• Corrosion Science and Technology
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• 제19권1호
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• pp.31-36
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• 2020

An efficient wet process approach to modifying natural graphite (NG) electrodes for Li-ion batteries is introduced in this paper. With homogeneous mixing and thermal decomposition of NG with diammonium phosphate ((NH₄)₂HPO₄), phosphorus and nitrogen were successfully incorporated into the surface layer of NG particles. Electron microscopy and X-ray photoelectron spectroscopy analyses demonstrated that the surface was well modified by this process. As a result, the treated NG electrodes exhibited much improved electrochemical performance over pristine NG at two different temperatures: 25 ℃ and 50 ℃. Excellent capacity retention of 95.6% was obtained after 100 cycles at 50 ℃. These enhanced properties were confirmed in a morphology analysis on the cross-sections of the NG electrodes after galvanostatic cycling. The improved cycle and thermal stabilities can be attributed to the surface treatment with phosphorus and nitrogen; the treatment formed a stable solid electrolyte interphase layer that performed well when undergoing Li insertion and extraction cycling.

• 한국작물학회지
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• 제47권2호
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• pp.137-141
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• 2002

Decomposition of green manure is necessary for the nutrient supply in farm soil. Hairy vetch as a green manure is superior to other winter legumes in terms of wintering ability and N accumulation. This experiment was carried out to investigate the decomposition and N release of hairy vetch and its effect on rice production as the following crop in paddy field. Decomposition of hairy vetch placed by soil depth of 0, 10 and 20cm at transplanting time was investigated by mesh bag method, which was enclosed chopped residue in mesh bags. The fate of $^{15}$ N derived from $^{15}$ N-labeled hairy vetch was investigated at harvest in three levels of N fertilization. Grain yield of the transplanted paddy rice cultured with hairy vetch as starter N were compared with that of applying urea as starter N in the field. Hairy vetch residue decomposed very rapidly both in transplanted and dry-seeded paddy field. In transplanted paddy field, hairy vetch residue lost 72-81 % and 86-90% of its weight after one and five month, respectively, as affected by incorporation depth. The C/N ratio of the decomposing vetch residue increased sharply during the early stages and after then, decreased slowly. The amounts of N and P released from the vetch were about 90% and 97% of initial content after one month, respectively. Recoveries of hairy vetch-$^{15}$ N by rice plant were 30.6, 34.6 and 35.7% in 0, 6 and 12 kg urea-N 10 $a^{-l}$ application, respectively, indicating that N fertilization increased the recovery of hairy vetch. $^{15}$ N. Hairy vetch residue incorporated as starter maintained significant N $H_4$$^{+}$-N concentration in soil water of plow layer until effective tillering stage. Grain yield in the plot applied with hairy vetch was not significantly different from that in the plot with urea. We concluded that hairy vetch incorporation could substitute starter N fertilization and showed possibility to reduce N amount of top-dressing.g.g.

• 한국세라믹학회지
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• 제54권2호
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• pp.108-113
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• 2017

The use of aluminum-based coagulants in water pretreatment is being carefully considered because aluminum exposure is a risk factor for the onset of Alzheimer's disease. Lightly burned-dolomite kiln dust (LB-DKD) was evaluated as an alternative coagulant because it contains high levels of the healthful minerals calcium and magnesium. An organic pore forming agent (OPFA) was incorporated to prepare porous granules after OPFA removal through a thermal decomposition process. A spray drying method was used to produce uniform and reproducible spherical granules with low density, since fine dolomite particles have irregular agglomeration behavior in the hydration reaction. The use of fine dolomite powder and different porosity granules led to a visible color change in raw algae (RA) containing water, from dark green to transparent colorlessness. Also, dolomite powders and granules exhibited a mean removal efficiency of 48.3% in total nitrogen (T-N), a gradual increase in the removal efficiency of total phosphorus (T-P) as granule porosity increased. We demonstrate that porous dolomite granules can improve the settling time and water quality in summer seasons for the emergent treatment of excessive algal blooms in eutrophic water.

