• Title/Summary/Keyword: Physico-chemical analysis

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Pine Forest Soil Characteristics and Major Soil Impact Factors for Natural Regeneration

  • Kim, Min-Suk;Kim, Yong-Suk;Min, Hyun-Gi;Kim, Jeong-Gyu;Koo, Namin
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.3
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    • pp.179-186
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    • 2017
  • This study was conducted to identify characteristics of domestic pine forest soils and to elucidate major soil influencing factors for natural regeneration. We analyzed the physico-chemical characteristics of the soil samples collected from 23 pine forests and confirmed the similar results with the forest soil characteristics. Soil pH, organic matter content, total nitrogen, exchangeable Ca, silt content, and exchangeable Al were selected as the major soil factors among the exposed soils through 10 days of pine seedlings exposure and cultivation experiments and statistical analysis. Multiple regression analysis showed that soil pH had a positive effect on specific root length (SRL) of red pine seedlings and exchangeable Al was a significant factor affecting negative change in SRL. Taken together, the reduction of exchangeable Al by soil pH adjustment would be helpful for natural regeneration by restoring the forest and improving the fine root and root integrity of pine seedlings. Therefore, soil pH and exchangeable Al could be recommended as a major soil factor to be carefully considered in the monitoring and management of soil in pine forests that need to be renewed in the future.

Preliminary Ecological Environmental Assessments of a Brooklet in Jeungchon (증촌 도랑의 생태환경 조사와 평가)

  • Han, Jeong-Ho;An, Kwang-Guk
    • Journal of Environmental Impact Assessment
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    • v.21 no.6
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    • pp.841-857
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    • 2012
  • Preliminary ecological environmental assessments including physico-chemical constituents, water quality, fish fauna analysis, physical habitat health, and ecological health assessment were conducted as a primary step for Jeungchon micro-habitat ecosystem restoration in 2012. Water chemistry analysis of conductivity, dissolved oxygen, chlorophyll-a and etc. indicated that there were no significant differences(p < 0.05) among 6 sites between the headwaters and downstream. Multi-metric model analysis of Qualitative Habitat Evaluation Index(QHEI) showed that brooklets were at "good condition" as a mean QHEI of 158.7(n = 6) and the longitudinal differences of the model values between the sites were minor(QHEI range: 153 - 165). Total fish species and the number of individuals were 12 and 481, respectively, and dominant species were Zacco platypus(49.5%) and Zacco koreanus(36.8%). Tolerance guild analysis showed that the proportion of sensitive species($S_S$) had a negative linear function[$S_S=86.35-0.31(D_H)$; $R^2$ = 0.892, p < 0.01] with a distance from the headwaters, while the proportion of tolerant species($T_S$) had a positive linear function($R^2$ = 0.950, F = 90.28, p < 0.001) with the distance. Trophic feeding guild analysis showed that the proportion of insectivore species($I_n$) had a negative linear function($R^2$ = 0.934, p < 0.01) with a distance from the headwaters, while the proportion of omnivore species($O_m$) had a positive linear function($R^2$ = 0.958, p < 0.001) with the distance. Index of Biological Integrity(IBI) model, based on fish assemblages, showed a "fair condition" as a mean IBI of 23(n = 6), and there was a distinct differences of ecological health between the headwaters(S1 = 30; "good condition") and the downstreams(S6 = 14; "poor condition"). Overall, the preliminary environmental impact assessments suggest that water quality, physical habitat conditions(QHEI model), and ecological health(IBI model) were maintained well, even if the state was not an excellent conditions.

Effect of Dry Surface Treatment with Ozone and Ammonia on Physico-chemical Characteristics of Dried Low Rank Coal (건조된 저등급 석탄에 대한 건식 표면처리가 물리화학적 특성에 미치는 영향)

