• 제목/요약/키워드: Physical Compatibility

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Surface Modification of Polypropylene Membrane by ${\gamma}$ Irradiation Methods and their Solutes Permeation Behaviors

  • Shim, J. K.;Lee, S. H.;Kwon, O. H.;Lee, Y. M.;Nho, Y. C.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.99-101
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    • 1998
  • 1. Introduction : The conventional grafting polymerization technique requires chemically reactive groups on the surface as well as on the polymer chains. For this reason, a series of prefunctionalization steps are necessary for covalent grafting. The surface prefunctionalizational technique for grafting can be used to ionization radiation, UV, plasma, ion beam or chemical initiators. Of these techniques, radiation method is one of the useful methods because of uniform and rapid creation of active radical sites without catalytic contamination in grafted samples. If the diffusion of monomer into polymer is large enough to come to the inside of polymer substrate, a homogeneous and uniform grafting reaction can be carried out throughout the whole polymer substrate. Radiation-induced grafting method may attach specific functional moieties to a polymeric substrate, such as preirradiation and simultaneous irradiation. The former is irradiated at backbone polymer in vacuum or nitrogen gas and air, and then subsequent monomer grafting by trapped or peroxy radicals, while the latter is irradiated at backbone polymer in the presence of the monomer. Therefore, radiation-induced polymerization can be used to modification of the chemical and physical properties of the polymeric materials and has attracted considerable interest because it imparts desirable properties such as blood compatibility. membrane quality, ion excahnge, dyeability, protein adsorption, and immobilization of bioactive materials. Synthesizing biocompatible materials by radiation method such as preirradiation or simultaneous irradiation has often used $\gamma$-rays to graft hydrophilic monomers onto hydrophobic polymer substrates. In this work, in attempt to produce surfaces that show low levels of anti-fouling of bovine serum albumin(BSA) solutions, hydroxyethyl methacrylate(HEMA) was grafted polypropylene membrane surfaces by preirradiation technique. The anti-fouling effect of the polypropylene membrane after grafting was examined by permeation BSA solution.

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Deposition of Tungsten Thin Film on Silicon Surface by Low Pressure Chemical Vapor Deposition Method (저압 화학 기상 증착법을 이용한 실리콘 표면 위의 텅스텐 박막의 증착)

  • Kim, Seong Hun
    • Journal of the Korean Chemical Society
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    • v.38 no.7
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    • pp.473-479
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    • 1994
  • Tungsten thin film was deposited on p-(100) silicon substrate by using the LPCVD(low pressure chemical vapor deposition) technique. $WF_6$ was used as a source gas for tungsten and $SiH_4$ was used as a reducing gas for $WF_6$. Tungsten thin film was deposited by either SiH4 or Si substrate reduction of $WF_6$ under cold-wall condition and it was deposited by $SiH_4$ reduction of $WF_6$ under hot-wall condition. The crystal structure of deposited thin film under both conditions were identified to be bcc (body centered cubic). The physical and electrical properties of deposited thin films were investigated. The deposited film under hot-wall condition changed to $WSi_2$ film by the annealing under $800^{\circ}C.$ From the experimental results and theoretical considerations, the change of the crystal structure of the thin film by annealing was discussed. $WSi_2$ thin film, which was known to have good compatibility with Si substrate, could be produced under hot-wall condition although the film properties were superior under cold-wall condition.

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A Study on the Design Technique of Linear Actuator by using CAE System (전산응용설계 시스템을 이용한 리니어 액츄에이터의 설계기법 고찰)

  • 이권헌;조제황;조경재;오금곤;김영동
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.11 no.1
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    • pp.106-113
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    • 1997
  • In this paper, we introduce the design method using CAE(Computer Aided Engineering) which is profitable in the compatibility and standardization of the developed product and in the reduction of construction time and price to develop and design a machine equipment. Particularly, we select the standard model to design ot develop from the large machinery to the super precision one, extract the peculiar characters of the model by the close analysis of the physical and technical part, can predict the previous result of experimental characteristics on objective dimensions through the analogical mathematical analysis, and can induce the design model demanded by user investigating optimal data in advance. We present the analogical algorithms and process method of design factors and restriction factors in the systematization design with computer. Then we analyze step functions for each systematization equipment and induce the process of technical data with actuator model.

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Educational Insect Robot Content use of play(Game) for the Nuri Process Education of Creative in Smartphone (스마트폰을 활용한 로봇 교육 콘텐츠 게임 활용 연구)

  • Park, Young-suk;Park, Dea-woo
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2013.10a
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    • pp.131-134
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    • 2013
  • Nuri process is a common process of childcare and education for infants to 5 years old in 2012 has been carried out. In order to operate a paint program, teachers not only easy to take advantage in the field, education robot, taking into account developmental compatibility in accordance with stable, physical stability, age psychological infant, the diversity, education robot that can be worn thinking, creativity, scientific thinking is required. In this paper, I will study the applications and Internet services to infants through your favorite smartphones. To the study of development in the smartphone educational insect robot application with the educational environment that infants are environmentally friendly. Utilizing the game smartphone, Nari proceed to step 15, place the questions and answers for enhancing the education effect on the way, to enhance the creative effect of the robot and education. In this paper, I will continue to contribute to the development of content for the education of taste creative.

