• Title/Summary/Keyword: Physico/chemical processes

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Biochar for soil carbon sequestration (토양탄소격리를 위한 바이오차)

  • Woo, Seung Han
    • Clean Technology
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    • v.19 no.3
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    • pp.201-211
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    • 2013
  • Biochar is charred materials generated during pyrolysis processes in the absence of oxygen using biomass, resulting in high carbon contents. In recent years, biochar has attracted more increasingly due to its potential role in carbon sequestration, renewable energy, waste management, soil amendment for agricultural use, and environmental remediation. Since biochar has a long-term stability in soil for thousands of years, biochar can be carbon negative compared to carbon-neutral biomass energy that decomposes eventually. Moreover, when biochar is applied to soil, crop production can be largely improved due to its high pH and its superior ability to retain water and nutrients. This paper review the research trends of biochar including the principles of carbon sequestration by biochar, its physico-chemical properties, and its applications on agricultural and environmental area.

Research Trend of Membrane Technology for Separation of Carbon Dioxide from Flue Gas (온실기체 분리회수를 위한 막분리기술 연구 동향)

  • 김정훈;임지원;이수복
    • Membrane Journal
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    • v.12 no.3
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    • pp.121-142
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    • 2002
  • The $CO_2$ emission is the largest contribute for the green house effect. Among the existing chemical separation processes, the membrane separation technology is(/will be) the most potential process for $CO_2$, separation from flue gas. Based on the solution-diffusion theory and physical properties of carbon dioxide/nitrogen and the permeation data in the literature, the relationships between physico-chemical structures of polymeric membrane materials and the perm-selectivities for $CO_2$/$N_2$ gases were described in detail. The progress of membrane module and process development was introduced briefly. Finally, the worldwide research activity including South Korea's for carbon dioxide separation by membrane technology were introduced through the survey of papers and technical reports published.

HTPB Propellant Ageing Property and HFC Base Shelf-Life Evaluation Method (HTPB 추진제 노화 특성 및 HFC 기반 수명 평가 기법)

  • Cho, Wonho;Westerlund, M.;Ryoo, Baek-Neung;Jung, Gyoo-Dong;Yoo, Ji-Chang
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.148-153
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    • 2017
  • During natural ageing of HTPB propellant undergoes a series of slow physico-chemical degradation reactions. By using accelerated ageing conditions it is possible to simulate the material behaviour at different time-temperature conditions especially focused on the in-service conditions. Ageing behaviour of HTPB propellant were investigated using HFC(Micro-Heat Flow Calorimeter) is universal technique for measuring the rate of slow chemical and physical processes in long-term storage.

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Generation of novel hyaluronic acid biomaterials for study of pain in third molar intervention: a review

  • Shuborna, Nadia Sultana;Chaiyasamut, Teeranut;Sakdajeyont, Watus;Vorakulpipat, Chakorn;Rojvanakarn, Manus;Wongsirichat, Natthamet
    • Journal of Dental Anesthesia and Pain Medicine
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    • v.19 no.1
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    • pp.11-19
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    • 2019
  • Hyaluronic acid (HA) has long been studied in diverse applications. It is a naturally occurring linear polysaccharide in a family of unbranched glycosaminoglycans, which consists of repeating di-saccharide units of N-acetyl-D-glucosamine and D-glucuronic acid. It is almost ubiquitous in humans and other vertebrates, where it participates in many key processes, including cell signaling, tissue regeneration, wound healing, morphogenesis, matrix organization, and pathobiology. HA is biocompatible, biodegradable, muco-adhesive, hygroscopic, and viscoelastic. These unique physico-chemical properties have been exploited for several medicinal purposes, including recent uses in the adjuvant treatment for chronic inflammatory disease and to reduce pain and accelerate healing after third molar intervention. This review focuses on the post-operative effect of HA after third molar intervention along with its various physio-chemical, biochemical, and pharmaco-therapeutic uses.

HTPB Propellant Ageing Property and HFC Base Shelf-life Evaluation Method (HTPB 추진제 노화 특성 및 HFC 기반 수명 평가 기법)

  • Cho, Wonho;Westerlund, M.;Ryoo, Baekneung;Jung, Gyoodong;Yoo, Jichang
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.5
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    • pp.59-65
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    • 2018
  • During natural aging, hydroxyl-terminated polybutadiene(HTPB) propellant undergoes a series of slow physico-chemical degradation reactions. By using accelerated ageing conditions it is possible to simulate the material behavior at different time-temperatures focusing on in-service conditions. Aging behaviors of HTPB propellant are investigated using HFC(heat flow calorimeter), a universal technique for measuring the rate of slow chemical and physical processes in long-term storage.