  • Choi, Changsik;Han, Gi Bo;Jang, Jung Hee;Park, Jaehyeon;Bae, Dal Hee;Shun, Dowon
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.532-539
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    • 2011
  • The physical and chemical properties of the dried low rank coals (LRCs) before and after the surface treatment using ozone and ammonia were characterized in this study. The contents of moisture, volatiles, fixed carbon and ash consisting of dried LRCs before the surface treatment were about 2.0, 44.8, 44.9 and 8.9%, respectively. Also, it was composed of carbon of 62.66%, hydrogen of 4.33%, nitrogen of 0.94%, oxygen of 27.01% and sulfur of 0.09%. The dried LRCs was surface-treated with the various dry methods using gases such as ozone at room temperature, ammonia at $200^{\circ}C$ and then the dried LRCs before and after the surface treatment were characterized by the various analysis methods such as FT-IR, TGA, proximate and elemental analysis, caloric value, ignition test, adsorption of $H_2O$ and $NH_3-TPD$. As a result, the oxygen content increased and the calorific value, ignition temperature and the contents of carbon and hydrogen relatively decreased because the oxygen-contained functional groups were additionally generated by the surface oxidation with ozone which plays a role as an oxidant. Also, its $H_2O$ adsorption ability got higher because the hydrophilic oxygen-contained functional groups were additionally generated by the surface oxidation with ozone. On the other hand, it was confirmed that the dried LRCs after the surface treatment with $NH_3$ at $200^{\circ}C$ have the decreased oxygen content, but the increased calorific value, ignition temperature and contents of carbon and hydrogen because of the decomposition of oxygen-contained functional groups the on the surface. In addition, the $H_2O$ adsorption ability was lowered bucause the surface of the dried LRCs might be hydrophobicized by the loss of the hydrophilic oxygen-contained functional groups. It was concluded that the various physico-chemical properties of the dried LRCs can be changed by the surface treatment.

Comparison of Four Different Ordination Methods for Patterning Water Quality of Agricultural Reservoirs

  • Bae, Mi-Jung;Kwon, Yong-Su;Hwang, Soon-Jin;Park, Young-Seuk
    • Korean Journal of Ecology and Environment
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    • v.41 no.spc
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    • pp.1-10
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    • 2008
  • We patterned water quality of agricultural reservoirs according to the differences of six physico-chemical environmental factors (TN, TP, DO, BOD, COD, and SS) using four different ordination methods: Principal Components Analysis (PCA), Detrended Correspondence Analysis (DCA), Nonmetric Multidimensional Scaling (NMS), and Isometric Feature Mapping (Isomap). The data set was obtained from the water quality monitoring networks operated by the Ministry of Agriculture and Forestry and the Ministry of Environments. Chlorophyll-${\alpha}$ displayed the highest correlation with COD, followed by TP, BOD, SS, and TN (p<0.01), while negatively correlated with altitude and bank height of the reservoirs (p<0.01). Although four different ordination methods similarly patterned the reservoirs according to the gradient of nutrient concentration, PCA and NMS appeared to be the most efficient methods to pattern water quality of reservoirs based on the explanation power. Considering variable scores in the ordination map, the concentration of nutrients was positively correlated with Chl-${\alpha}$, while negatively correlated with altitude and bank height. These ordination methods may help to pattern agricultural reservoirs according to their water quality characteristics.

The analysis of variational characteristics on water quality and phytoplankton by principal component analysis(PCA) in Kogum-sudo, Southwestern part of Korea (주성분분석에 의한 거금수도의 수질환경 및 식물플랑크톤 변동 요인 해석)

  • 윤양호;박종식
    • Journal of Environmental Science International
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    • v.9 no.1
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    • pp.1-11
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    • 2000
  • A study on the variational characteristics of water quality and phytoplankton biomass by principal component analysis(PCA) was carried out in Kogum-sudo from February to October in 1993. We analyzed PCA on biological factors such as chlorophyll a and phytoplankton cell numbers for centric and pennate diatoms, phytoflagellates, and total phytoplankton as well as physico-chemical factors as water temperature, salinity, transparency, dissolved oxygen(DO), saturation of DO, apparent oxygen utilization (AOU), chemical oxygen demand(COD), nutrient (ammonia, nitrite, nitrate, phosphate and silicate), N/P ratio and suspended solid(SS). The source of nutrients supply depended on the mineralization of organic matters and inputs of seawater from outside rather than runoff of freshwater. The phytoplankton biomass was changed within short interval period by nutrients change. And it was controlled by the combination of several environmental factors, especially of light intensity, ammonia and phosphate. The marine environmental characteristics were determined by the mineralization of organic matters in winter, by runoff of freshwater including high nutrients concentration in spring, by ammonia uptake and high phytoplankton productivity in summer, and phosphate supplied input seawater from outside of Kogeum-sudo in autumn. And Kogum-sudo was separated with 2 regions by score distributions of PCA. That is to say, one region was middle parts of straits which was characterized by the mixing seawater and the accumulated organic matters, other one region was Pungnam Bay and the water around Kogum Island which was done by high phytoplankyon biomass and productivity year-round.

