• Title/Summary/Keyword: Pitch Fiber

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Conductive Properties of Thermoplastic Carbon Fiber Reinforced Plastics Highly Filled with Carbon Fiber Fabrics and Conductive Carbon Fillers (탄소섬유 직물 및 전도성 탄소 필러가 고충진 된 열가소성 탄소섬유강화플라스틱의 전도 특성)

  • Kim, Seong Yun;Noh, Ye Ji;Jang, Ji-un;Choi, Seong Kyu
    • Composites Research
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    • v.34 no.5
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    • pp.290-295
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    • 2021
  • The application of lightweight structural composites to automobiles as a solution in line with global fuel economy regulations to curb global warming is recognized as a megatrend. This study was conducted to provide a technical approach that can respond to the issue of replacing parts that require conductive properties to maximize the application of thermoplastic carbon fiber reinforced plastics (CFRPs), which are advantageous in terms of repair, disposal and recycling. By utilizing the properties of the low-viscosity polymerizable oligomer matrix, it was possible to prepare a thermoplastic CFRP exhibiting excellent impregnation properties while uniformly mixing the conductive filler. Various carbon-based conductive fillers such as carbon black, carbon nanotubes, graphene nanoplatelets, graphite, and pitch-based carbon fibers were filled up to the maximum content, and electrical and thermal conductive properties of the fabricated composites were compared and studied. It was confirmed that the maximum incorporation of filler was the most important factor to control the conductive properties of the composites rather than the type or shape of the conductive carbon filler. Experimental results were observed in which it might be advantageous to apply a one-dimensional conductive carbon filler to improve electrical conductivity, whereas it might be advantageous to apply a two-dimensional conductive carbon filler to improve thermal conductivity. The results of this study can provide potential insight into the optimization of structural design for controlling the conductive properties of thermoplastic CFRPs.

The Numerical Analysis on Insulation Performance with Respect to the Envelope Geometries and Array of Evacuated Powder Panel in Rigid Foam/Evacuated Powder Composite Panels (혼합초단열재에서 진공분말패널의 외피형상 및 패널배열에 따른 단열성능해석)

  • Hong, J.K.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.4
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    • pp.497-509
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    • 1996
  • Evacuated powder insulations have long been known to have better thermal performance than existing commercially available insulators, such as fiber glass and CFC-blown foam. To make a composite powder panel, a series of individually evacuated panels was encapsulated in a rigid closed cell foam matrix. The panels were encapsulated in a thin glass sheet barrier to preserve the vacuum. The thermal conductivity of the individual panel was found to be $0.0062W/m^{\circ}K$ by experiment and the polyurethane foam above had a thermal conductivity of $0.024W/m^{\circ}K$. In this study, numerical analysis using finite element method was carried out to investigate insulation performance of rigid foam/evacuated powder composite panel with respect to panel geometries such as panel pitch, panel aspect ratio and panel area ratio. Numerical analysis has indicated that more optimal vacuum panel geometries, much lower overall thermal conductivities can be achieved.

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Yield enhancement of matrix precursor in short carbon fiber reinforced randomly oriented carbon/carbon composite

  • Raunija, Thakur Sudesh Kumar;Sharma, Sharad Chandra;Verma, Anil
    • Carbon letters
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    • v.19
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    • pp.57-65
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    • 2016
  • Isroaniso matrix precursor synthesized from commercially available petroleum pitch was stabilized in air. The influence of oxygen mass gain during stabilization on the yield of matrix precursor was studied. Additionally, the influence of pressure on the yield of the stabilized matrix precursor in a real system was studied. The fourier transform infrared spectrometry (FTIR), thermogravimetric analysis (TGA), yield, yield rate, and yield impact were used to check the effect of stabilization and pressure on the yield of the matrix precursor and the end properties of the composite thereafter. The results showed that the yield increased with stabilization duration up to 20 h whereas it decreased for stabilization duration beyond 20 h. Further results showed that the stabilized matrix precursor for a duration of 5 h could withstand almost two-fold greater hot-pressing pressure without resulting in exudation as compared to that of a 1 h stabilized matrix precursor. The enhanced hot-pressing pressure significantly improved the yield of the matrix precursor. As a consequence, the densification and mechanical properties were increased significantly. Further, the matrix precursor stabilized for a duration of 20 h or more failed to provide proper and uniform binding of the reinforcement.

A study of Frictional Behavior of SCM415 Steel as a Function of Density of Micro Dimples (미세 딤플의 밀도에 따른 SCM415강의 마찰 거동 연구)

  • Cho, Min-Haeng;Lee, Seung-Hyuk;Park, Sang-Il;Lyo, In-Woong
    • Tribology and Lubricants
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    • v.26 no.6
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    • pp.311-316
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    • 2010
  • Surface texturing of micro dimple or pore-shaped pattern was prepared using a fiber laser system. Surface texturing was designed to have a square pattern with a particular pitch distance for each corresponding density of 5, 10, 20, and 30%. Thermal damages such as bulges and burrs formed during laser irradiation were observed around the dimples. Thermal damages were later removed by lapping using alumina particles of $0.3{\mu}m$ in diameter. Oscillating friction tests were performed against heat-treated high speed steels under lubricated condition. The lubricant used was SAE 5W-30 automotive engine oil. Normal contact pressure and oscillating frequency was 0.28 MPa and 20 Hz, respectively. The tests were continued for 20 minutes, and friction plots were recorded for examination. Results revealed that the coefficient of friction was lowered regardless of texturing density. Moreover, the lowest coefficient of friction was obtained for 10% density texturing. It is attributed to increased lubricity due to the introduction of surface texturing. In addition, it is concluded that the optimum texturing density and pattern must be found for the best lubricity and low friction.