• 한국환경농학회지
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• 제31권4호
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• pp.308-312
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• 2012

본 연구는 녹비작물-벼 재배 작부체계에서 볏짚과 녹비작물을 전량 회수하여 사료작물로 활용시 농경지 비옥도 관리를 위한 양분수지를 평가하였다. 녹비보리와 헤어리베치 혼파비율에 따른 녹비작물 생산량은 B75H25에서 가장 높게 나타났다. B75H25 처리구의 벼 수량은 NPK 처리구 대비 90%를 보였다. 녹비작물과 볏짚을 전량 회수시 NPK, B100, B75H25, B50H50, B25H75, H100 처리구의 질소 수지는 각각 2.0, -80.8, -104.0, -93.5, -82.9, 76.2 kg N/ha 이었다. 그리고 질소 수지가 가장 낮은 B75H25 처리구의 인산수지는 -50.3 kg P/ha로 가장 낮았다. 따라서 녹비작물-벼 재배 작부체계에서 녹비작물과 볏짚을 전량 사료로 활용시 농경지 비옥도 유지를 위해서 각각 약 90 kg N /ha, 50 kg P/ha의 질소와 인산 시비가 필요한 것으로 나타났다. 그리고 금후 녹비작물을 사료로 활용하고자 할 경우 화학비료 시용량과 적정 녹비작물의 회수량에 관한 연구가 필요한 것으로 판단된다.

• 한국토양비료학회지
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• 제47권6호
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• pp.586-593
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• 2014

Newly reclaimed tidal land is known to be in low status of soil fertility. The incorporation of crop residue is an effective method to improve soil properties and fertility in reclaimed saline soils. The objective of this study was to evaluate the efficiency of rice straw (RS) application to improve physico-chemical properties of saline-sodic soil and its contribution to productivity of whole crop barley. Increasing rate of rice straw improved growth parameter related to yield of whole crop barley, which increased tiller number significantly (p<0.05).The yield increased by 15% (F.W) and 9% (D.W) in rice straw-amended plots. The content of soil organic matter (SOM) in the surface soil (0-20cm) with rice straw incorporation increased by 5~9% (RS 2.5~RS 7.5) compared to RS 0, in which the content of SOM decreased after two consecutive cultivations. Rice straw incorporation promoted soil physico-chemical properties and nutrient-availability of the test crop, as indicated in change in soil bulk density, porosity and increased nutrient uptake of plant. Especially, the P content and uptake of whole crop barley increased with increasing the rate of rice straw application. In conclusion, the rice straw application at rates of $5.0-7.5ton{\cdot}ha^{-1}$ in reclaimed saline soils effectively improved soil properties and crop productivity, which has potentials to reduce the loss of chemical fertilizers and facilitate the favorable condition for crop growth under adverse soil condition.

• 한국작물학회지
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• 제47권2호
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• pp.132-136
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• 2002

The rice straw managements are essential for maintaining soil fertility as well as reducing chemical fertilizer application in paddy field. A field experiment was conducted on moderately well draining alluvial paddy soil to investigate the decomposition pattern of rice straw. The mesh bags containing the rice straw harvested in the previous year were placed at soil surface and buried into around 10cm depth and recovered periodically for determining the straw decomposition. Pot experiments were conducted to investigate the fates of N released from $^{15}$ N-labeled rice straw under different levels of N fertilizer application. The overall decomposition patterns of rice straw were similar for the two incorporation depths in transplanted paddy field. The straw incorporated at transplanting date showed weight loss of about 50%, 70% and 90% after 2 months, 5 months, and 2 years, respectively. The decompositions of straw cell wall components showed somewhat different pattern. The decompositions of cellulose and silica were similar to that of dry weight while the decomposition of lignin was slower than that of cellulose and silica. N was released from rice straw 42% and 65 % of the initial N after one month and after five months, respectively. P release was faster than N release. Recoveries of rice straw-$^{15}$ N by rice plants were 10.2, 13.4 and 14.9% in 0, 120 and 240 mg N pot$^{-1}$ , respectively. Soil recoveries of rice straw $^{15}$ N were 17.3, 20.6 and 18.9% in 0, 120 and 240mg N pot$^{-1}$ , respectively.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2011년도 학술발표회
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• pp.191-191
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• 2011