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A Consideration on its Kinetics for shelf-life Prediction of Meat Sausage (축육소시지 저장성 산출을 위한 속도론적 고찰)

  • Kim, Soo-Min
    • Korean Journal of Food Science and Technology
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    • v.24 no.3
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    • pp.256-260
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    • 1992
  • This study was conducted to calculate and predict the shelf-life of meat sausage through physicochemical and biological analysis. Judging from physico-chemical components, it can be found out the most effective indicator in meat sausage. And also, the materials used for packaging is cellulose #23 in inner-packaging and CN/HDPE laminating film in outer-packaging. The changes of the most effective indicator were discussed through the method of kinetic analysis. Judging from physico-chemical components, VBN was the most available component in quality judgement of meat sausage and their upper limiting contents were 20 mg%. It is possible to calculate and predict the shelf-life of meat sausage through the regression equation and $Q_{10}$ value. As a result, the shelf-life prediction was $58{\sim}63$ days at $10^{\circ}C$, $47{\sim}51$ days at $20^{\circ}C$ and 26 days at $40^{\circ}C$, respectively, but the difference between two methods showed about $4{\sim}5$ days. $Q_{10}$ value on the changes contents was 1.35 at acceralated temperature $40^{\circ}C$. The reaction rate of VBN contents could be interpreted as a first order reaction that divided into 2 periods with different reaction rate constants. The corresponding Arrhenius activation energies were 2.959 Kcal/mole and 3.632 Kcal/mole, respectively.

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Pretreatment of Cane Molasses for Production of Bacterial Cellulose and Its Physico-Chemical Properties (미생물 셀룰로오스 생산을 위한 당밀의 전처리 및 생산된 셀룰로오스의 물리화학적 특성)

  • Jung, Ho-Il;Jeong, Jin-Ha;Jeon, Young-Dong;Lee, Na-Ri;Park, Ki-Hyun;Kim, Yong-Gyun;Park, Geun-Tae;Son, Hong-Joo
    • Journal of Life Science
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    • v.19 no.10
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    • pp.1432-1437
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    • 2009
  • The aim of this study is to investigate cane molasses pretreatments for the production of cellulose by Acetobacter sp. V6, which has excellent bacterial cellulose (BC) producing capacity in the shaking culture. Among pretreatments of cane molasses, 1% (w/v) tricalcium phosphate (TP) treatment was more efficient in BC production. The physico-chemical properties of BCs that were produced in static and shaking cultures were also investigated. Although BC had an emulsifying ability, its emulsion stability was low. Water holding capacity (WHC) of BC was high; the WHC of BC produced in static culture was 14 times higher than that of $\alpha$-cellulose. In addition, the viscosity of BC was higher than that of $\alpha$-cellulose. Composition analysis by FT-IR showed no difference in composition between BC and plant cellulose. In the crystallinity analysis by XRD, all BC samples showed crystallinity. All BC samples showed reticulated structures consisting of ultrafine cellulose fibriles. Microfibriles of cellulose from static culture were especially more compact than those of cellulose from shaking culture.