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Design and Implementation of an Integrated CA-GIS System (CA-GIS 통합시스템의 설계와 구현)

  • 박수홍
    • Spatial Information Research
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    • v.9 no.2
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    • pp.185-206
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    • 2001
  • Cellular Automata(CA) have been investigated and utilized as a theoretical framework and/or methodology for analyzing and simulating the properties and behaviors of many complex systems in various physical science and engineering field. Due to the conceptual elegance and effectiveness of implementing spatio-temporal dynamic models and the compatibility with raster GISs, recently a variety of modeling works using both CA and GIS have been published in GIS fields Most of spatial dynamic models introduced in previous research, however, were very limited and furthermore integrated CA-GIS system for practical modeling purpose are not developed yet. This study aims to develop an integrated CA-GIS system in which a CA simulator is used as an analytical engine for GIS providing a multipurpose spatial dynamic modeling functionalities. This integrated CA-GIS system is anticipated radically enhancing the current lacking dynamic modeling functionalities of GIS and being utilized as an powerful and effective tool for practical spatial dynamic modeling research.

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Characterization of Acryl Polymer Concretes for Ultra Thin Overlays (초박층 덧씌우기용 아크릴 폴리머 콘크리트의 특성 연구)

  • Kim, Dae-Young;Kim, Tae-Woo;Lee, Hyun-Jong;Kim, Hyung-Bae
    • International Journal of Highway Engineering
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    • v.12 no.3
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    • pp.1-8
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    • 2010
  • This study is performed to evaluate the physical and mechanical characteristics of an acryl polymer concrete that is developed as an overlay material for cement concrete slabs and pavements. Various laboratory tests including viscosity, flow, compressive strength, flexural strength, tensile strength, linear shrinkage, thermal expansion and thermal compatibility tests are performed. It is observed from the laboratory tests that the acryl polymer concrete developed in this study satisfies all the requirements suggested by ACI guideline. In addition to the laboratory tests, an accelerated performance testing (APT) is conducted to validate the performance of the acryl polymer concrete. During the APT, no significant distresses are observed until 15,903,939 cycles of equivalent single axle loading is applied. Finally, a 10mm thick overlay with the acryl polymer concrete is applied on top of an old deteriorated concrete pavement to evaluate field performance. Right after the field construction, skid resistance, noise and roughness are measured. The skid resistance and noise level have been significantly improved while the roughness is increased. Periodic investigation for the field study section will be conducted to evaluate the long-term performance.

Wear Particulate Matters and Physical Properties of Silica filled ENR/BR Tread Compounds according to the BR Contents

  • Ryu, Gyeongchan;Kim, Donghyuk;Song, Sanghoon;Lee, Hyun Hee;Ha, Jin Uk;Kim, Wonho
    • Elastomers and Composites
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    • v.56 no.4
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    • pp.243-249
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    • 2021
  • The demand for truck bus radial (TBR) tires with enhanced fuel efficiency and wear resistance have grown in recent years. In addition, as the issue of particulate matter and air pollution increases, efforts are being made to reduce the generation of particulate matter. In this study, we investigated the effect of varying the content of butadiene rubber (BR) on the properties of the rubber compounds and the amount of particulate matter in the TBR tire tread compound. Furthermore, we utilized carbon black in the NR/BR blend compounds owing to its excellent compatibility, and we used silica in the ENR-25/BR blend compounds because it can interact chemically with epoxide groups. The NR/BR blend compounds and the ENR-25/BR blend compounds were evaluated by varying their BR content between 20 phr and 30 phr. The results showed that the ENR-25/BR blend compounds had superior wear resistance than the NR/BR blend compounds. This was caused by the interaction between silica and ENR. In addition, it was confirmed that the increased wear resistance as the BR content increased. Furthermore, compared to the NR/BR blend compounds, ENR-25/BR blend compounds exhibited a lower tan 𝛿 value at 60℃ because silica was used as filler. This indicates a higher fuel efficiency. The measurement results for wear particulate matter showed that as increasing the BR content resulted in generation of less wear particulate matter. This was caused by the increased wear resistance. Moreover, the ENR-25/BR blend compounds with excellent filler-rubber interaction exhibited lower quantities of generated wear particulate matters as compared to the NR/BR blend compounds.