Catalytic Oxidation of Aromatic Compounds over Spent Ni-Mo and Spent Co-Mo based Catalysts: Effect of Physico-chemical Pretreatments (폐 Ni-Mo 및 폐 Co-Mo계 촉매상에서 방향족 화합물의 촉매산화: 물리화학적 전처리 효과)

  • Shim, Wang Geun;Kang, Ung Il;Kim, Chai
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.63-70
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    • 2010
  • Transition metal based spent catalysts (Ni-Mo and Co-Mo), which were scrapped from the petrochemical industry, were reused for the removal processes of volatile organic compounds (VOCs). Especially the optimum regeneration procedures were determined using the removal efficiency of VOCs. In this work, the spent Ni-Mo and spent Co-Mo catalysts were pretreated with different physic-chemical treatment procedure: 1) acid aqueous solution, 2) alkali solution, 3) chemical agent and 4) steam. The various characterization methods of spent and its regenerated catalysts were performed using nitrogen adsorption, X-ray diffraction (XRD) and scanning electron microscopy (SEM) equipped with an energy dispersive spectrometry (EDS). It was found that all spent catalysts were found to be potentially applicable catalysts for catalytic oxidation of benzene. The experimental results also indicated that among the employed physico-chemical pretreatment methods, the oxalic acid aqueous (0.1 N, $C_2H_2O_4$) pretreatment appeared to be the most efficient in increasing the catalytic activity, although the catalytic activity of spent Ni-Mo and spent Co-Mo catalysts in the oxidation of benzene were greatly dependent on the pretreatment conditions. The pretreated spent catalysts at optimum condition could be also applied for removing other aromatic compounds (Toluene/Xylene).

A Study on the Granulometry and Chemical Composition of Psudo-Gleized Soil in Jeongdongjin Area (정동진 의사글레이층의 입도와 화학 조성에 대한 연구)

  • Kim, Jong Yeon
    • Journal of The Geomorphological Association of Korea
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    • v.24 no.3
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    • pp.27-45
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    • 2017
  • At the upper part of terrace deposits at Jeongdongjin area, there is a structure in which reddish brown and grayish white layers laying horizontally. Previous studies have reported the existence of these structures within the deposits and suggested the theoretical background related to the formation process. However, the analysis of physical properties and chemical composition such as particle size, classification, etc. of the materials constituting the reddish brown and grayish white layers is scarcely done. In this study, the physico - chemical properties of gray - white and reddish brown beds are investigated. The mean grain size of the particles was less than $4{\varphi}$ in both layers and the reddish brown layer was more coarse. The results shows that the sorting of the grayish white layer is better. The chemical composition of both layers shows that the average concentration of $SiO_2$, $Al_2O_3$ and $K_2O$ of the grayish white layer was higher than those of the reddish brown layer. The concentration of $Fe_2O_3$ of reddish brown lyaer was 3 times higher than those of the grayish white layer. The degree of chemical weathering (CIA) is 90 or so in both the reddish brown and grayish white layers, indicating a significant level of chemical weathering. In conclusion, reddish brown layers had been formed by the processes related to the migration of iron and the migration of water that induced aggregation after the formation of sediments (psudo-gleization). In this study area, a vertical layer of grayish white which cuts off horizontal reddish brown and grayish white color was found. The vertical layer or wedge similar to a ice-wedge or columnar structure that in a cold environment, and there is a difference in shape and size. The vertical layer appears to have occurred three or more cycles. The vertical layers begin to form at a certain height within the outcrop and descend downwards, which of course is difficult to see as directing certain times.