Physico-chemical and biological characteristic analysis of stratified anaerobic granules in a full-scale UASB reactor (실규모 UASB반응조 내부 계층화된 혐기성 그래뉼의 물리화학적 & 생물학적 특성 조사)

  • Jo, Hongmok;Kim, Minsang;Shin, Seung Gu;Cho, Si-Kyung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.4
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    • pp.33-40
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    • 2021
  • In this study, the physico-chemical and biological characteristics of anaerobic granular sludge at different heights of a full-scale UASB reactor (UASBr) were investigated. Granular sludge was taken from 1 m, 2 m, and 3 m above the ground level in the UASBr. The morphological analysis showed that the upper part had bigger granules and the lower part had rounder granules. The ANOVA test confirmed that the mean size and the roundness of the granules had statistically significant difference along the height at 95% confidence level, and there was a significant negative linear relationship between the size and roundness (r=-0.40, p<0.05). A SMA test using acetic, propionic and butyric acids showed that granules from 2 m height had the highest specific methanogenic activity. The EPS contents were also unequal to each height, with 2 m showing the highest content. These findings could be helpful to understand the different characteristics of stratified anaerobic granules in full-scale UASBr and maintain the reactor performance.

A Study on Fire Explosion Characteristics via Physico-chemical Analysis of Petroleum Residues (석유 부산물의 물리화학적 분석을 통한 화재폭발 특성연구)

  • Kim, Hyeonggi;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.30 no.5
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    • pp.556-561
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    • 2019
  • In this study, the physical and chemical analyses of petroleum residues (pyrolized fuel oil, PFO) were conducted and major components were selected to investigate their fire and explosion characteristics. Major component distribution areas of the PFO were identified via the GC-SIMDIS and MALDI-TOF analyses. In addition, the qualitative analysis of major component distribution areas was performed by GC-MS analysis. Major components of pyrolysis residue were selected based on the results of various analyses such as EA, SARA and TGA. As a result, benzene, toluene and xylene were selected as major components. Finally, the process hazard analysis software tool (PHAST) analysis was performed to investigate the range of maximum damage effect in case of fire and explosion. Toluene presented the highest risk due to the radiation effect of $227kW/m^2$ and 118 m in the case of jet fire. Xylene and benzene showed the maximum radiant heat values of 114 and $151kW/m^2$, respectively. It was also confirmed from the analysis of pasquill stability and wind speed that the radiant heat increased up to 55% according to wind speed in benzene, which was considered to be a main factor increasing the influence range.

Physico-chemical Water Quality Gradients Along the Main Axis of the Headwater-to-Downstream of Geumho River and Their Influences on Fish Guilds (금호강의 상.하류간 이.화학적 수질구배 및 이에 따른 어류 길드영향)

  • Kim, Young-Hui;Han, Jeong-Ho;An, Kwang-Guk
    • Journal of Korean Society on Water Environment
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    • v.28 no.4
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    • pp.561-573
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    • 2012
  • The object of this study was to analyze long-term water quality gradients during 1992-2008 at six sites of Geumho River and near-by two sites of Nakdong River and their influences on fish trophic guilds and tolerance guilds along with ecological health. Water quality including biological oxygen demand (BOD), chemical oxygen demand (COD), conductivity, total phosphorus (TP), total nitrogen (TN), and total suspended solids (TSS) varied largely depending on the sampling locations and seasons. Values of ambient BOD, COD, TP, and TN were greater in the downstream than in the upstream reach, and seasonal and interannual variabilities were also higher in the downstreams. This phenomenon was evident due to a dilution by the Asian monsoon rainfall during the monsoon. These outcomes indicate that point sources near the downstream are important for the chemical conditions, but also seasonal stream runoff was considered as an important factor regulating the chemical conditions. Conductivity decreased rapidly during the summer due to ionic dilution, and nutrients (N, P), BOD, COD had an inverse function of seasonal precipitation. Based on the water quality, we selected two sites (control site = $C_s$ vs. impacted site = $I_s$) for impact analysis of water chemistry on fish community and trophic/tolerant guilds. Fish guild analysis showed that species diversity was higher in the headwater stream ($C_s$) than the impacted downstream ($I_s$), and that the proportion of tolerant and omnivore species were greater in the impacted site of downstream. Comparisons of water quality between Geumho River and Nakdong River indicated that Geumho River was considered as a point source which degradated water quality to the Nakdong River. Overall, chemical water quality and fish guild analysis suggest that even if current chemical quality got better after 1996 due to continuous constructions of wastewater disposal plants near the downstreams, fish compositions of tolerant and omnivores were still dominated the community. Thus, biological restoration based on ecological health is required for the ecosystem conservation.