• Tunnel and Underground Space
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• v.19 no.2
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• pp.146-157
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• 2009

An experimental study of accelerated weathering on mudstone sample specimens from Haman, Gyeongnam was performed to investigate the variations of physico-mechanical properties of deteriorated rocks due to freeze-thaw weathering. Each complete cycle of freeze and thaw lasted 24 hours, comprising 2 hours of saturating in vacuum chamber, 8 hours of freezing at $-16{\pm}1^{\circ}C$ and 14 hours of thawing at room temperature. Total of 55 cycles of freeze-thaw were completed with measuring the index properties as well as geometries of microfractures. The measured specific gravity and P-wave velocity found to decrease with increasing freeze-thaw cycles. On the other hand, absorption ratio and effective porosity were continuously increased with increasing freeze-thaw cycles. It was found that the index properties of deteriorated sample specimen depend on its initial properties and flaws in rock. The size and density of the traces of the microfracture on slab specimen exhibited abrupt changes after 30 cycles of freeze-thaw weathering. The results obtained in this study show that the box fractal dimension($D_B$) given in this paper has the strong capability of quantifying the size and density of the microfracture.

• Advances in materials Research
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• v.2 no.1
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• pp.37-49
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• 2013

The transition metal salt doped solid polymer electrolyte [TSPE] were prepared with HPMC as a host polymer. The virgin and doped films were prepared by solution-casting method and investigated using wide angle X-ray scattering method. Micro structural parameters like lattice strain (g%), stacking/twin faults, the average number of unit cells counted in a direction perpendicular to the Bragg's plane (hkl) spacing of (hkl) planes dhkl, crystallite size Ds, distortion width, standard deviation were determined by whole pattern powder fitting (WPPF) method, which is an extension of single order method. It is found that the crystallite size decreases with the increase in the content of $FeCl_3$. This decrease is due to increase in localized breaking of polymer network which also accounts for the amorphous nature of the material. The filler inorganic salt $FeCl_3$ acts as plasticizer. FTIR study also confirms and justifies the interaction between the polymer and in-organic salt in the matrix. Physical properties like mechanical stability and Ac conductivity in these films are in conformity with the X-ray results.

• Journal of Ceramic Processing Research
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• v.19 no.6
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• pp.483-491
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• 2018

Effects of additives on phase development and physico-mechanical properties of mullite-carbon was investigated. Powdered clay, kaolinite and graphite of predetermined compositions were blended with additives using ball mill for 3 hrs at 60 rev/min. Samples were produced by uniaxial compression and sintered between $1400^{\circ}C$ and $1600^{\circ}C$ for one hr. They were characterized for various properties, developed phases and microstructural features. It was observed that the properties and phase developments in the samples were influenced by the additives. 10 wt % SiC served as nucleating point for SiC around $1400^{\circ}C$. 10wt % $TiO_2$ lead to development of 2.5 wt % TiC at $1500^{\circ}C$ which increased to 6.8 wt % at $1600^{\circ}C$. Ifon clay in the sample leads to development of anorthite and microcline in the samples. 10wt % $TiO_2$ is effective as anti-oxidant for graphite up to $1500^{\circ}C$. Base on strength and absorbed energy, sample C (with 10wt % $TiO_2$) sintered at $1500^{\circ}C$ is considered to be optimum.

• Tunnel and Underground Space
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• v.26 no.3
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• pp.220-234
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• 2016

Sprayable waterproofing membrane has been considered as a substitute for a sheet waterproofing membrane in a variety of underground excavation works. However, fundamental properties of sprayble waterproofing membrane have not been fully given yet. In this study, a new two-component sprayable waterproofing membrane prototype was developed. In addition, its physico-mechanical properties were measured and compared with those of two kinds of thin spray-on liners where constitutive materials and construction methods are very close to each other. From direct tensile tests, the sprayable waterproofing membrane with elongations at break between 250% and 300% showed much higher ductility than TSLs. However, the sprayable waterproofing membrane had a limitation as a support member since its bond strength and loading capacity was lower than those of TSLs. From three-dimensional X-ray CT images, the porosity of the sprayable waterproofing membrane was estimated to be 26.13%. However, most of pores which might have been generated during membrane curing were not observed to be interconnected but isolated.

• Korean Journal of Poultry Science
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• v.30 no.3
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• pp.211-217
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• 2003

A study was conducted to investigate the fattening performance, physico-chemical properties of breast meat, vaccine titers in cross bred meat type hybrid chicks fed organic sulfur. Total three hundred and sixty chicks of eight weeks old were replaced in individual cage from 8 to 10 weeks old. Four levels of organic sulfur (0, 1.0, 2.0, 4.0%) containing 45% sulfur were added into basal diet containing CP 19% and ME 2,950 kcal/kg. Weight gain, feed intake, fred conversion were weekly measured. The proximate composition, physico-chemical properties of breast meat, vaccine titer and sensory characteristics were examined at the end of experiment. Weight gain, feed intake and feed conversion of birds fed organic sulfur were not statistically different with control. There were no significant difference in feed intake and feed conversion. However, abdominal fat(%) of birds fed organic sulfur tended to increase compared with control. Crude fat of breast meat decreased significantly in organic sulfur treatments(P<0.05). The red color of breast meat seemed to increase but was not statistically different among the treatments. Cooking loss showed decrements significantly in organic sulfur treatments(P<0.05). Mechanical Hardness, cohesiveness and springiness were prone to be high and gumminess greatly high in breast meat of birds fed organic sulfur addition compared with control. Juiciness tended to increase and greasiness decreased(P<0.05) in organic sulfur treatments by the sensory evaluation. The overall acceptability of the breast meat was the highest at 2.0% organic sulfur added chicks(P<0.01). There were no different blood cholesterol, AST, ALT and BUN.

