• 제목/요약/키워드: Pi

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궤도간 상호작용의 PMO 이론 (제5보). ${\pi}$-${\pi}$${\pi}^{\ast}$-${\pi}^{\ast}$ 궤도간 상호작용 (PMO Theory of Orbital Interaction (Ⅴ). ${\pi}$-${\pi}$ and ${\pi}^{\ast}$-${\pi}^{\ast}$ Orbital Interactions)

  • 이익춘;양기열;이난표;김왕기
    • 대한화학회지
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    • 제29권1호
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    • pp.23-30
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    • 1985
  • ${\pi}^{\ast}$-${\pi}^{\ast}$ 궤도간 상호작용에 관한 섭동식을 유도하였다. 섭동식으로부터 예측되는 ${\pi}$-${\pi}$${\pi}^{\ast}$-${\pi}^{\ast}$ 상호작용간의 중요한 두가지 차이점은 : (ⅰ)에너지분리정도가 ${\pi}$-${\pi}$ 상호작용의 경우보다 ${\pi}^{\ast}$-${\pi}^{\ast}$의 경우가 더 컸으며, ( ii ) 상호작용에 의한 에너지 변화량은 ${\pi}$-${\pi}$ 상호작용의 경우보다 ${\pi}^{\ast}$-${\pi}^{\ast}$의 경우가 더 불안정화 되었다. 이러한 예측들은 실험결과들과 MO이론적 계산에 의하여 잘 밝혀졌다. 한편 STO-3G 및 INDO-LCBO 계산방법은 ${\pi}^{\ast}$-${\pi}^{\ast}$ 상호작용을 과소평가하고 있음을 알았으며 MO이론적 계산을 이용하여 이러한 ${\pi}^{\ast}$-${\pi}^{\ast}$상호작용을 적절히 표현하는 데는 split valence 기초함수를 사용하여야 함을 밝혔다.

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고추의 탄저병(炭疽病) 저항성(抵抗性)에 관(關)한 연구(硏究) (Studies on Resistance to anthracnose (Colletrichum dematium) in Pepper)

  • 박현규;김병수;이우승
    • Current Research on Agriculture and Life Sciences
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    • 제4권
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    • pp.7-11
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    • 1986
  • 한국(韓國) 지방(地方) 재래종(在來種) 고추 9계통(系統)과 미국(美國) 식물(植物) 도입국계통(導入局系統)(PI) 34개(個) 계통(系統)을 공시(公試)하여 흑색(黑色) 병징(病徵)의 탄저병(炭疽病)(Colletotrichum dematium)에 대한 저항성(抵抗性)을 검정(檢定)하였다. 적열과(赤熱果)에다 침상후(針傷後) 병원균(病原菌) 현탁액(懸濁液)을 분무(噴霧)하는 방법(方法)과 점적(點滴)하는 방법(方法)으로 접종(接種)한후 침상부위(針傷部位)를 중심(中心)으로 형성(形成)된 병반(病班) 직경(直徑)을 측정(側定)하여 저항성(低抗性)을 평가(評價)한 결과(結果)는 다음과 같다. 1) PI 201232, PI 224451, PI 257044, PI 257119, PI 257099, PI 224433, PI 244668, PI 257102, PI 173877, 남지 청룡 서동 등(等)은 발병(發病)이 가장 적어 저항성(抵抗性)으로 사료(思料)된다. 2) PI 241670, PI 244670, PI 224423 등(等)은 발병(發病)이 가장 커 이병성(罹病性)으로 사료(思料)된다. 3) 기외(其外)는 중간(中間) 정도(程度)였다.

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SOME RESULTS ON STRONG π-REGULARITY

  • Cho, Yong Uk
    • 충청수학회지
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    • 제22권3호
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    • pp.293-297
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    • 2009
  • We will introduce some properties of strongly reduced near-rings and the notion of left $\pi$-regular near-ring. Also, we will study for right $\pi$-regular, strongly left $\pi$-regular, strongly right $\pi$-regular and strongly $\pi$- regular. Next, we may characterize the strongly $\pi$-regular near-rings with related strong reducibility.