Adsorption of Nitrogen Oxides on Manufactured Impregnated Activated Carbon Fibers with Potassium Hydroxide

  • Kim, Hyun-Jin;Lee, Young-Whan;Choi, Dae-Ki;Lee, Eun-Il
    • Carbon letters
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    • v.3 no.4
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    • pp.198-204
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    • 2002
  • In this paper, impregnated activated carbon fiber (IACF) was manufactured to pitch-based activated carbon fibers (ACF) with potassium hydroxide (KOH) by using wet impregnation method to raise nitrogen oxides ($NO_x$) adsorptivity. The properties of IACF were observed using EPMA, TGA and DSC and $NO_x$ adsorptivity was observed at high and low temperature. Before and after adsorption was analyzed using ToF-SIMS for examine surface characterization of adsorbed $NO_x$. The results showed that the better adsorptivity appeared for increasing KOH ratio. So, $NO_x$ adsorptivity showed result that is proportional between KOH and the adsorbed amount. On the other hand, adsorbent that manufactured without washing was better $NO_x$ adsorptivity than adsorbent that manufactured with washing. The behavior of adsorption show that crossing time of NO and $NO_2$ delayed for a rising adsorptivity. And NO ratio increased but $NO_2$ ratio decreased according as KOH ratio increases. $NO_x$ was confirmed through surface analysis that remain in $NO_2^-$ and $NO_3^-$ form on IACF surface.

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Surface Characterization of Carbon Fibers as Anode Materials for Li Secondary Batteries

  • Takamura, Tsutomu;Awano, Hidekazu;Ura, Tetsuya;Ikezawa, Yasunari
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.583-590
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    • 1995
  • Pitch-based mesophase carbon fibers prepared at different temperatures were heat-treated at temperatures lower than those of the preparation and the electrochemical Li doping/undoping characteristics were evaluated in relation to the data of IR, mass, etc. Presence of surface hydroxyls were confirmed by FTIR for lower temperature sample which showed poor anode characteristics. Upon oxidative heating, removal of surface hydroxyls took place, resulting in a remarkable improvement of the electrode characteristics. At the same time, surface roughening took place, which was confirmed by SEM and double layer capacity measurements. In situ mass spectra obesrved during the heat-treatments showed gas evolution of $H_2O$, CO, $CO_2$, $C_2H_4$, and/or $H_2$ depending on the conditions. These data together with those of weight loss and conductivity provided us a valuable information in regard to the evaluation of the electrochemical characteristics.

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Design of an Endoscopic Microscope Objective Lens Composed of Flexible Fiber Bundle and Gradient-index with a High Resolution and a Minimally-Invasive Outer Diameter (광섬유 다발과 Gradient-index Lens가 결합된 고 분해능 및 최소침습 직경의 공초점 내시 현미경 대물렌즈의 설계)

  • Jang, Sun-Young;Rim, Cheon-Seog
    • Korean Journal of Optics and Photonics
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    • v.19 no.2
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    • pp.87-94
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    • 2008
  • We present a new design for an endoscope objective lens composed of a lexible fiber bundle with 30,000 core, and a gradient-index (GRIN) objective lens with an optical adaptor. The characteristic of this objective lens is to be minimally-invasive to be able to insert easily in the internal organs of live animals. The GRIN lens has a small diameter and a very simple construction, which is selected with the diameter of 1.0 mm and numerical aperture of 0.5 to achieve a minimally-invasive outer diameter and a high resolution. The resultant designed lens shows the performance as follows; a lateral resolution of 1.63 um and diameters of 100% encircled energy of $0.3\;{\mu}m$ and $0.83\;{\mu}m$ for the on-axis and the off-axis image point, respectively. Also, we can present a cheap solution with a lateral resolution of 1.74 um and diameters of 100% encircled energy of $1.10\;{\mu}m$ and $2.84\;{\mu}m$ for the on-axis and the off-axis image point, respectively.