• Polymer(Korea)
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• v.39 no.1
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• pp.114-121
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• 2015

Mutli-walled carbon nanotubes (MWCNTs) were surface-modified by a hydrofluoric acid solution to remove impurities and improve interfacial bonding and dispersion of nanotubes in an epoxy matrix. The crystallinity on the surface of treated MWCNTs was investigated by X-ray photoelectron spectroscopy and Raman spectroscopy. The mechanical properties were characterized by tensile test, and the enhancement of mechanical properties of the modified MWCNTs/epoxy composites was indicated by a 33% increase in tensile strength. The electromagnetic interference shielding effectiveness (EMI-SE) of modified MWCNTs/epoxy composites was improved with an increase in concentration of hydrofluoric solution, and EMI-SE showed the maximum increase with 25% HF. However, mechanical and EMI-SE properties didn't show further increase with over 50% HF concentration because the properties of MWCNTs were influenced by degradation of crystallinity and intrinsic properties of MWCNTs. The mechanical and electrical property enhancements of the polymer composites are attributed to the modification of MWCNTs which improve crystallinity of MWCNTs and dispersion in the epoxy resin.

• Applied Chemistry for Engineering
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• v.19 no.3
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• pp.345-350
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• 2008

Polymer Impregnated Concrete (PIC) prepared from Ordinary Portland Cement Concrete (OPC) has excellent mechanical properties as well as physico-chemical properties. For the manufacturing of PIC, drying process of basis concrete (precast concrete), impregnation process with evacuation system and ultrasonic vibration system, polymerization process of monomers are essential. Modified microwave reactor using magnetron was used for polymerization of styrene/MMA (1 : 1) impregnated in pore volume of basis concrete. From the experimental results, the degree of polymerization increased up to 30% and more homogeneous PIC was prepared as compared to the conventional thermal method. Also the mechanical strengths increased more than 400% ($800{\sim}1200kg_f/cm^2$) and the resistance for corrosion to acids was improved up to 25%. AIBN and BPO as initiators for polymerization were used at the concentration less than 1%. Optimum conditions for polymerization were obtained at the frequency of microwave of 400 W and 2450 MHz, and optimum reaction temperature was $120^{\circ}C$ at an atmospheric pressure.

• Geomechanics and Engineering
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• v.13 no.3
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• pp.459-474
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• 2017

To investigate the mechanical properties of Expanded Polystyrene (EPS) Beads Stabilized Lightweight Soil (EBSLS), Laboratory studies were conducted. Totally 20 sets of specimens according to the complete test design were prepared and tested with unconfined compressive test and consolidated drained triaxial test. Results showed that dry density of EBSLS ($0.67-1.62g/cm^3$) decreases dramatically with the increase of EPS beads volumetric content, while increase slightly with the increase of cement content. Unconfined compressive strength (10-2580 kPa) increases dramatically in parabolic relationship with the increase of cement content, while decreases with the increase of EPS beads volumetric content in hyperbolic relationship. Cohesion (31.1-257.5 kPa) increases with the increase of cement content because it is mainly caused by the bonding function of hydration products of cement. The more EPS beads volumetric content is, the less dramatically the increase is, which is a result of the cohesion between hydration products of cement and EPS beads is less than that between hydration products of cement and sand particles. Friction angle ($14.92-47.42^{\circ}$) decreases with the increase of EPS beads volumetric content, which is caused by the smoother surfaces of EPS beads than sand grains. The stress strain curves of EBSLS tend to be more softening with the increase of EPS beads content or the decrease of cement content. The shear contraction of EBSLS increases with the increase of $c_e$ or the decrease of $c_c$. The results provided quantitative relationships between physico-mechanical properties of EBSLS and material proportion, and design process for engineering application of EBSLS.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.129.2-129.2
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• 2010

AEM which were used for solid alkaline fuel cell(SAFC) were prepared by photo polymerization in method pore-filling with various quaternary ammonium cationic monomers and crosslinkers without an amination process. Their specific thermal and chemical properties were characterized through various analyses and the physico-chemical properties of the prepared electrolyte membranes such as swelling behavior, ion exchange capacity and ionic conductivity were also investigated in correlation with the electrolyte composition. The polymer electrolyte membranes prepared in this study have a very wide hydroxyl ion conductivity range of 0.01 - 0.45S/cm depending on the composition ratio of the electrolyte monomer and crosslinking agent used for polymerization. However, the hydroxyl ion conductivity of the membranes was relatively higher at the whole cases than those of commercial products such as A201 membrane of Tokuyama. These pore-filling membranes have also excellent properties such as smaller dimensional affects when swollen in solvents, higher mechanical strength, lowest electrolyte crossover through the membranes, and easier preparation process compared of traditional cast membranes. The prepared membranes were then applied to solid alkaline fuel cell and it was found comparable fuel cell performance to A201 membrane of Tokuyama.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2004.05a
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• pp.9-15
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• 2004

The copolymerization of HEMA with different hydrophilic and hydrophobic co-monomers allows for the manipulation of their intrinsic properties. 2-Hydroxyethylmethacrylate (HEMA)-based hydrogels thus are of great interest due to their outstanding physico-mechanical properties and chemical stability. The idea to use HEMA in order to create thermo-sensitive polymers was based on our assumption that thermal-sensitivity comes from a suitable hydrophilic-hydrophobic balance of macromolecules. In this work we have chosen N-vinyl pyrrolidone as a hydrophilic co-monomer with the relatively hydrophobic HEMA due to its good polymerizing properties as well as its non-toxicity in a polymer state and deserved recognition as a biocompatible material. As a result, copolymerization of NVP and HEMA was successful in obtaining new types of thermo-sensitive polymers composed of hydrophilic and hydrophobic monomers.