However, the electrolyzed water using copper and silver electrodes had no effect. The EWP disrupted the biofilm of oral microbes, except the S. mutans biofilm. Comparing the different electrolyzed waters that we created the platinum electrode generated water may be an ideal candidate for prevention of dental caries and periodontitis.

Fabrication and Test of Micro Direct Methanol Fuels using Platinum Sputtered Microcolumn Electrodes with a Limited Fuel Source (백금 촉매가 증착된 미소돌기 전극과 유한 연료를 가지는 극소형 직접메탄을 연료전지의 제작 및 성능 평가)

  • 서영호;조영호
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.4
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    • pp.218-224
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    • 2004
  • We present a miniature Direct Methanol Fuel Cell (micro-DMFC) using platinum sputtered microcolumn electrodes with a limited amount of fuel. We use the microcolumn electrode in order to improve the power density of the micro-DMFC that consists of two electrodes and polymer electrolyte. We also design the built-in fuel chamber in the anode for the portable electronics applications. We design and fabricate both microcolumn and planar electrodes, having an identical projective area of 5mm${\times}$5mm. The diffusion current density of the microcolumn electrode is 1.73 times higher than that of the planar electrode at electrode potential of 1.1V in the half-cell test. The micro-DMFC based on the microcolumn electrodes shows the maximum power of 10.8$\pm$7.54㎼(43.23$\pm$0.16㎼/$\textrm{cm}^2$) at the projective area of 5mm${\times}$5mm, while the planar electrode micro-DMFC shows the maximum power of 0.81$\pm$0.42㎼(3.24$\pm$1.68㎼/$\textrm{cm}^2$) at the same projective area. The micro-DMFC based on the microcolumn electrodes shows 13 times higher power density that the micro-DMFC based on the planar electrodes does.

Electrode Performance of Pt-Cr-Ni Alloy Catalysts for Oxygen Electrode in Polymer Electrolyte Fuel Cell (고분자전해질형 연료전지에서 산소극을 위한 백금-크롬-니켈 합금촉매의 전극특성)

  • Sim, Jung-Pyo;Lee, Hong-Gi
    • Korean Journal of Materials Research
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    • v.10 no.12
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    • pp.831-837
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    • 2000
  • To improve the catalytic activity of platinum on polymer electrolyte fuel cell(PEFC), platinum was alloyed with cobalt and nickel at various temperature. By XRD, it was observed the crystal structure of alloy catalysts were the ordered face centered cubic(f.c.c) due to the superlattice line at $33^{\circ}$. As heat-treatment temperature was increased, the particle size of alloys also were increased and the crystalline lattice parameters were decreased. According to the results from mass activity, specific activity and Tafel slope measured by cell performance test and cyclic voltammogram, the catalyst activities of alloys are higher than that pure platinum.

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The Characteristic of Prepared Electrode Catalyst and MEA using CNF and CNT (CNT 및 CNF를 이용하여 제조된 전극 촉매 및 막 전극 접합체의 특성)

  • 임재욱;최대규;류호진
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.1
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    • pp.59-64
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    • 2004
  • The performance of fuel cell electrode depends on the characteristics of the catalyst support material. This paper deals with the use of CNF(carbon nanofibre) and CNT(carbon nanotube) as platinum catalyst support. The CNF and CNT were synthesized with catalyst treated by mechanochemical process and were prepared by chemical vapor deposition (CVD) method. The platinum supported on CNF and CNT for polymer electrolyte membrane fuel cell (PEMFC) application. In result, the best I-V characteristic was verified by the prepared MEA(membrane electrode assembly) from twisted CNF that had a diameter of 65 nm.

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Anodic Oxidation of Iodate to Periodate by Lead Peroxide Anode (전착과산화납양극에 의한 옥소산염 전해산화)

  • Chong Woo Nam;Hak Joon Kim
    • Journal of the Korean Chemical Society
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    • v.15 no.6
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    • pp.324-329
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    • 1971
  • In order to evaluate the mechanism of electrolytic oxidation of iodate and to determine the optimum conditions for the electrolysis, studies were made using the cells without diaphragm and the lead peroxide anode. Results are summarized as followings: 1) Current density vs. anode potential curve by lead peroxide electrode had the different limiting current densities from platinum electrode and was more positive than platinum electrode. 2) Additions of potassium bichromate in the electrolyte contribute to maintain high current efficiency. 3) In the acid and alkaline regions, the current efficiencies decreased by reduction of iodate and discharge of hydroxyl ion, so maximum current efficiency was shown at pH 7. 4) Higher current density lowered the current efficiency in the region of 60-80% conversion of iodate. 5) Influence of the conversion on current efficiency in the region of 60-80% conversion of iodate.

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Mechanistic Studies on the Formation of Soluble Intermediate during the Electrochemical Nucleation of Lead Dioxide

  • Hwang Euijin;Cho Keunchang;Kim Ho Il;Kim Hasuck
    • Bulletin of the Korean Chemical Society
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    • v.15 no.12
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    • pp.1054-1058
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    • 1994
  • Different behavior on the formation of soluble intermediate was observed depending on the substrate employed during the nucleation of lead dioxide from plumbous ion using a rotating ring-disk electrode. It was found that no soluble intermediate was formed at glassy carbon electrode, while the presence of soluble intermediate could be detected at platinum substrate. From the different anodic behavior of two substrates, the formation of a probable Pb(Ⅲ) soluble intermediate was suggested. A most probable nucleation mechanism at the platinum substrate involving a second order chemical reaction was derived on the basis of rotating disk electrode experiments.

New Micro Rotating Mercury Electrode for Voltammetry (전류전압법을 위한 미크로 회전수은 전극)

  • Choe, Gyu-Won
    • Journal of the Korean Chemical Society
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    • v.11 no.3
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    • pp.81-84
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    • 1967
  • A simple rotating micro mercury electrode is constructed in such a way that the mercury surface can be renewed quite easily with reasonable reproducibility. It consists of a glass capillary of about 1mm diameter connected to a mercury filled tube by means of a ground joint that allows mercury flow at a particular relative position only, and the electrical connection between the two parts is made by a platinum wire fused in the bottom of the latter. Thus the mercury surface exposed at the tip of the capillary replaces the platinum tip of the usual platinum micro electrode; however, the capillary has to be bent so that the tip directs upwards. It has been found to be a convenient electrode in the amperometric titration in strongly acidic media. Furthermore, it has been advantageously used in the alternating-current polarography because of its smaller electrical resistance than the ordinary dropping mercury electrodes. It also can be used as a stationary mercury electrode in fast scanning polarography.

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