• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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• pp.526-530
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• 2004

We report the space charge and the surface potential of the interface between metal and CuPc according to isotropic property and different metal by measuring the microwave reflection coefficients $S_{11}$ of copper(II)-phthalocyanine(CuPc) thin films by using a near-field microwave microscope(NSMM) in order to understand. CuPc thin films were prepared on gold and aluminium substrates using a thermal evaporation method. Two kinds of CuPc thin films were prepared. One was deposited on preheated substrate at $150^{\circ}C$ and the other was annealed after deposition by using thermal evaporation methods. The microwave reflection coefficients $S_{11}$ of CuPc thin films were changed by the dependence on the heat treatment conditions. By comparing reflection coefficient $S_{11}$ we measured electrical conductivity of CuPc thin films and studied this results with respect to the surface potential and space charge of the interface between metal and CuPc thin films.

• 대한화학회지
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• 제12권3호
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• pp.89-92
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• 1968

基底狀態의 Porphin 核과 Phthalocyanine 核의 電子狀態와 反應性을 理論的으로 考察하였다. 이때 各 ${\pi}$軌道의 energy量과 superdelocalizability 및 結合次數(bond order)는 單純分子軌道法에 依據해서 算出하였다. 이 두 化合物의 경우, 最高被占軌道와 最底空軌道 사이의 energy 差가 一般的인 다른 有機化合物보다 상당히 적었는데, 이것은 곧 이 두 化合物이 勵起되기 쉬운 狀態에 놓여 있음을 뜻한다. 또한 superdelocalizability와 結合次數로서 이 두 化合物의 各 原子位置에서의 親電子的, 親核的 및 radical 反應의 反應性과 結合强度를 各各 決定하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.395-396
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• 2008

Copper-Phthalocyanine (Cu-Pc) thin films of 100nm thickness have been deposited on silicon substrates as the different heating temperatures by thermal evaporation deposition technique. X-ray patterns showed with different temperature conditions at the $2\theta$ range of 5-$55^{\circ}$. The surface roughness of Cu-Pc thin films was investigated by using an atomic force microscope (AFM). A scanning electron microscope (SEM) has been used to characterize the micro-structures and morphologies depended on the substrate temperatures.

• 한국전기전자재료학회논문지
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• 제17권6호
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• pp.641-646
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• 2004

We report the changes of the microwave reflection coefficients S$_{11}$ of copper(II)-phthalocyanine (CuPc) thin films by using a near-field microwave microscope(NSMM) in order to understand the phase transition of CuPc. For a NSMM system, a high-quality microstrip resonator coupled with a dielectric resonator was used. CuPc thin films were prepared on the pre-heated glass substrates using a thermal evaporation method. The reflection coefficients S$_{11}$ of CuPc thin films were changed by the dependence on the substrate pre-heating temperatures. By comparing reflection coefficient S$_{11}$ and crystal structures, we found the phase transition of CuPc thin films from $\alpha$-phase to $\beta$-phase at the substrate heating temperature 200 $^{\circ}C$./TEX>.

• 한국응용과학기술학회지
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• 제14권3호
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• pp.89-95
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• 1997

It is well known that the metallo-phthalocyanine(MPcs) are sensitive to toxic gaseous molecules such as $NO_2$ and also chemically and thermally stable. Therefore, lots of MPcs have been studied for the potential chemical sensor for $NO_2$ gas using quartz crystal microbalance or electrical conductivity. In this study, 2,3,9,10,16,17,23,24-[octa-(dodecyloxy)] copper phthalocyanine and 2,3,9,10,16,17,23,24-[octa-(octyloxy)] copper phthalocyanine were synthesized and their possibility of LB film preparation were tested. It was confirmed by using FT-IR, DSC, NMR, UV-Vis absorption spectroscopy and Elemental Analysis that CuPc derivatives were successfully synthesized. From the ${\pi}$-A characteristics and limiting areas of two CuPc derivatives it was found that the preparation of LB films with these CuPc derivatives is possible.