우리나라의 수질 관리는 점오염원 관리에 집중되어 왔다. 수계의 수질이 크게 향상되지 않는 이유는 점오염원의 관리가 엄격히 수행되고 있는 가운데 비점오염원의 영향이 큰 것으로 판단되었다. 본 연구에서는 수문수질 모의가 가능한 SWAT (Soil and Water Assessment Tool) 모형을 이용하여, 비점오염원 저감을 위한 BMP (Best Management Practice) 시나리오를 작성하여 비점오염 부하량의 저감효과를 모의하였다. SWAT 모형의 적용성 평가를 위해 충주댐 유역 ($6,585.1km^2$)을 대상으로 민감도 분석을 통해 최적의 유출 및 유사관련 매개 변수를 선정하였으며, 1998년 부터 2003년까지의 기간 동안 일별 유출, 월별 수질자료에 대한 보정 및 검증을 실시하였다. 전체 17개 소유역에 대한 검보정에 의해 산정된 수질자료인 TN (Total Nitrogen), TP (Total Phosphorus) 그리고 sediment의 부하량을 파악하여 소유역별 TN, TP, Sediment 오염부하특성을 파악하였고, 이에 대하여 선정한 7개의 BMP 시나리오를 소유역의 오염 특성에 맞게 적용하였다. 선정한 BMP 시나리오로는 Streambank stabilization, Porous gully plugs, Recharge structures, Conservation tillage, Terrace, Contour farming 그리고 Manure incorporation이 있고 각 시나리오는 흐름에서의 침전물 감소, 단기간의 토양침식 저감, 지하수양의 증가, 경작지의 침식감소, 지표유출 저하, 흐름에서의 영양물질 감소를 목적으로 최적의 매개변수를 설정하였다. 이상의 결과를 종합적으로 고찰해 볼 때 SWAT 모형은 실측자료를 바탕으로 비점오염에 의한 하천수질 모의가 가능하며, 이 결과를 가지고 BMP시나리오를 적용하여 비점오염 저감에 따른 하천수질 개선을 기대할 수 있다.

• Journal of Nutrition and Health
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• 제4권4호
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• pp.39-46
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• 1971

Iso-butyl bromide의 합성을 시작으로 D.L-1-amino-3-methylbutylphosphonic acid의 합성을, Diethyl phophite의 합성을 시작으로 D.L-1-amino-2-phenyl ethylphosphonic acid의 합성을 하였다. 합성되어진 필수 아미노산인 Isoleucine analogue phosphonic acid는 각각 0.2%, 0.4%를 식이에 첨가했고 Phenylalanine analogue phosphonic acid는 0.35%와 0.7%를 각각 첨가하였으며 Standard-1과 Standard-2군과 비교군인 Isoleucine 0.2%와 0.4% Phenylalanine 0.35%와 0.7%군으로써 총 100마리의 숫쥐로 각 7주씩 14주의 사육 실험을 하였다. 동물 사육 기간내의 뇨채취와 사육후의 각 장기의 채취로써 총 질소와 P, glycogen측정을 시도하였다. 이러한 일련의 실험결과 (1) D.L-1-amino-3-methylbuthylphosphonic acid나D.L-1-amino-2-phenylethylphosphonic acid의 유기 합성에 있어서는 다 수율이 낮고 상당히 높은 융점을 보였으며 ${\alpha}-NH_2$기가 Ninhydrin 반응에 예민했다. (2) Aminophosphonic acid의 첨가군(D.L-1-amino-3-methylbutyl phosphonic acid, D.L-1-amino-2-Phenylethylphosphonic acid)에서나 Amino acid(Isoleucine, Phenylalanine)첨가군에 있어서 모든 장기의 무게, 총체내질소 보유율, 간장내 총단백질량과 인의양, 및 뇨를 통한 인의 배설량에 각각 큰 차이를 보이지 않았다. 이로 보아서 Phenylalanine Aminophosphonic acid나 Isoleucine aminophosphonic acid가 다 보통 아미노산인 Isoleucine이나 Phenylalanine에 못지않게 체내에서 이용됨이 밝혀졌다. (3) 그러나 Phenylalanine aminophosphonic acid 첨가군이 간의 glycogen 함량에 있어서 Phenylalanine 첨가군과 Standard군과 비교해 보았을때 높았으며 이는 통계적인 유의성을 나타냈다.(<0.05) 이는 Phenylalanine Aminophosphonic Acid가 active state로써 간내에서 쉽게 이용되어서 Tricarboxylic cycle의 intermediate로 incorporate되는 경향으로 생각 할 수 있다.