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비음(脾陰) 이론의 형성에 대한 고찰 (A Study On the Development of the Pi-Yin Theory)

  • 尹基領
    • 대한한의학원전학회지
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    • 제35권3호
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    • pp.91-106
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    • 2022
  • Objectives : To examine the developmental process of the Pi-Yin theory since the Huangdineijing to Miu Xiyong. Methods : Related contents since the Huangdineijing to Miu Xiyong was searched to examine the development of the Pi-Yin theory. Results & Conclusions : In the Huangdineijing and Shanghanzabinglun, the origin of the Pi's body fluids that nurtures everywhere is explained to be the Wei, which limited the development of the Pi-Yin theory. Liu Wansu understood tonification of the Pi by means of moistening medicinals to mean adding Pi-Yin based on the manifestation of dryness in the case of dampness deficiency which is the main Qi of the Pi and Wei. Zhu Danxi understood adding Pi-Yin as accomplished by supplementing Blood. The understanding of the nature of Pi to be 'likes dryness and hates dampness' leading to thinking that drying dampness tonifies the Pi was the reason why the Pi-Yin theory could not develop fully. Miu Xiyong accepted theories of both Li Dongyuan and Zhu Danxi, and constructed the Pi-Yin theory to bring caution to the unwanted effects of using Baizhu wrongly. Through examination of the developmental process of the Pi-Yin theory, it could be understood that rather than focusing on the physiological function of the Pi-Yin and ways of maintaining its proper functioning, the theory was developed to bring caution to using medicinals with dry and hot properties that could dry the Pi-Yin.

PMO Theory of Orbital Interactions (Part 7). $\sigma-\pi$ Interactions

  • Kong, Byung-Hoo;Lee, Byung-Choon;Lee, Ik-Choon;Yang, Ki-Yull
    • Bulletin of the Korean Chemical Society
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    • 제6권5호
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    • pp.277-279
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    • 1985
  • Orbital interactions of the types, ${\sigma}-{\pi},\;{\sigma}^*-{\pi},\;{\sigma}-{\pi}^*\;and\;{\sigma}^*-{\pi}^*$ are investigated for the rotamers of ${\alpha}$-X-acetones (X = F and Cl) using STO-3G method of calculation. It was found that the interactions are possible only in gauche forms, and the ${\sigma}^*-{\pi}^*$ interactions are in general greater than the $\sigma-\pi$ interactions due to the greater overlap, in spite of the greater energy gap involved; the greater ${\sigma}^*-{\pi}^*$ interaction causes greater lowering of ${\pi}^*$ level relative to the lowering of ${\sigma}$ in the ${\sigma}-{\pi}$ interaction so that both ${\sigma}-{\pi}^*$ and $n-{\pi}^*$ interactions are enhanced in the gauche forms. The extra stability of the gauche form and the red shift in the $n-{\pi}^*$ transition are thus found to be natural corollaries of the greater ${\sigma}^*-{\pi}^*$ interaction in the gauche forms.

N-메틸루티돈의 電子構造와 光化學反應性에 關한 硏究 (Electronic Structure and Photoreactivity of N-Methyllutione)

  • 심상철;현명호;채규호
    • 대한화학회지
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    • 제21권6호
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    • pp.434-439
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    • 1977
  • 4-피리돈과 루티돈의 전자구조를 SCF MO-CI PPP 방법과 configuration analysis 법을 사용하여 연구하였다. 계산결과와 스펙트럼 분석치와는 잘 일치하였으며 첫번째 $({\pi},{\pi}^*)$ 단일상태는 두 화합물 모두 장축 방향으로 편극되어 있다. Configuration analysis 결과 가장 낮은 $({\pi},{\pi}^*)$ 단일 상태에서는 C=O 작용기의 ${\pi}$ 결합궤도로 부터 디비닐아민 부분의 ${\pi}^*$ 반결합 궤도로 전하가 이동되어 있으나 가장 낮은 $({\pi},{\pi}^*)$ 삼중상태에서는 반대로 디비닐아민 부분으로 부터 C=O 작용기 쪽으로 전하가 이동되어 있음을 알 수 있다.

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S-PI 제어기를 이용한 개선된 하이브리드 멀티전동부항시스템 (Enhanced Hybrid Multi Electrical Cupping System using S-PI Controller)

  • 김종찬;김치용
    • 한국멀티미디어학회논문지
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    • 제18권11호
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    • pp.1400-1407
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    • 2015
  • In the paper, we suggest bettered EHMECS(Enhanced Hybrid Multi Electrical Cupping System) to regulate automatically vacuum pressure using many cupping cup at once. We controlled accurately the pressure using S-PI control technique in pump motor to input the air inside cupping cup. S-PI control compared constant velocity, load and velocity variance between existing PI and FLC(Fuzzy Logic Control). The stabilization time of suggested S-PI control improve 20% of existing PI and 8% of FLC. The error constant of normal condition improved 71% of existing PI and 62% of FLC in steady speed and 80% of existing PI and 67% of FLC in load change. Also the error constant about velocity variance improve 45% of PI control. It is prove the suggested S-PI control technique. When use long time vacuum pressure of cupping cup regulated the suggested S-PI control technique, can loosen knotted muscles.