• Journal of Electrochemical Science and Technology
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• 제10권3호
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• pp.321-328
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• 2019

A new miniaturized all solid-state contact Fe (III)-selective PVC membrane electrode based on Fe (II) phthalocyanine as a neutral carrier was described. The effects of the membrane composition and foreign ions on the electrode performance was investigated. The best performance was obtained with a membrane containing 32% poly (vinyl chloride), 64% dioctylsebacate, 3% Fe (II) phthalocyanine, and 1% potassium tetrakis (p-chlorophenyl) borate. The electrode showed near Nernstian response of $26.04{\pm}0.95mV/decade$ over the wide linear concentration range $1.0{\times}10^{-6}$ to $1.0{\times}10^{-1}M$, and a very low limit of detection $1.8{\pm}0.5{\times}10^{-7}M$. The potentiometric response of the developed electrode was independent at pH 3.5-5.7. The lifetime of the electrode was approximately 3 months and the response time was very short (< 7 s). It exhibited excellent selectivity towards Fe (III) over various cations. The miniaturized all solid-state contact Fe (III)-selective membrane electrode was successfully applied as an indicator electrode for the potentiometric titration of $1.0{\times}10^{-3}M$ Fe (III) ions with a $1.0{\times}10^{-2}M$ EDTA and the direct determination of Fe (III) ions in real water samples.

• 한국염색가공학회지
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• 제29권4호
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• pp.195-201
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• 2017

To study the effect of oxyfluorination on water dispersion of phthalocyanine blue(C.I. pigment blue 15:3), the pigment was oxyfluorinated using various oxygen to fluorine ratio of the reactant gas. After the oxyfluorination of the phthalocyanine blue pigment, no significant change in FT-IR spectra was observed, whereas XPS spectra showed the introduction of oxygen and fluorine containing functional groups. This suggests that the oxyfluorination of the pigment only occurred on the surface of the pigment particle and resulted in no significant change in UV-Vis spectra of the pigment. However, the oxyflurinated pigments showed improved water dispersion, compared to the non-treated pigment. Especially, when the oxygen to fluorine ratio was 47:3, the water dispersion of the oxyfluorinated pigments significantly increased, compared to the non-treated pigments. This suggests that the oxyfluorination of the phthalocyanine blue pigment has a potential to be used as a water dispersion improving method.

• 한국재료학회지
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• 제10권1호
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• pp.7-14
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• 2000

본 연구는 무금속프탈로시아닌 색소계를 이용한 전자사진 감광체의 개발에 관한 것이다. 전하발생물질로서는 각종 형태의 무금속프탈로시아닌을 사용했고, 결합제로서는 각종 폴리머를 사용했으며, 전하이동물질로서는 히드라존유도체나 아연착화합물을 사용했다. 전하발생물질로서 사용한 ${\alpha}-$, ${\beta}-$, x형의 프탈로시아닌중에서는 x형의 무금속프탈로시아닌($x-H_2Pc$)의 경우가 가장 좋은 감도를 보였다. 전하발생물질로서는 $x-H_2Pc$를, 전하수송물질로서는 히드라존유도체를 사용했을 때, 다른 감광체들과 비교하여 73.1%의 높은 $1.50lux{\cdot}sec$의 좋은 감도를 보였다.

• 한국염색가공학회지
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• 제14권1호
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• pp.27-33
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• 2002

The preparations of deodorizing fibers using medal-phthalocyanines have been investigated. The five metal-phthalocyanine derivatives(M-taPc, M=Fe, Co, Ni, Zn, Cu) were prepared in modest to good yields. The metal-phthalocyanine derivative as a deodorant material was introduced to fibers by a dyeing method. The deodorant activity(D.A.) of these deodorizing fibers was measured by chromogenic gas detector tubes. In comparison with untreated fibers, these deodorizing fibers was remarkably effective against $NH_3$ and CH3SH. More than 99% of ammonia can be removed within 20 min. The D.A.(%) of fiber adsorbed M-taPc was more than 80% after 90min.

• 폴리머
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• 제25권5호
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• pp.609-616
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• 2001

본 연구에서는 copper phthalocyanine (CUPc)을 높은 합성 수율로서 성공적으로 합성시킴에 따라 용매를 사용하는 고분자의 합성 분야에 마이크로파 기술의 응용 가능성을 제시하고자 하였다. 가정용 전자레인지의 용기를 개조시키고 마이크로파 출력 조절기를 부착시키는 방법으로 본 실험에 사용되는 가변식 마이크로파 합성 장치를 자체 제작하였다. 화학 분석법, X선 회절장치(XRD), 주사형 전자현미경 (SEM) 및 입도 분석법 (PSA)을 이용하여 재래식 열 공정 및 마이크로파 공정을 사용하여 여러 조건하에서 합성된 시료들의 특성을 비교 분석하였다.