• 제목/요약/키워드: Phosphorescence

검색결과 110건 처리시간 0.024초

Electrical Characteristics of Green Emitting Phosphor $Ir(PPY)_3$ Doped OLEDs

  • Kim, Jun-Ho;Kim, Yun-Myung;Ha, Yun-Kyung;Kim, Young-Kwan;Kim, Jung-Soo
    • KIEE International Transactions on Electrophysics and Applications
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    • 제11C권3호
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    • pp.53-57
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    • 2001
  • The organic light-emitting devices (OLEDs) based on fluorescence have low efficiency due to the requirement of spin-symmetry conservation. By using the phosphorescent material, internal quantum efficiency can reach 100%, compared with 25% in the case of the fluorescent material. Thus, phosphorescent OLEDs have recently been extensively studied and shown higher internal quantum efficiency than the conventional OLEDs. In this study, we investigated the characteristics of the phosphorescent OLEDs with the green emitting phosphor, $Ir(ppy)_3$ (tris(2-phenylpyridine)iridium). The device with a structure of ITO/TPD$Ir(ppy)_3$ doped in BCP/BCP/$Alq_3$/Li:Al/Al was fabricated, and its electrical and optical characteristics were studied. By changing the doping concentration of $Ir(ppy)_3$, we fabricated several devices and investigated their characteristics.

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발광층 두께가 삼층 구조 청색 인광 OLED의 효율 특성에 미치는 영향 (Effects of Emission Layer Thickness on the Efficiency of Blue Phosphorescent Organic Light Emitting Diodes with Triple Layer Structure)

  • 서유석;문대규
    • 한국전기전자재료학회논문지
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    • 제23권2호
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    • pp.143-147
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    • 2010
  • We have fabricated simple triple-layer blue-emitting phosphorescent organic light emitting diodes (OLEDs) using different thicknesses of N,N'-dicarbazolyl-3,5-benzene (mCP) host layers doped with bis[(4,6-di-fluorophenyl)-pyridinate-N,$C^{2'}$]picolmate (FIrpic) guest materials. The thicknesses of mCP:FIrpic layers were 5, 10, and 30 nm. Driving voltage, current and power efficiencies were investigated. The current efficiency was higher in the 10 nm thick mCP:FIrpic device, resulting from the better electron-hole balance. The device with 10 nm mCP:FIrpic layer exhibited the maximum current efficiency of 22.5 cd/A and power efficiency of 7.4 lm/W at a luminance of 1000 cd/$m^2$.

축광 성능을 갖는 고압용 장거리 호스 개발에 관한 연구 (The Development of High Pressure Long Distance Fire-fighting Hose with Phosphorescent Performance)

  • 한용택;나병균;최진성;민세홍
    • 한국화재소방학회논문지
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    • 제31권5호
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    • pp.63-69
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    • 2017
  • 본 연구에서는 초고압 펌프의 개발과 같이 사용할 수 있는 초고압용 장거리 호스 개발에 관한 연구이며, 접근과 방수거리의 도달이 어려운 초고층 건물 및 대심도 터널의 화재진압에 효율적으로 적용이 가능함과 동시에 축광 성능을 포함하여 소방관의 화재 진압 시 퇴로 확보에도 도움이 될 수 있는 초고압용 호스의 개발에 관한 연구이다. 호스의 성능으로서 압력 3 MPa, 유량 2000 lpm을 목표로 초고압 호스를 개발하였으며, 2중의 자켓과 3중의 폴리우레탄 코팅 및 52의 경사를 사용하여 매우 촘촘하고 높은 고압에도 견딜 수 있는 초고압 소방호스를 개발하였다. 개발된 초고압 호스의 성능을 확보하기 위하여 구조 및 외관, 고압에서의 누수, 길이, 신장률, 박리시험, 마찰시험, 파단압시험 및 자유낙하 시험 등이 공인된 인증기관에서 수행되었으며 수행결과 성능에 이상이 없는 것으로 파악되었다. 또한 소방관의 화재진압 시 퇴로를 확보하기 위한 축광 성능의 초고압 호스에 추가하여 연구 및 개발하였으며, 휘도시험의 값으로 축광의 발광시험 개시부터 40분 후까지 휘도 측정치가 휘도시험의 기준 값 이상으로 충분히 확보되는 것을 확인할 수 있었다. 향후, 이와 같은 초고압용 소방용 호스가 상용화가 되어 현장에서 적용된다면 초고층 건물의 화재진압 및 장대터널에서의 화재진압에 있어서 현재 사용되고 있는 소방호스 보다 개선된 화재 진압 및 안전한 퇴로를 확보하는 측면에서 기여할 수 있을 것으로 판단된다.

