• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 2003.11a
• /
• pp.455-456
• /
• 2003

광화학 스모그 현상을 재현하기 위한 메카니즘은 약 20,000개의 반응식과 수천개의 종이 포함되어야 하므로 자세한 반응 메카니즘을 포함하는 데는 한계가 있다(Dodge, 2000). 최근에 morphecule이라 부르는 대리종(surrogates)을 사용하는 방법(morphecule approach)이 개발되었다. 이 메카니즘은 반응 속도, 생성율, 생성물의 형태를 포함하여 lumped surrogates와 관련된 인자들이 모사하는 전체 시간 중 각 t시간 동안 일정하고 그 시간이후에는 인자들이 변화한다고 가정한다. 또한 특성이 비슷한 유기 화합물의 다양한 그룹을 표현할 때 morphecule이라 부르는 특정 화학종들을 사용한다. (중략)

• Asian Journal of Atmospheric Environment
• /
• v.9 no.4
• /
• pp.259-271
• /
• 2015

This study conducted analyses on biogenic volatile organic compounds (BVOC) emission sources contributing to urban ozone ($O_3$) concentration in Osaka Prefecture, Japan in summer 2010 by using the Weather Research and Forecasting model (WRF) version 3.5.1 and the Community Multiscale Air Quality model (CMAQ) version 5.0.1. This prefecture is characterized by highly urbanized area with small forest area. The contributions of source regions surrounding Osaka were estimated by comparing the baseline case and zero-out cases for BVOC emissions from each source region. The zero-out emission runs showed that the BVOC emissions substantially contributed to urban $O_3$ concentration in Osaka (10.3 ppb: 15.9% of mean daily maximum 1-h $O_3$ concentration) with day-by-day variations of contributing source regions, which were qualitatively explained by backward trajectory analyses. Although $O_3$ concentrations were especially high on 23 July and 2 August 2010, the contribution of BVOC on 23 July (35.4 ppb: 25.6% of daily maximum $O_3$) was much larger than that on 2 August (20.9 ppb: 14.2% of daily maximum $O_3$). To investigate this difference, additional zero-out cases for anthropogenic VOC (AVOC) emissions from Osaka and for VOC emissions on the target days were performed. On 23 July, the urban $O_3$ concentration in Osaka was dominantly increased by the transport from the northwestern region outside Osaka with large contribution of $O_3$ that was produced through BVOC reactions by the day before and was retained over the nocturnal boundary layer. On 2 August, the concentration was dominantly increased by the local photochemical production inside Osaka under weak wind condition with the particularly large contribution of AVOC emitted from Osaka on the day.

• Journal of Environmental Impact Assessment
• /
• v.15 no.3
• /
• pp.193-206
• /
• 2006

Recently, high ozone episode occurred frequently in Korea. Moreover ozone episode occurred not only in the city but also in background area where local anthropogenic sources are not important. It analyzed frequency exceeding 100ppb ozone at air quality monitoring stations in Seoul and rural area during 1995-2004. This paper reports on the use of the Community Multiscale Air Quality (CMAQ) modelling system to predict hourly ozone levels. Domain resolutions of 30km, 10km, 3.333km (innermost) have been employed for this study. Summer periods in June 2004 have been simulated and the predicted results have been compared to data for metropolitan and rural air quality monitoring stations. The model performance has been evaluated with measured data through a range of statistical measures. Although, the CMAQ model reproduces the ozone temporal spatial trends it was not able to simulate the peak magnitudes consistently.

• Journal of Korean Society for Atmospheric Environment
• /
• v.19 no.1
• /
• pp.13-23
• /
• 2003

A local wind model and a three dimensional local environmental model including advection, diffusion, deposition. and photochemical reactions were performed at Gwangyang Bay, Korea, to predict air flow and air pollutants concentrations. A large grid was used, and nesting method was employed for small grid calculation. From the meterological module simulation, we were able to reproduce local wind characteristics such as sea/land winds and mountain/valley winds simulation at Gwangyang Bay. In addition, the concentration module showed high concentration regions at Yosu industrial complex, Gwangyang steel company. and Container anchor. It was also seen that air pollutants were dispersed by sea/land winds. A comparison between the measurement and the prediction of sulfur dioxide and nitric oxide, which are relatively low-reacted pollutants, was performed. However, the measured nitrogen dioxide and ozone concentrations were higher than the simulated ones. Particularly, ozone concentration between 8 a..m. and 8 p.m. agreed well, but the measured ozone during the rest of time were generally higher.

