• Title/Summary/Keyword: Physicochemical factors

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Research Trends of Ecotoxicity of Nanoparticles in Soil Environment

  • Lee, Woo-Mi;Kim, Shin-Woong;Kwak, Jin-Il;Nam, Sun-Hwa;Shin, Yu-Jin;An, Youn-Joo
    • Toxicological Research
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    • v.26 no.4
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    • pp.253-259
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    • 2010
  • We are consistently being exposed to nanomaterials in direct and/or indirect route as they are used in almost all the sectors in our life. Nations across the worlds are now trying to put global regulation policy on nanomaterials. Sometimes, they are reported to be more toxic than the corresponding ion and micromaterials. Therefore, safety research of nanoparticles has huge implications on a national economics. In this study, we evaluated and analyzed the research trend of ecotoxicity of nanoparticles in soil environment. Test species include terrestrial plants, earthworms, and soil nematode. Soil enzyme activities were also discussed. We found that the results of nanotoxicity studies were affected by many factors such as physicochemical properties, size, dispersion method and test medium of nanoparticle, which should be considered when conducting toxicity researches. In particular, more researches on the effect of physicochemical properties and fate of nanoparticles on toxicity effect should be conducted consistently.

Effect of Varous Physicochemical Factors on the Biodegradation of Explosive 2,4,6-Trinitrotoluene by Stenotropomonas maltophilia (Stenotrophomonas maltophilia에 의한 폭약 2,4,6-Trinitrotoluene의 생분해에 영향을 미치는 물리화학적 요인)

  • 김영진;이명석;조윤석;한현각;김승기;오계헌
    • KSBB Journal
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    • v.14 no.3
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    • pp.315-321
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    • 1999
  • The relationships between the explosive 2,4,6-trinitrotoluene (TNT) degradation by Stenotrophomonas maltophilia and several relevant physicochemical environmental parameters were examined. At neutral pH of the cultures, the degradation of TNT proceeded to completion, whereas only about 50% of TNT was utilized when the cultures were adjusted to acidic pH. The effect of various co-substrates (e.g., glucose, fructose, acetate, citrate, succinate) on the degradation of TNT by the test culture of S. maltophilia was evaluated. The results indicated that, among the various co-substrates studies, the test culture that received 2 mM fructose degraded 100 mg/L of TNT completely within 20 days of incubation at ambient temperature, whereas partial degradation of TNT was observed in the test culture with acetate, citrate, or succinate as a co-substrate, respectively. In fact, fructose was the best co-substrate for TNT degradation in this experiment. The effect of supplemented nitrogens [e.g., (NH$_4$)$_2$,SO$_4$, NH$_4$Cl. urea] on the TNT degradation was monitored. All supplemented nitrogens in this study were inhibitory to TNT degradation. Addition of 1% Tween80 accelerated TNT degradation, and showed complete degradation of TNT within 8 days of incubation. Addition of yeast extract resulted higher growth yields, based on turbidity measurement, but it inhibited TNT degradation.

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Physicochemical Characteristics of Traditional Vinegars in Andong province (안동지역 전통식초의 이화학적 특성)

  • Lee, Young-Chul;Jang, One-Young;Kim, Hyeon-Wee;Choi, Chun-Un;Yoon, Sook-Kyung
    • Journal of the Korean Society of Food Culture
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    • v.14 no.1
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    • pp.17-20
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    • 1999
  • Three kinds of traditional Andong vinegars, manufactured from Songwhaju which was a traditional rice alcoholic beverage in Andong province, were investigated on the physicochemical characteristics compared with commercial rice vinegar speciality and on the factors affecting their flavor components. Traditional Andong vinegars had a low level of total acids$(3.1{\sim}3.6%)$ and more soluble solids than rice vinegar speciality. Lactic acid contents were also high and it came from lactic acid fermentation in the early stage of the vinegar manufacturing process. Other organic acids such as malic, citric and succinic acid were also detected. Free amino acid analysis showed that alanine, arginine and leucine contents, which were known as a main characteristics of rice vinegar, were especially high. In addition, a considerable amounts of glutamic acid and aspartic acid which were known as a mild effectors of acidic taste in rice vinegar products were detected.