Highly Efficient Phosphorescent White Organic Light-Emitting Devices with a Poly(N-vinylcarbazole) Host Layer

  • Kang, Min-Ki;Moon, Dae-Gyu
    • Transactions on Electrical and Electronic Materials
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    • 제12권2호
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    • pp.80-83
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    • 2011
  • We have fabricated phosphorescent white organic light-emitting devices (WOLEDs) with a spin-coated poly(Nvinylcarbazole) [PVK] host layer. Iridium(III) bis[(4,6-difluorophenyl)-pyridinato-N,$C^{2'}$]picolinate (FIrpic), tris(2-phenylpyridine)iridium(III) [$Ir(ppy)_3$], and tris(2-phenyl-1-quinoline)iridium(III) [$Ir(phq)_3$], were used as the blue, green, and red guest materials, respectively. The PVK was mixed with FIrpic, $Ir(ppy)_3$, and $Ir(phq)_3$ molecules in a chlorobenzene solution and spin-coated in order to prepare the emission layer; 3-(4-biphenylyl)-4-phenyl-5-(4-tertbutylphenyl)-1,2,4-triazole (TAZ) was used as an electron transport material. The resultant device structure was ITO/PVK:FIrpic:$Ir(ppy)_3:Ir(phq)_3$/TAZ/LiF/Al. The electroluminescence, efficiency, and electrical conduction characteristics of the WOLEDs based on the doped PVK host layer were investigated. The maximum current efficiency of the three wavelength WOLED with the doped PVK host was 19.2 cd/A.

청색 인광 유기EL 소자를 위한 wide-gap 재료의 제작 및 특성 (Properties of Wide-Gap Material for Blue Phosphorescent Light Emitting Device)

  • 전지연;한진우;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 춘계학술대회 및 기술 세미나 논문집 디스플레이 광소자
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    • pp.36-36
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    • 2008
  • Organic light-emitting device (OLED) have become very attractive due to their potential application in flat panel displays. One important problem to be solved for practical application of full-color OLED is development of three primary color (Red, Green and Blue) emitting molecule with high luminous operation. Particularly, the development of organic materials for blue electroluminescence (EL) lags significantly behind that for the other two primary colors. For this reason, Flu-Si was synthesized and characterized by means of high-resolution mass spectro metry and elemental analyses. Flu-Si has the more wide optical band gap (Eg = 3.86) than reference material (Cz-Si, Eg = 3.52 eV). We measured the photophysical and electrochemical properties of Flu-Si. The HOMO-LUMO levels were estimated by the oxidation potential and the onset of the UV-Vis absorption spectra. The EL properties were studied by the device fabricated as a blue light emitting material with FIrpic.

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정공수송층에 따른 백색 OLED의 발광 특성 (Emission Characteristics of White OLEDs with Various Hole Transport Layers)

  • 임병관;서정현;주성후;백경갑
    • 한국전기전자재료학회논문지
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    • 제23권12호
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    • pp.983-987
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    • 2010
  • In order to investigate the emission characteristics of the phosphorescent white organic light-emitting diodes (PHWOLEDs) according to various hole transport layers (HTLs), PHWOLEDs composed of HTLs whose structure are NPB/TCTA, NPB/mCP and NPB/TCTA/mCP, two emissive layers (EMLs) which emit two-wavelengths of light (blue and red), and electron transport layer were fabricated. The applied voltage, power efficiency, and external quantum efficiency at a current density of $1 mA/cm^2$ for the fabricated PHWOLEDs were 7.5 V, 11.5 lm/W, and 15%, in case of NPB/mCP, 5 V, 14.8 lm/W, and 13.7%, in case of NPB/TCTA, and 5.5 V, 14.6 lm/W, and 15%, in case of NPB/TCTA/mCP in the hole transport layer, respectively. High emission efficiency can be obtained when the amount of hole injection from anode is balanced out by the amount of electron injection from the cathode to EML by using NPB/TCTA/mCP structured HTL.

