• Title/Summary/Keyword: Phosphorous removal

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Assessment of Field Applicability of a Zero Discharge and Reuse System (무방류 재이용 시스템 현장 적용성 평가)

  • Cho, Kyung-Sook;Lee, Kwang-Ya
    • Current Research on Agriculture and Life Sciences
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    • v.29
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    • pp.75-81
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    • 2011
  • This study performed field examinations of a zero discharge and reuse system developed by Hong and Choi(2009). The system installed one of villages located in Hyoryeong-myeon, Gunwee-gun for the experiments. The zero discharge and reuse system consists of anoxic, FES (Ferrous Electricity System), Oxic, Cralifier processes for water treatments. The main feature of the system is to remove phosphorous by using Fe-ionizing module within the FES process. The water purification performances of the system were evaluated, while any defects for using the system were investigated through the field monitoring. It was found that the removal capacities of T-P, T-N, and BOD of the system meet the required water quality with outstanding performance from T-P by obtaining the results of over 90 % removal rates. The efficiency of T-P removal rate of the system found to be greatly influenced by whether using an automatic washing system to the Fe-ionizing module and conducting replacement of iron plate within a proper period.

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TNT and Nutrients Removal in the Constructed Wetlands

  • Park, Jong-Kyu;Kim, Se-Kyoung;Song, Keun-Yea;Kang, Su-Jin;Kim, Tak-Soo;Kang, Ho-Jeong;Zoh, Kyung-Duk
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2003.06a
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    • pp.199-203
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    • 2003
  • This study was carried out to investigate the removal of 2,4,6-trinitrotoluene, nutrients such as nitrogen, phosphorous compounds in the wetland microcosms. Microcosm study indicated that TNT nutrients were more lastly reduced in the anaerobic condition. The major reductive transformation products included 2,4diamino-6-nitrotoluene (2,4-DANT) 2,6diamino-4-nitrotoluene (2,6-DANT) 4diamino-2,6-nitrotoluene (4-ADNT) 2diamino-4,6-nitrotoluene (2-ADNT). The experimental results for nitrogen removal showed that denitrification kom NO$\sub$3//$\^$-/ to NH$_3$ was dominant process at the bottom of marsh, but nitrification from NH$_3$ to NO$\sub$3//$\^$-/ was dominant on the top of marsh.

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Development and Application of Modified Intermittently Aeration mode for Advanced Phase Isolation Ditch (APID) process at Winter Season (APID공정 내 동절기 개량형 간헐포기 운전모드 적용 및 개발)

  • Kwak, Sung-Keun;An, Sang-Woo;Chung, Mu-Keun;Park, Jae-Ro;Park, Jae-Woo
    • Journal of Korean Society on Water Environment
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    • v.25 no.6
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    • pp.872-878
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    • 2009
  • Advanced Phase Isolation Ditch (APID) process was studied to develop economic retrofitting technology, for the plants where retrofitting of common activated sludge process is required. In this study, to develop and apply the modified intermittently aeration mode as process control conditions for treating municipal wastewater, a demonstration plant was installed and operated in the existing sewage treatment plant of P city. During this study, the average effluent $BOD_5$, SS, T-N, and T-P concentrations were 6.3, 4.5, 10.0, and 1.3 mg/L. The modified mode decreased the nitrification capability more than the conventional mode in the application period. Nitrate in the anaerobic condition can have a negative effect on biological phosphorus removal. In the decreasing nitrate levels, the modified mode increased the biological ability of removal phosphorus more than the conventional mode in this study. Therefore, newly developed APID process with modified intermittent aeration mode can be one of the useful processes for stable organic matter and nutrients removal.

Evaluation of treatment efficiencies of pollutants in daecheong lake juwon stream constructed wetlands (대청호 주원천 인공습지의 오염물질 정화효율 평가)

  • Kim, Tae-Hun;Sung, Ki-Eun;Ha, Duk-Ho;Kim, Dong-Hee;Heo, Soon-Uk;Choi, Chung-Sik
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.2
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    • pp.211-222
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    • 2015
  • This study focused on evaluating the efficiency of the removal of non-point source pollution by Daecheong Lake Juwon Stream constructed wetlands. The constructed wetland system is a surface flow type designed in the year 2007 for purifying eutrophic water of Daecheong Lake Juwon Stream. The value of conductivity, suspended solids(SS), chemical oxygen demand using a potassium permanganate($COD_{Mn}$), five-day biochemical oxygen demand($BOD_5$), total nitrogen(T-N), total phosphorous(T-P), and pH in inflow averaged 220.2, 2.46, 3.33, 1.34, 2.00, 0.04 mg/L and 7.24, respectively and in outflow averaged 227.9, 1.12, 3.34, 0.87, 1.16, 0.02 mg/L and 7.45, respectively. The average removal efficiency of constructed wetlands was 30 % for SS, 22 % for $BOD_5$, 45 % for T-N and 31 % for T-P. The removal rates of SS, $BOD_5$ and T-N in the spring, summer and autumn were higher than those in winter. The removal rate of T-P was not significant different in all seasons. The amounts of pollutants removal in the constructed wetlands were higher in the order of $3^{rd}$ < $2^{nd}$ < $1^{st}$ wetland for SS and T-P, $2^{nd}$ < $3^{rd}$ < $1^{st}$ wetland for $BOD_5$ and T-N. Therefore, our findings suggest that the constructed wetlands could well treat the eutrophic Daecheong Lake Juwon Stream waters.