Uranium Occurrences, and Process Development for Recovering Uranium and Vanadium from Uranium Ore in Coaly Meta-Pelites in Ogcheon Terrain, Korea (I) (한반도(韓半島) 옥천대(沃川帶) 탄질이암층중(炭質泥岩層中)의 저품위(低品位) 우라늄광(鑛)의 부존상태(賦存狀態) 및 우라늄, 바나듐 회수공정개발연구(回收工程開發硏究) ( I ))

  • So, Chil-Sup;Choi, Cheong-Song
    • Economic and Environmental Geology
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    • v.17 no.1
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    • pp.35-47
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    • 1984
  • Combined mineralogical and geochemical studies were made on two hundred eighty one representative samples from uraniferous coaly meta-pelites of the Ogcheon metamorphic terrain. Different mineral occurrence of the areas investigated should be taken into account for chemical processes for uranium extraction. Secondary uranium minerals identified are metauranocircite, metatorbernite and autunite. These are disseminated mostly on the laumontites which infused and filled secondary openings in the coaly matrix, and are often closely associated with iron oxides. The uranium distribution show distinctly log normal. Geochemical correlation coefficient of uranium and organic carbon displays +0.624~+0.796. The relationship of the major components to uranium can be expressed by the following regression equation: Log $(U_3O_8{\times}10^4)$=1.40117-0.00076 (quartz) -0.00118 (muscovite) +0.00235 (biotite) +0.00323 (other silicates) - 0.01114 (apatite) +0.01124 (hematite) +0.00149 (limonite) -0.01823 (opaques)+0.03049 (organic carbon). Uranium in the coaly meta-pelites of the Ogcheon Group was deposited together under same physico-chemical environmental conditions. There is a considerable variation in the ${\delta}^{34}S$ values (11.2~16.8 per mil) of the pyrites from the U-bearing meta-pelites, which implies sedimentary origin. The two U-bearing coaly rocks analyzed have ${\delta}^{13}C$ values between -16.88~-18.00 per mil, which suggests organic.

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The Possible Signs of Hydrogen and Helium Accretion from Interstellar Medium on the Atmospheres of F-K Giants in the Local Region of the Galaxy

  • Yushchenko, Alexander;Kim, Seunghyun;Jeong, Yeuncheol;Demessinova, Aizat;Yushchenko, Volodymyr;Doikov, Dmytry;Gopka, Vira;Jeong, Kyung Sook;Rittipruk, Pakakaew
    • Journal of Astronomy and Space Sciences
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    • v.38 no.3
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    • pp.175-183
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    • 2021
  • The dependencies of the chemical element abundances in stellar atmospheres with respect to solar abundances on the second ionization potentials of the same elements were investigated using the published stellar abundance patterns for 1,149 G and K giants in the Local Region of the Galaxy. The correlations between the relative abundances of chemical elements and their second ionization potentials were calculated for groups of stars with effective temperatures between 3,764 and 7,725 K. Correlations were identified for chemical elements with second ionization potentials of 12.5 eV to 20 eV and for elements with second ionization potentials higher than 20 eV. For the first group of elements, the correlation coefficients were positive for stars with effective temperatures lower than 5,300 K and negative for stars with effective temperatures from 5,300 K to 7,725 K. The results of this study and the comparison with earlier results for hotter stars confirm the variations in these correlations with the effective temperature. A possible explanation for the observed effects is the accretion of hydrogen and helium atoms from the interstellar medium.

General Perspectives for Molecular Nuclear Imaging (분자핵의학영상 개관)

  • Chung, June-Key
    • The Korean Journal of Nuclear Medicine
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    • v.38 no.2
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    • pp.111-114
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    • 2004
  • Molecular imaging provides a visualization of normal as well as abnormal cellular processes at a molecular or genetic level rather than at a anatomical level. Conventional medical imaging methods utilize the imaging signals produced by nonspecific physico-chemical interaction. However, molecular imaging methods utilize the imaging signals derived from specific cellular or molecular events. Because molecular and genetic changes precede anatomical change in the course of disease development, molecular imaging can detect early events in disease progression. in the near future, through molecular imaging we can understand basic mechanisms of disease, and diagnose earlier and, subsequently, treat earlier intractable diseases such as cancer, neuro-degenerative diseases, and immunologic disorders. In beginning period, nuclear medicine started as a molecular imaging, and has had a leading role in the field of molecular imaging. But recently molecular imaging has been rapidly developed. Besides nuclear imaging, molecular imaging methods such as optical imaging, magnetic resonance imaging are emerging. Each imaging modalities have their advantages and weaknesses. The opportunities from molecular imaging look bright. We should try nuclear medicine continues to have a leading role in molecular imaging.