형광과 인광 첨가제에 의한 적색 OLED 소자의 발광 특성 (Emission Characteristics of Red OLEDs with Fluorescent and Phosphorescent Dopant)

  • 박연석;양재웅;주성후
    • 한국전기전자재료학회논문지
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    • 제22권12호
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    • pp.1039-1044
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    • 2009
  • Red color OLED has been fabricated by the doping method apply to CBP using co-evaporation, GDI4349 of phosphorescent dopant, and rubrene of fluorescent dopant. The OLED structure are multi-layer of ITO(150 nm)/ELM_HIL(50 nm)/ELM_HTL(30 nm)/CBP : Rubrene, GDI4349 (30 nm)/BAlq (30 nm)/LiF(0.7 nm)/Al (100 nm). Accomplished best result at 3 vol.% of rubrene when the OLEDs were made of 1, 3, 5, 7, 9 vol.% doped rubrene. The highest efficiency of 7.2 cd/A was resulted at 8 vol.% of GDI4349 when the OLEDs were made among 5, 8, 11, 14 vol.% of GDI4349. Obviously, the best concentration of rubrene at 3 vol.% and changing GDI4349 concentration to 5, 8, 11, 14 vol.% OLED dramatically enhanced characteristic of resulted 10.7 cd/A at 8 vol.% of GDI4349. This result would understand to analyse as the emission efficiency increases by energy transport efficiency increase using GDI4349 energy transfer when rubrene absorbs the energy from CBP of fluorescences host.

발광층 내의 스페이서가 인광 OLED의 효율 및 발광 특성에 미치는 영향 (Effects of Spacer Inserted Inside the Emission Layer on the Efficiency and Emission Characteristics of Phosphorescent Organic Light-emitting Diodes)

  • 서유석;문대규
    • 한국전기전자재료학회논문지
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    • 제27권6호
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    • pp.377-382
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    • 2014
  • We have investigated the effects of spacer layer inserted between blue and red doped emission layers on the emission and efficiency characteristics of phosphorescent OLEDs. N,N'-di-carbazolyl-3,5-benzene (mCP) was used as a host layer. Iridium(III)bis[(4,6-di-fluorophenyl)- pyridinato-N,$C^2$']picolinate (FIrpic) and tris(1-phenyl-isoquinolinato-$C^2$,N)iridium(III) [Ir(piq)3] were used as blue and red dopants, respectively. The emission layer structure was mCP (1-x) nm/mCP:$Ir(piq)_3$ (5 nm, 10%)/mCP (x nm)/mCP:FIrpic (5 nm, 10%). The thickness of mCP spacer layer was varied from 0 to 15 nm. The emission from $Ir(piq)_3$ and the efficiency of the device were dominated by energy transfer from mCP host and FIrpic molecules, and by diffusion of mCP host triplet excitons.

Low roll-off of efficiency with increasing current density in phosphorescent OLEDs

  • Kang, Jae-Wook;Lee, Se-Hyung;Park, Hyung-Dol;Jeong, Won-Ik;Yoo, Kyung-Mo;Park, Young-Seo;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1654-1657
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    • 2007
  • We demonstrate that the reduction of quantum efficiency with increasing current density in phosphorescent light emitting diodes (PhOLEDs) is related to the formation of excitons in hole transporting layer based on the analysis of emission spectra and exciton formation zone. By employing dual emitting layerm we could achieve maintaining quantum efficiency at high current density up to $10000\;cd/m^2$ as 13.1% compared to the devices with single emitting layer (S-EML) (${\eta}_{ext}$= 6.9% at $10000\;cd/m^2$).

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패션디자인에 활용된 빛의 유형 분석 (A Study on the Type of Light in Fashion Design)

  • 정현;금기숙
    • 복식
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    • 제58권2호
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    • pp.120-133
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    • 2008
  • The purpose of this study is to analysis types of light and to find the characteristics of light in contemporary fashion design. In a scientific context, light is electromagnetic radiation of a wavelength that has the characteristics of straightness, reflection, refraction, scattering and diffraction. But in philosophical speculations, light has been used as a metaphor of 'being', 'to-be' or 'enlightenment.' And through the ages, people have tried to represent and apply the light into plastic art like painting and architecture. The types of light in fashion design was categorized as those; reflective light from the surface of clothing which is the result of interaction between illumination and material, representative light as the pattern of light or light effect such as sun or its rays and optical or psychedelic patterns, luminescent light from light emitting material like phosphorescence or LED which combines into fashion design, projective light from a medium to reveal virtual patterns on the surface or a fashion design itself using holography. These lights in fashion design can be considered as reflection of emphasis of sexuality, longing for fantasy and mystique, visualization of interaction and communication and groping for the play.