M-dephanox Process with Rotating Biological Contactor (RBC) in Nitirification Reactor (회전원판형 질화조를 이용한 M-dephanox 공정)

  • Kim, Keum-Yong;Kang, Min-Koo;Shin, Gwan-Woo;Kang, Jung-Kyu;Shin, Min-Su;Kang, Han-Sol;Lee, Sang-Ill
    • Journal of Korean Society on Water Environment
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    • v.29 no.1
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    • pp.1-6
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    • 2013
  • This study was focused on improving nitrification efficiencies of M-dephanox (Modified-Dephanox) process. Rotating biological contactor (RBC) was used instead of floating sponge type media in nitrification reactor. High ammonia removal efficiencies were observed in nitrification reactor, regardless of organic loading from contactor of M-dephanox process. Denitrification efficiencies were also increased to maintain low $NO_3-N$ concentration in effluent. This enhanced phosphate release in anaerobic contactor and resulted in high removal efficiencies of phophorus. Average removal efficiencies of $TCOD_{Cr}$ and $SCOD_{Cr}$ were 93.8% and 81.6%, respectively, while those of TKN and ${NH_4}^+-N$ were 80.9% and 74.4%, respectively. As for phosphorous treatment, the average removal efficiencies of TP and OP were 94.7% and 94.3%, respectively. Also, effect of operating temperature on nitrogen removal was examined. Average removal efficiency of TN was 65.8 % at $15^{\circ}C$ or below (at average temperature of $13.3^{\circ}C$), while that was 82.8% at $15^{\circ}C$ or above (at average temperature of $21.9^{\circ}C$).

Fate and mass balance of pharmaceuticals of unit processes in a sewage treatment plant (하수처리시설 단위공정별 잔류의약물질 거동 및 물질수지 분석)

  • Park, Junwon;Kim, Changsoo;Lee, Wonseok;Lee, Soo-Hyung;Chung, Hyenmi;Jeong, Dong-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.5
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    • pp.367-377
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    • 2019
  • In this study, the fate and removal of 15 pharmaceuticals (including stimulants, non-steroidal anti-inflammatory drugs, antibiotics, etc.) in unit processes of a sewage treatment plant (STP) were investigated. Mass loads of pharmaceuticals were 2,598 g/d in the influent, 2,745 g/d in the primary effluent, 143 g/d in the secondary effluent, and 134 g/d in the effluent. The mass loads were reduced by 95% in the biological treatment process, but total phosphorous treatment did not show a significant effect on the removal of most pharmaceuticals. Also, mass balance analysis was performed to evaluate removal characteristics of pharmaceuticals in the biological treatment process. Acetaminophen, caffeine, acetylsalicylic acid, cefradine, and naproxen were efficiently removed in the biological treatment process mainly due to biodegradation. Removal efficiencies of gemfibrozil, ofloxacin, and ciprofloxacin were not high, but their removal was related to sorption onto sludge. This study provides useful information on understanding removal characteristics of pharmaceuticals in unit processes in the STP.

Granulation of Artificial Zeolite for the Simultaneous Removal of Nitrogen and Phosphorous from the Wastewater (질소, 인 동시 제거용 입상 인공제올라이트 제조)

  • Lee, Deog-Bae;Lee, Kyeong-Bo;Han, Sang-Soo;Henmi, Teruo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.1
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    • pp.67-71
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    • 1998
  • This study was carried out to granulate artificial zeolite powder that remove ammonium nitrogen and phosphorous simultaneously in wastewater treatment. Optimum water content was required for 30 percent volume to granulate artificial zeolite with 1.7mm diameter and 1~2cm length using granulator. Portland cement could remove much $NH_4{^+}$ and $PO_4{^{3-}}$ from the wastewater than other binding materials. Mixed 33, 25. 20. 16 percent of portland cement to artificial zeolite powder(v/v), cation exchange capacity of the granulars were 66.5, 81.4, 126.8, $151.2cmol^+kg^{-1}$ and hardness of that were 176.1, 24.4, 4.1, $0.4kg\;cm^{-2}$, respectively. Content of portland cement in the granular were related with removal of $PO_4{^{3-}}$ positively and that of $NH_4{^+}$ negatively. Shaked 1g of the granulars that made of portland cement 33 percent with 40ml synthetic wastewater containing $NH_4{^+}$ $1545mgl^{-1}$ and $PO_4{^{3-}}$ $417mgl^{-1}$, 99.4 percent of $NH_4{^+}$ and 90.3 percent of $PO_4{^{3-}}$ were removed simultaneously after 48 hours shaking. The longer shaking, the more $NH_4{^+}$ and $PO_4{^{3-}}$were removed. The artificial zeolite granular had both micropore and macropore that could be useful in the wastewater purification.