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Physicochemical Properties of Rice Extrudate with Added Ginger Powder by the Response Surface Regression Analysis (반응 표면 분석에 의한 생강 분말을 첨가한 쌀 압출 성형물의 이화학적 성질)

  • 고광진
    • The Korean Journal of Food And Nutrition
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    • v.6 no.3
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    • pp.178-188
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    • 1993
  • This research was attempted to investigate changes in physicochemical properties of rice extrudate with added ginger powder extruded by single screw extruder. Graphic three dimensional analysis on response surface regression was used to evaluate effects of extrusion variables on quality factors of the extrudate according to two independent variables, ginger consent 0∼12%, moisture content 14∼26%. The summarized results are as follows : 1) Regarding proximate composition of rice extrudate with added ginger powder, as ginger powder content of raw material Increased, crude tat, crude protein, crude ash and crude fiber increased, while soluble nitrogen free extract decreased. 2) Graphic three dimensional analysis on response surface regression was conducted for each dependent variable which revealed statistically significant relationship with independent variables, 0∼120A ginger and 14∼26% moisture content. Expansion ratio had a critical point as moisture content changed. As ginger and moisture content Increased, bulk density, break strength and water absorption Index Increased, while water solubility Index decreased. The predicted maximum degree of gelatinization in 6.15% ginger and 15.56% moisture content is 88.27%, and lightness decreased as ginger content Increased. According to the microstructure for the cross section of extrudate obsorbed with image analyzer, air cell number and perimeter revealed saddle point, meanwhile total area and fractarea of air cell had critical points as moisture content changed. In view of the results, quality of rice extrudate with added ginger powder was optimum when rice flour was fed to the extruder with 2∼7% singer powder and 15∼20% moisture content.

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QSPR Models for Chromatographic Retention of Some Azoles with Physicochemical Properties

  • Polyakova, Yulia;Jin, Long Mei;Row, Kyung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.27 no.2
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    • pp.211-218
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    • 2006
  • This work deals with 24 substances composed of nitrogen-containing heterocycles. The relationships between the chromatographic retention factor (k) and those physicochemical properties which are relevant in quantitative structure-properties relationship (QSPR) studies, such as the polarizability $(\alpha)$, molar refractivity (MR), lipophilicity (logP), dipole moment $(\mu)$, total energy $(E_{tot})$, heat of formation $(\Delta H_f)$, molecular surface area $(S_M)$, and binding energy $(E_b)$, were investigated. The accuracy of the simple linear regressions between the chromatographic retention and the descriptors for all of the compounds was satisfactory (correlation coefficient, $0.8 \leq r \leq 1.0$). The QSPR models of these nitrogen-containing heterocyclic compounds could be predicted with a multiple linear regression equation having the statistical index, r = 1.000. This work demonstrated the successful application of the multiple linear approaches through the development of accurate predictive equations for retention factors in liquid chromatography.

Physicochemical Analysis according to Temperature Changes of Iopamidol and Ioversol Formulation Contrast Agents (Iopamidol과 Ioversol 제제 조영제의 온도변화에 따른 물리화학적 분석)

  • Han, Beom-Hee
    • Journal of radiological science and technology
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    • v.43 no.4
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    • pp.273-280
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    • 2020
  • In this study, the P contrast agent of Iopamidol, which is a nonionic iodide contrast agent most commonly used as a vascular contrast agent in medical institutions, and the O contrast agent of Ioversol, were studied. The physicochemical changes according to the temperature change were compared and analyzed using the Bruker Avance 500MHz Nuclear Magnetic Resonance Spectrometer owned by the Korea Basic Science Institute (KBSI). There was no physical or chemical change in the O contrast medium of Ioversol formulation in temperature change. However, in the P contrast agent of Iopamidol, a doublet peak began to appear in the 1.1 ppm region of the sample at 60℃, and the doublet peak was clearly observed in the sample at 80℃. As a result of this study, 1H-NMR analysis revealed that the P contrast agent of the Iopamidol formulation was dissociated from chemical bonds as it rose to a high temperature of 60℃ or higher, resulting in the formation of foreign substances. It was evaluated that the O contrast agent of Ioversol formulation had physico-chemical stability than the P contrast agent of Iopamidol formulation. As shown in this study, it is necessary to analyze the physical and chemical changes of contrast agents according to various environmental factors.

Physicochemical of Turnip Baek-Kimchi and Anti-Cancer Effects of Human Gastric Cancer Cells (AGS) (순무백김치의 이화학적 특성 및 인체위암세포(AGS)의 항암효과)

  • Im, Gum Ja;Kang, Soon Ah
    • The Korean Journal of Food And Nutrition
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    • v.35 no.2
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    • pp.127-136
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    • 2022
  • Comparing the quality characteristics of kimchi were measured and anticancer effects using AGS human gastric cancer cells were observed. Five kinds of kimchi samples were made of Kanghwa Baek kimchi (KB), Kangwha Turnip kimchi (KT), Turnip: Chinese cabbage = 1:1 Baek kimchi (T1B1), Turnip:Chinese cabbage = 4:1 Baek kimchi (T4B1), Turnip mul kimchi (T). As a result T kimchi showed the best fermentation characteristics among the five samples. T kimchi had a lower percentage of the total number of aerobic bacteria, while the number of lactobacillus was higher than that of other samples. The mRNA and protein expression levels of apoptosis-related factors found that T kimchi significantly increases the mRNA expression levels of caspases-3 and caspases-9 in AGS human gastric cancer cells as compared to the other kimchi samples. It showed high anticancer effects in the order of T, T1B1, and KB kimchi. As the anticancer effect of Turnip mul kimchi made only of turnip was higher, the higher the turnip content, the higher the anticancer effect. These results show that there were changes in fermentation characteristics such as pH, acidity, number of lactic acid bacteria, and anticancer effects according to the ratio of turnip and cabbage.