THE STUDY OF THE SYSTEM OF NONLINEAR WAVE EQUATIONS

  • Jung, Tacksun;Choi, Q-Heung
    • 충청수학회지
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    • 제20권3호
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    • pp.261-267
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    • 2007
  • We show the existence of the positive solution for the system of the following nonlinear wave equations with Dirichlet boundary conditions $$u_{tt}-u_{xx}+av^+=s{\phi}_{00}+f$$, $$v_{tt}-v_{xx}+bu^+=t{\phi}_{00}+g$$, $$u({\pm}\frac{\pi}{2},t)=v({\pm}\frac{\pi}{2},t)=0$$, where $u_+=max\{u,0\}$, s, $t{\in}R$, ${\phi}_{00}$ is the eigenfunction corresponding to the positive eigenvalue ${\lambda}_{00}=1$ of the eigenvalue problem $u_{tt}-u_{xx}={\lambda}_{mn}u$ with $u({\pm}\frac{\pi}{2},t)=0$, $u(x,t+{\pi})=u(x,t)=u(-x,t)=u(x,-t)$ and f, g are ${\pi}$-periodic, even in x and t and bounded functions in $[-\frac{\pi}{2},\frac{\pi}{2}]{\times}[-\frac{\pi}{2},\frac{\pi}{2}]$ with $\int_{-\frac{\pi}{2}}^{\frac{\pi}{2}}f{\phi}_{00}=\int_{-\frac{\pi}{2}}^{\frac{\pi}{2}}g{\phi}_{00}=0$.

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퍼지 PI 제어기를 사용한 BLDC 제어 응답특성 (The Characteristic of Control Response of BLDC using a Fuzzy PI Controller)

  • 윤용호;김재문;김덕헌;원충연
    • 전기학회논문지
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    • 제60권10호
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    • pp.1978-1983
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    • 2011
  • BLDC motor is used in a wide variety of industrial and servo applications. Its features and advantages mainly consist in high value of torque/inertia ratio, high efficiency with speed range and high dynamic performance. This paper deals with the speed control of a trapezoidal type brushless DC motor using Fuzzy PI controller. The conventional PI controller has been widely used in industrial applications. If we select a optimal PI control gain, the PI controller shows very good control performance. But it is very difficult to find the optimal PI control gain. Fuzzy control does not need any model of plant and is basically adaptive and gives robust performance for plant parameter variation. Therefore the combinations of conventional PI controller and fuzzy controller seem to be very effective. This paper deals with PI controller with 4-rule based fuzzy controller. The proposed fuzzy PI controller increases the control performance of the conventional PI controller. Simulation and experimental results show that fuzzy PI controller has a good robustness regarding the improper tuned PI controller.

풍력 발전기 피치 제어를 위한 퍼지 PI 제어기 (A Fuzzy PI Controller for Pitch Control of Wind Turbine)

  • 천종민;김진욱;김홍주;최영규;김무림
    • 드라이브 ㆍ 컨트롤
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    • 제15권1호
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    • pp.28-37
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    • 2018
  • When the wind speed rises above the rated wind speed, the produced power of the wind turbines exceeds the rated power. Even more, the excessive power results in the undesirable mechanical load and fatigue. A solution to this problem is pitch control of the wind turbines. This paper presents a systematic design method of a collective pitch controller for the wind turbines using a discrete fuzzy Proportional-Integral (PI) controller. Unlike conventional PI controllers, the fuzzy PI controller has variable gains according to its input variables. Generally, tuning the parameters of fuzzy PI controller is complex due to the presence of too many parameters strongly coupled. In this paper, a systematic method for the fuzzy PI controller is presented. First, we show the fact that the fuzzy PI controller is a superset of the PI controller in the discrete-time domain and the initial parameters of the fuzzy PI controller is selected by using this relationship. Second, for simplicity of the design, we use only four rules to construct nonlinear fuzzy control surface. The tuning parameters of the proposed fuzzy PI controller are also obtained by the aforementioned relationship between the PI controller and the fuzzy PI controller. As a result, unlike the PI controller, the proposed fuzzy PI controller has variable gains which allow the pitch control system to operate in broader operating regions. The effectiveness of the proposed controller is verified with computer simulations using FAST, a NREL's primary computer-aided engineering tool for horizontal axis wind turbines.