Strategy to increase distortional rigidity of crane box girder: Staggered truss diaphragm

  • Yangzhi Ren;Wenjing Guo;Xuechun Liu;Bin Wang;Piyong Yu;Xiaowen Ji
    • Structural Engineering and Mechanics
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    • v.86 no.4
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    • pp.461-472
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    • 2023
  • This paper proposes a novel method for increasing the distortional frame rigidity of off-rail box girder bridges for cranes by reinforcing the diaphragm with staggered truss. The study starts by using the Matrix Displacement Method to determine the shear angle of the staggered truss diaphragm under two assumptions: hinge joint and rigid joint. To obtain closed-form solutions for the transversal and longitudinal deformations and warping stress of the crane girder, the study employs the Initial Parameter Method and considers the compatibility of shear deformation at joints between the diaphragms and the girder. The theoretical solutions are validated through finite element analysis, which also confirms that the hinge-joint assumption accurately represents the shear angle of the staggered truss diaphragm in girder distortion. Additionally, the study conducts extensive parameter analyses to examine the impact of staggered truss dimensions on distortional stress and deformation. Furthermore, the study compares the distortional warping stresses of crane girders reinforced with staggered truss diaphragms and those reinforced with perforated ones, emphasizing the importance of incorporating stagger truss in diaphragms. Overall, this paper provides a thorough evaluation of the proposed approach's effectiveness in enhancing the distortional frame rigidity of off-rail box girder bridges for cranes. The findings offer valuable insights into the design and reinforcement of diaphragms using staggered truss to enhance the structural performance of crane girders.

Advantages and disadvantages of renewable energy-oil-environmental pollution-from the point of view of nanoscience

  • Shunzheng Jia;Xiuhong Niu;Fangting Jia;Tayebeh Mahmoudi
    • Advances in concrete construction
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    • v.16 no.1
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    • pp.69-78
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    • 2023
  • This investigation delves into the adverse repercussions stemming from the impact of arsenic on steel pipes concealed within soil designated for rice cultivation. Simultaneously, the study aims to ascertain effective techniques for detecting arsenic in the soil and to provide strategies for mitigating the corrosion of steel pipes. The realm of nanotechnology presents promising avenues for addressing the intricate intersection of renewable energy, oil, and environmental pollution from a novel perspective. Nanostructured materials, characterized by distinct chemical and physical attributes, unveil novel pathways for pioneering materials that exert a substantial impact across diverse realms of food production, storage, packaging, and quality control. Within the scope of the food industry, the scope of nanotechnology encompasses processes, storage methodologies, packaging paradigms, and safeguards to ensure the safety of consumables. Of particular note, silver nanoparticles, in addition to their commendable antibacterial efficacy, boast anti-fungal and anti-inflammatory prowess, environmental compatibility, minimal irritability and allergenicity, resilience to microbial antagonism, thermal stability, and robustness. Confronting the pressing issue of arsenic contamination within both environmental settings and the food supply is of paramount importance to preserve public health and ecological equilibrium. In response, this study introduces detection kits predicated upon silver nanoparticles, providing an expeditious and economically feasible avenue for identifying arsenic concentrations ranging from 0.5 to 3 ppm within rice. Subsequent quantification employs Hydride Atomic Absorption Spectroscopy (HG-AAS), which features a detection threshold of 0.05 ㎍/l. A salient advantage inherent in the HG-AAS methodology lies in its capacity to segregate analytes from the sample matrix, thereby significantly reducing instances of spectral interference. Importantly, the presence of arsenic in the soil beneath rice cultivation establishes a causative link to steel pipe corrosion, with potential consequences extending to food contamination-an intricate facet embedded within the broader tapestry of renewable energy, oil, and environmental pollution.

Reduction of Leakage Current and Enhancement of Dielectric Properties of Rutile-TiO2 Film Deposited by Plasma-Enhanced Atomic Lay er Deposition

  • Su Min Eun;Ji Hyeon Hwang;Byung Joon Choi
    • Korean Journal of Materials Research
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    • v.34 no.6
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    • pp.283-290
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    • 2024
  • The aggressive scaling of dynamic random-access memory capacitors has increased the need to maintain high capacitance despite the limited physical thickness of electrodes and dielectrics. This makes it essential to use high-k dielectric materials. TiO2 has a large dielectric constant, ranging from 30~75 in the anatase phase to 90~170 in rutile phase. However, it has significant leakage current due to low energy barriers for electron conduction, which is a critical drawback. Suppressing the leakage current while scaling to achieve an equivalent oxide thickness (EOT) below 0.5 nm is necessary to control the influence of interlayers on capacitor performance. For this, Pt and Ru, with their high work function, can be used instead of a conventional TiN substrate to increase the Schottky barrier height. Additionally, forming rutile-TiO2 on RuO2 with excellent lattice compatibility by epitaxial growth can minimize leakage current. Furthermore, plasma-enhanced atomic layer deposition (PEALD) can be used to deposit a uniform thin film with high density and low defects at low temperatures, to reduce the impact of interfacial reactions on electrical properties at high temperatures. In this study, TiO2 was deposited using PEALD, using substrates of Pt and Ru treated with rapid thermal annealing at 500 and 600 ℃, to compare structural, chemical, and electrical characteristics with reference to a TiN substrate. As a result, leakage current was suppressed to around 10-6 A/cm2 at 1 V, and an EOT at the 0.5 nm level was achieved.