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Magnetite for phosphorus removal in low concentration phosphorus-contained water body

  • Xiang, Heng;Liu, Chaoxiang;Pan, Ruiling;Han, Yun;Cao, Jing
    • Advances in environmental research
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    • v.3 no.2
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    • pp.163-172
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    • 2014
  • Magnetite was chosen as a typical adsorbent to study its phosphate adsorption capacity in water body with low concentration of phosphorus (below $2mg\;PL^{-1}$). Magnetite was collected from Luoyang City, Henan Province, China. In this research, three factors have been studied to describe the adsorption of phosphate on magnetite, which was solution concentration (concentration ranging from 0.1 to $2.5mg\;PL^{-1}$), suspension pH (1 to 13) and temperature (ranging from $10^{\circ}C$ to $40^{\circ}C$). In addition, the modified samples had been characterized with XRD and FE-SEM image. The results show that iron ions contains in magnetite were the main factors of phosphorus removal. The behavior of phosphorus adsorption to substrates could be fitted to both Langmuir and Freundlich isothermal adsorption equations in the low concentration phosphorus water. The theoretical saturated adsorption quantity of magnetite is 0.158 mg/g. pH has great influence on the phosphorus removal of magnetite ore by adsorption. And pH of 3 can receive the best results. While temperature has little effect on it. Magnetite was greatly effective for phosphorus removal in the column experiments, which is a more practical reflection of phosphorous removal combing the adsorption isotherm model and the breakthrough curves. According to the analysis of heavy metals release, the release of heavy metals was very low, they didn't produce the secondary pollution. The mechanism of uptake phosphate is in virtue of chemisorption between phosphate and ferric ion released by magnetite oxidation. The combined investigation of the magnetite showed that it was better substrate for water body with low concentration of phosphorus.

Changes in Pollutant Concentrations by Artificial Floating Island Installed in Reservoir for Irrigation (농업용 저수지에 설치한 인공식물섬에 의한 오염물질 농도의 변화)

  • Yang, Hongmo
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.9 no.2
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    • pp.23-32
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    • 2006
  • Total suspended solids (TSS), five-day biochemical oxygen demand ($BOD_5$), total nitrogen (T-N), and total phosphorous (T-P) concentrations around and under a floating island were examined from October 2002 to September 2003. The island was installed in July 2002 on the surface of an agricultural irrigation reservoir located in the southern part of the Korean Peninsula. It was composed of six polyethylene panels. Each panel was 2 m (length) ${\times}$ 1 m (width) ${\times}$ 0.02 m (thick) and had about thirty-two holes each with a diameter of eight centimeters, through which plant roots grew down into the water. Coconut fibers of nine-centimeters in height were placed on the panel, which sustained plants rhizomes and roots. Both the fibers and the panel were raped with polyethylene wire mashes. About thirty irises (Iris pseudoacorus) were planted into the fibers of each panel. The concentrations of TSS, $BOD_5$, T-N and T-P below the island during the iris-growing season averaged 9.70, 2.59, 3.61 and 0.14 mg/L, respectively and those around it averaged 9.99, 2.83, 4.07 and 0.16 mg/L, respectively. The average concentrations of TSS, $BOD_5$, T-N and T-P below it during the iris non-growing season were 8.68, 2.37, 3.25 and 0.14 mg/L, respectively and those near it were 8.76, 2.43, 3.34 and 0.15 mg/L, respectively. At a significance level of ${\alpha}$=0.05, $BOD_5$, T-N and T-P concentrations under the island during the iris-growing season were significantly low when compared with those around it except TSS. No differences in TSS, $BOD_5$, T-N and T-P concentrations between around and near it were found at a significance level of ${\alpha}$=0.05 during the iris non-growing season. The removal of $BOD_5$, T-N, and T-P during the growing season were significantly high when compared with those during the non-growing season. TSS abatement of the floating island was very low during both the growing and non-growing seasons. The island's reductions of $BOD_5$, T-N and T-P were good during the growing season, especially T-N and T-P, which have been considered as primary pollutant sources causing the water quality degradation of reservoirs. The removal of T-N and T-P was primarily attributed to the absorption of nitrogen and phosphorous by the irises during the growing season.

Phosphorus removal from dewatering centrate in wastewater treatment by struvite formation (스트루바이트 생성을 통한 하수슬러지 탈수여액 내 인 제거)

  • Kim, Sang-Hyoun;Park, Jong-Hun;Ju, Hyun-Jun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.2
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    • pp.71-78
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    • 2013
  • This study examined the feasibility of phosphorus removal from dewatering centrate/filtrate in wastewater treatment by struvite formation. Since dewatering centrate/filtrate obtained after anaerobic digestion contains a high content of ammonia, magesium addition and pH adjustment could remove phosphorous. The optimum magnesium dose, reaction time, settling time, and pH value was found at 2 mol Mg/mol $PO_4^{3-}$, 10 min, 120 min, and 8.5, respectively. A bench-scale continuous operation at the optimum condition showed 80% of total phosphorus removal and 82% of phosphate removal in dewatering centrate. The elemental composition and crystal structure of the chemical precipitate was similar to the reported values of struvite.