• Title/Summary/Keyword: Pitting Corrosion

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Phosphorus Removal by Aluminium Ion Generated with the Pitting Corrosion of Aluminium (알루미늄의 부식으로 발생한 알루미늄 이온에 의한 인 제거)

  • Cheong Kyung-Hoon;Jung Oh-Jin
    • Journal of Environmental Science International
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    • v.8 no.6
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    • pp.705-710
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    • 1999
  • The fundamental experiments on the phosphorus removal from water were carried out by the batch and continuous reactors which used aluminium and copper plate. In this systems, the phosphorus was removed by aluminium ion generated with the electrochemical interaction (pitting corrosion) of aluminium and copper. In the batch experiments, the efficiencies of phosphorus removal increased when the surfaces of aluminium and copper plate were brushed. The phosphorus removal by aluminium ion was affected the copper plate and NaCI in this system. The optimal pH values were 5 and 6 for the phosphorus removal. The efficiency of phosphorus removal increased with increasing NaCI concentration, surface area of aluminium and copper plate. The $CUSO_4{\cdot}5H_2O$ instead of copper plate could be used as Cu source. The effluent $PO_4-P$ concentration as low as 2 $mg/{\ell}$ could have been obtained during the continuous experiment at HRT of 48 hrs.

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Effect of Solution Annealing Heat Treatment on the Localized Corrosion Resistance of Inconel 718 (Inconel 718의 국부 부식 저항성에 미치는 용체화 열처리의 영향)

  • Yoonhwa Lee;Jun-Seob Lee;Soon Il Kwon;Jungho Shin;Je-hyun Lee
    • Corrosion Science and Technology
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    • v.22 no.5
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    • pp.359-367
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    • 2023
  • The localized corrosion resistance of the Ni-based Inconel 718 alloy after solution heat treatment was evaluated using electrochemical techniques in a solution of 25 wt% NaCl and 0.5 wt% acetic acid. Solution heat treatment at 1050 ℃ for 2.5 hours resulted in an increased average grain diameter. Both Ti carbides (10 ㎛ diameter) and Nb-Mo carbides (1 - 9 ㎛ diameter) were distributed throughout the material. Despite heat treatment, the shape and composition of these carbides remained consistent. An increase in solution temperature led to a decrease in pitting potential value. However, the pitting potential value of solution heat-treated Inconel 718 was consistently higher than that of as-received Inconel 718 at all tested temperatures. Localized corrosion initiation occurred at 0.4 VSSE in a temperature environment of 80 ℃ for both as-received and solution heat-treated Inconel 718 alloys. X-ray photoelectron spectroscopic analysis indicated that the composition of the passive film formed on specimen surfaces remained largely unchanged after solution heat treatment, with O1s, Cr2p3/2, Fe2p3/2, and Ni2p3/2 present. The difference in localized corrosion resistance between as-received and solution heat-treated Inconel 718 alloys was attributable to microstructural changes induced by the heat treatment process.

The Effect of Annealing Heat Treatment Affecting Hardness and Corrosion Resistance of ALDC 12 Al Alloy (ALDC 12종의 경도와 내식성에 미치는 어닐링 열처리의 영향)

  • Cho, Hwang-Rae;Lee, Myeong-Hoon;Lee, Seung-Yeol;Moon, Kyung-Man
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.95-96
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    • 2006
  • ALDC 12 Al alloy is often corroded with some forms such as pitting corrosion, intergranular corrosion, and galvanic corrosion etc., in case of severe corrosion environment like seawater Annealing heat treatment was performed to improve the corrosion resistance of ALDC 12. Hardness was decreased with increasing of annealing temperature, however its corrosion resistance was clearly improved with increasing of annealing temperature.

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Study on Environment Corrosion Characteristics of Automobile Component Materials (차량용 부품재료의 환경부식 특성 연구)

  • Park, Keyoung-Dong;Shin, Yeong-Jin
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.5 no.3
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    • pp.86-91
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    • 2006
  • The compressive residual stress, which is inducing by shot peening process, has the effect of increasing the intrinsic fatigue strength of surface and therefore would be beneficial in reducing the probability of fatigue damage. However, it was not known that the effect of shot peening in corrosion environment. In this study, the influence of shot peening and corrosion condition for corrosion property were investigated on immersed in 3.5% NaCl, 10% HNO3 + 3% HF, 6% $FeCl_3$. The immersion test was performed with two kind of specimen. The immersion periods was performed 150days. Corrosion potential, weight loss were investigated from experimental results. From test results, the effect of shot peening on the corrosion characteristics was evaluated.

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Effect of ICCP Potential with Electrolyte on Corrosion and Discolor of Silver (은의 부식 및 변식에 미치는 전해질 용액에 따른 ICCP 전압의 영향)

  • Shin, Byung-Hyun;Kim, Do-Hyung;Chung, Won-Sub
    • Journal of the Korean institute of surface engineering
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    • v.53 no.5
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    • pp.207-212
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    • 2020
  • Silver is an inexpensive precious metal and is used in various jewelry in Asia. Although silver has high potential, it has corrosion resistance that is vulnerable to boiling sulfuric acid and nitric acid. So, silver research is needed to prevent the corrosion with environment. But silver corrosion is not studied. sulfuric acid make the uniform corrosion and chloride ion make the pitting corrosion. ICCP inhibits the corrosion because it offset electrons. This study used a potential from - 4 V to 4 V to check the effect of potential. Corrosion rate is lowet at -1 V.

Study on the Damage Behavior of 304 Stainless Steel for Gas Boiler with Specific Resistance (비저항에 따른 가스보일러용 304스테인리스강재의 손상거동에 관한 연구)

  • Yun, Byoung-Du;Lim, Uh-Joh;Jeong, Ki-Cheol
    • Journal of the Korean Institute of Gas
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    • v.9 no.4 s.29
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    • pp.6-10
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    • 2005
  • This paper was studied on the damage behavior of stainless steel (STS 304) for gas boiler with specific resistance. The electrochemical polarization test of STS304 for gas boiler was carried out. And the anodic polarization and damage aspect, such as pitting corrosion, was considered. With being low specific resistance, the passive current density of STS 304 increases, passive region and pitting potential is low. Also, the patting aspect of STS304 In specific resistance $74{\Omega}{\cdot}m$ water little appears, the pitting number increases and the damage behavior, such as pitting aspect, gradually grow bigger with being low specific resistance.

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Galvanic Corrosion of AZ31 Mg Alloy Contacting with Copper

  • Phuong, Nguyen Van;Moon, Sungmo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.151.1-151.1
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    • 2017
  • This work studied the corrosion behavior of AZ31 Mg alloy galvanically coupled with Cu during immersion in 0.1 and 0.5 M NaCl solutions by in-situ observation and galvanic corrosion current measurement using a zero resistance ammeter. The corrosion behavior of AZ31 Mg alloy was also studied by salt spray test. The average galvanic corrosion density during 2 h immersion in 0.1 NaCl solution was found to decrease as an exponential function with increasing the surface area ratios between AZ31:Cu or with increasing the distance between AZ31 and Cu. The corrosion of electrodeposited Cu on AZ31 Mg alloy was concentrated at the area next to Cu (about 5 mm for immersion test and 2 mm for salt spray test) and pitting corrosion was accelerated at the area beyond the severely corroded area by the galvanic coupling effect.

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