Seasonal Variation of Primary Productivity in Gangjin Bay (강진만 일차생산력의 계절변화)

  • 주현수;김성호;이우범
    • Korean Journal of Environmental Biology
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    • v.20 no.2
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    • pp.146-151
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    • 2002
  • The primary productivity and physicochemical factors were surveyed seasonally in Gangjin bay from February to October in 1998. The determination of the Primary Productivity Was performed in Situ by isotope-method using NaH/sup 14/CO/sub 3/. The range of primary productivity was 2.78 mgC m/sup -3/ hr/sup -1/-4.92 mgC m/sup -3/ hr/sup -1/ according to seasons. The primary productivity showed the highest value in summer, followed by those of winter, autumn and spring. The primary productivities of station 1, 2 which are located the upper area, were lower than those of station 3, 4, 5 and 6. The correlations showed that the primary productivity correlated with chlorophyll a, underwater light intensity but reversely correlated with suspended solids. These results suggested that the primary productivity in Gangjin Bay was mainly influenced by the inflow of freshwater from Tamjin River.

The Effects of Physicochemical Factors and Cell Density on Nitrite Transformation in a Lipid-Rich Chlorella

  • Liang, Fang;Du, Kui;Wen, Xiaobin;Luo, Liming;Geng, Yahong;Li, Yeguang
    • Journal of Microbiology and Biotechnology
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    • v.25 no.12
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    • pp.2116-2124
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    • 2015
  • To understand the effects of physicochemical factors on nitrite transformation by microalgae, a lipid-rich Chlorella with high nitrite tolerance was cultured with 8 mmol/l sodium nitrite as sole nitrogen source under different conditions. The results showed that nitrite transformation was mainly dependent on the metabolic activities of algal cells rather than oxidation of nitrite by dissolved oxygen. Light intensity, temperature, pH, NaHCO3 concentrations, and initial cell densities had significant effects on the rate of nitrite transformation. Single-factor experiments revealed that the optimum conditions for nitrite transformation were light intensity: 300 μmol/m2/s; temperature: 30℃ pH: 7-8; NaHCO3 concentration: 2.0 g/l; and initial cell density: 0.15 g/l; and the highest nitrite transformation rate of 1.36 mmol/l/d was achieved. There was a positive correlation between nitrite transformation rate and the growth of Chlorella. The relationship between nitrite transformation rate (mg/l/d) and biomass productivity (g/l/d) could be described by the regression equation y = 61.3x (R2 = 0.9665), meaning that 61.3 mg N element was assimilated by 1.0 g dry biomass on average, which indicated that the nitrite transformation is a process of consuming nitrite as nitrogen source by Chlorella. The results demonstrated that the Chlorella suspension was able to assimilate nitrite efficiently, which implied the feasibility of using flue gas for mass production of Chlorella without preliminary removal of NOX.

Temporal and spatial variations of vegetation in a riparian zone of South Korea

  • Park, Hyekyung;Kim, Jae Geun
    • Journal of Ecology and Environment
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    • v.44 no.2
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    • pp.62-71
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    • 2020
  • Understanding vegetation structure and the relationship with environmental factors has been crucial for restoration and conservation of riparian zones. In this study, we conducted field survey in a riparian zone of Namhan River in South Korea both before and after flooding in order to understand temporal and spatial variations of riparian vegetation. There were significant temporal and spatial variations in species composition, and distribution patterns of vegetation were different along a gradient of elevation above the water level. At low elevation, Zizania latifolia was dominant throughout the field survey periods, and Bidens frondosa began to grow late and dominated both in post-flooding 1 and 2. Prior to flooding, Scirpus radicans and Polygonum thunbergii were widely distributed at middle elevation, while Artemisia vulgaris, Phragmites australis, and Miscanthus sacchariflorus were dominant at high elevation. After flooding, P. thunbergii was dominant at middle elevation with most other species decreasing, and more invasive or pioneer plants, including Artemisia princeps, H. scandens, and Sicyos angulatus, were observed at high elevation. Species composition and distribution patterns were homogeneous at low elevation, whereas dynamic variations of vegetation were observed both temporally and spatially at higher elevations. Elevation and distance from the water front were the most principal factors governing vegetation structure. Furthermore, soil physicochemical properties were also found to determine species composition and distribution patterns. These results indicate that vegetation structure in the riparian zones is formed by the combined effects of hydrological regime and soil physicochemical properties, inherent characteristics of species, and interspecific competition. Understanding of temporal and spatial variations of riparian vegetation may provide useful insights into ecological restoration and conservation of the vegetation within the riparian zones.