Moisture Content Prediction Model Development for Major Domestic Wood Species Using Near Infrared Spectroscopy (근적외선 분광분석법을 이용한 국산 주요 수종의 섬유포화점 이하 함수율 예측 모델 개발)

  • Yang, Sang-Yun;Han, Yeonjung;Park, Jun-Ho;Chung, Hyunwoo;Eom, Chang-Deuk;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.3
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    • pp.311-319
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    • 2015
  • Near infrared (NIR) reflectance spectroscopy was employed to develop moisture content prediction model of pitch pine (Pinus rigida), red pine (Pinus densiflora), Korean pine (Pinus koraiensis), yellow poplar (Liriodendron tulipifera) wood below fiber saturation point. NIR reflectance spectra of specimens ranging from 1000 nm to 2400 nm were acquired after humidifying specimens to reach several equilibrium moisture contents. To determine the optimal moisture contents prediction model, 5 mathematical preprocessing methods (moving average (smoothing point: 3), baseline, standard normal variate (SNV), mean normalization, Savitzky-Golay $2^{nd}$ derivatives (polynomial order: 3, smoothing point: 11)) were applied to reflectance spectra of each specimen as 8 combinations. After finishing mathematical preprocessings, partial least squares (PLS) regression analysis was performed to each modified spectra. Consequently, the mathematical preprocessing methods deriving optimal moisture content prediction were 1) moving average/SNV for pitch pine and red pine, 2) moving average/SNV/Savitzky-golay $2^{nd}$ derivatives for Korean pine and yellow poplar. Every model contained three principal components.

Recycling of Plant Fiber Resources: Enhanced Hydration of Newspaper Stock for Decrease of Deinking Reject (식물유래 섬유자원의 재활용: 탈묵 수율 개선을 위한 신문 지료의 수화 촉진 방안)

  • Chung, Sung-Hyun;Kim, Joong-Ho;Joo, Jong-Hun;Bang, Jae-Wook
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.10a
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    • pp.39-41
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    • 2011
  • The recycling rate of recovered paper in Korea is the highest in the world, 92%, but remanufacturing yield is low due to the extremely poor quality of the paper. The poor quality, in turn, influences to the reject amount in deinking process. To increase the yield of old newspaper recycling process, hydrophobic degree of inorganic pigments of deinking stock must be reduced. To determine the hydrophobicity, Pitch Potential Deposit Tester (PDT) was newly designed and applied with respect to the SB latex property of various quality used in Korea; its hydrophobic degree according to Tg, gel content, charge and particle size of latex and optimum designing condition of SB latex. And below are the conclusions: 1. The reason of excessive reject from old newspaper deinking process for total amount of printed ink is loss of inorganic pigments. When lipase, a biochemical catalyst, was applied with the purpose of preventing inorganic pigments loss about more than 70% of total reject weight and promoting hydration of pulp for deinking, deinking process yield of pre flotation secondary stage increased remarkably without any changes of deinking efficiency. 2. Lipase improved deinking stock by cutting ester linkage on surface of hydrophobic materials to promote its hydration. From this, it reached the conclusion that hydration degree of stock exercises significant effect on flotation deinking process yield. 3. Inorganic alkali promotes hydration of deinking stock. But there have been needs for more fundamental measures other than inorganic alkali of promoting hydration for yield improvement. For this, this study intended to find out reasons of chemical properties change on surface of hydrophobic material by change of pH. 4. Pitch Deposit Test (PDT) was performed for understanding principle of why surface of coating flake from OMG is hydrophobic and why it becomes hydrophilic when pH of stock is alkaline. As a result of this test, it is determined that swelling property by change of pH of latex film, which were used as coating adhesive is the reason for hydrophobic change. 5. Hydrophilicity of coating flake increased with hydrophilic pigments. And as more of SB Latex adhesive was used and higher of calcium hardness of stock became, its hydrophilicity decreased. SB Latex adhesive film is reformed by mechanical friction. For having hydrophilicity under neutral pH, strong bruising action such as kneading is required. 6. Because swelling of adhesive film decreases as Tg of SB latex gets lower and mean diameter gets smaller, it shows hydrophobicity under neutral pH. This lowers hydrophilicity of coating flake, which leads to easy elimination with flotation reject on DIP process. Therefore, for improving future flotation yield, it is necessary to develop to use eco-friendly clean SB latex by raising Tg and increasing mean diameter for recycling, and as a result, to reduce excessive loss of coating flake as a reject from deinking process.

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Cross-sectional Design and Stiffness Measurements of Composite Rotor Blade for Multipurpose Unmanned Helicopter (다목적 무인헬기 복합재 로터 블레이드의 단면 구조설계 및 강성 측정)

  • Kee, Young-Jung;Kim, Deog-Kwan;Shin, Jin-Wook
    • Journal of Aerospace System Engineering
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    • v.13 no.6
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    • pp.52-59
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    • 2019
  • The rotor blade is a key component that generates the lift, thrust, and control forces required for helicopter flight by the torque transmitted through the hub and the blade pitch angle control, and should be designed to factor vibration characteristics so that there is no risk of resonance with structural safety. In this study, the structural design of the main rotor blade for MPUH(Multi-Purpose Unmanned Helicopter) was conducted and the sectional stiffness measurement of the fabricated blade was performed. The evaluation of the vibration characteristics of the main rotor system was then conducted factoring the measured stiffness distribution. The interior of the rotor blade comprised of the skin, spar, and torsion box, and carbon and glass fiber composites were applied. The Ksec2D program was applied to predict the stiffness of blade, and the results were compared to the measured data. CAMRADII, a comprehensive rotorcraft analysis program, was applied to investigate the natural frequency trends and resonance risks due to the rotor rotation.