• Journal of Environmental Impact Assessment
• /
• v.8 no.1
• /
• pp.1-16
• /
• 1999

The acid deposition and photochemical modeling study was performed on the Eastern Asia using Regional Acid Deposition Model(RADM). The results of this study show that horizontal distribution of $SO_2$, concentration and dry deposition flux was higher in Beking, Shanghai and central part of Korea. However distribution pattern of sulfate and $O_3$ concentration calculated by RADM were not similar to emission pattern. In daytime, $SO_2$, sulfate and $O_3$ were mixed to whole PBL but in nighttime because of inversion layer these pollutants were suppressed to lower level.

• Journal of Korean Society for Atmospheric Environment
• /
• v.10 no.4
• /
• pp.224-232
• /
• 1994

A new neural network model has been developed to predict short-term air pollution concentration. In addition, a multiple regression model widely used in statistical analysis was tested. These models were applied for prediction of daily maximum ozone concentration in Seoul during the summer season of 1991. The time periods between May and September 1989 and 1990 were utilized to train set of learning patterns in neural network model, and to estimate multiple regression model. To evaluate the results of the different models, several Performance indices were used. The results indicated that the multiple regression model tended to underpredict the daily maximum ozone concentration with small r$^{2}$(0.38). Also, large errors were found in this model; 21.1 ppb for RMSE, 0.324 for NMSE, and -0.164 for MRE. On the other hand, the results obtained from the neural network model were very promising. Thus, we can know that this model has a prominent efficiency in the adaptive control for the non-linear multi- variable systems such as photochemical oxidants. Also, when the recent new information was added in the neural network model, prediction accuracy was increased. From the new model, the values of RMSE, NMSE and r$^{2}$ were 13.2ppb, 0.089, 0.003 and 0.55 respectively.

• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 2003.05b
• /
• pp.347-348
• /
• 2003

대기 중의 질산에 의해 생성되는 질산염은 해염성분이나 토양성분과 만나 조대입자 영역에 머물거나 암모늄과 만나 미세입자로 존재할 수 있다. 미세입자로 존재하는 질산염은 여름철과 같은 광화학 반응이 활발할 때 2차적으로 생성되는 물질로, 반휘발성 특성 때문에 측정하는 과정에서 오차가 발생할 가능성도 크다. Seinfeld (1986)에 의하면 미국의 도심 지역에서 미세입자 중 황산염이나 질산염 등 2차 이온 성분의 비율이 전체 입자의 40∼60 %를 차지한다고 보고되고 있으며, 대표적인 도심 지역인 서울에서도 비슷하다 (강충민 등, 1999). (중략)

• Proceedings of the Polymer Society of Korea Conference
• /
• 2006.10a
• /
• pp.106-107
• /
• 2006

A series of vinyl monomers and their saturated model compounds containing different chromophores were synthesized. These monomers display strong intra-molecular fluorescence quenching, their fluorescence quantum yields and lifetimes are generally lower than those of their model compounds. It was found that the C=C bonds in these monomers played a key role in the intra-molecular quenching, which was confirmed by intermolecular fluorescence quenching and time-resolved fluorescence studies. On the basis of the intra-molecular quenching, a new fluorescence approach can be developed to monitor the process of the polymerization and curing of bismaleimides, which can directly reflect the C=C bond consumption during polymerization and curing.

• Journal of Korean Society for Atmospheric Environment
• /
• v.20 no.E2
• /
• pp.43-52
• /
• 2004

A total of 10 boundary layer sampling events over the Pacific Ocean were analyzed for the purpose of defining the sea-to-air $CH_3$I flux using a mass balance photochemical model. These events were recorded on the National Center for Atmospheric Research (NCAR) C-130 aircraft as part of the Aerosol Charac-terization Experiment (ACE 1). The latitude range, covered by these events, was 2$^{\circ}$ N to 55$^{\circ}$ S. The flux ranges were 4 to 33 nmol m$^{-2}$ day$^{-1}$ , with an average value of 11$\pm$8 nmol m$^{-2}$ day$^{-1}$ . This study also indicated that the current approach to estimate the flux was not systematically different from the sea-air exchange model.

• Korean Journal of Optics and Photonics
• /
• v.10 no.4
• /
• pp.335-341
• /
• 1999

We fabricate acrylamide photopolymer as a holographic recording material and investigrate photobleaching characteristics. To explain the photobleaching kinetics of photopolymer we adopt two models of the Beer-Lambert law and optical transmittance based on rate equations obtained from a simplified energy-band model. The Beer-Lambert law is in good agreement with the experimental results in a first short-time region but not in long-time region. But the optical transmittance model based on rate equations explains the experimental results very well in both short-and long-time regions.