• Title/Summary/Keyword: Phosphate glass

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A Study on the Amplification Characteristics of High-Power Gaussian Nd:Glass Laser Beam (대출력 Gauss형 Nd:글라스 레이저 비임의 증폭특성에 관한 연구)

  • 강형부;장용무
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.36 no.10
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    • pp.741-747
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    • 1987
  • The high-power Nd:glass system with five-stage amplifier was designed and its amplification characteristics was studied for developing high-power Nd:glass laser system as an energy driver of inertial confinement fusion(ICF). In order to study the amplification characteristics of remporal and spacial Gaussian laser beam, the dependence of them on pumping efficiency and rod loss were studied and discussed. The output energy of this system using phosphate Nd glass rod(LHG-7,LHG-8) and silicate Nd glass rod(LSG-91H), respectively, was calculated by the computer simulation using Avizonis-Grotbeck and Frantz Nodvik equations. As results of this simulation, it was found that the shorter the risetime of laser pulse, the larger the amplification factor and that the larger peak value of laser pulse, the lower the amplification factor. The output inergies of 179J, 344J, and 7J were obtained by the designed five-stage amplified high-power Nd:glass laser system using glass rods of LHG-7,LHG-8, and LSG-91H, respectively. From the results it was found that the laser system using the LHG-8 glass rod was the most excellent one among the systems and the cross section for stimulated emission of the gain coefficient was essentially important parameter for the amplification characteristics.

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Characteristics of Carbon Tetrafluoride Plasma Resistance of Various Glasses

  • Choi, Jae Ho;Han, Yoon Soo;Lee, Sung Min;Park, Hyung Bin;Choi, Sung Churl;Kim, Hyeong Jun
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.700-706
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    • 2016
  • Etch rate, surface roughness and microstructure as plasma resistance were evaluated for six kinds of oxide glass with different compositions. Borosilicate glass (BS) was found to be etched at the highest etch rate and zinc aluminum phosphate glass (ZAP) showed a relatively lower etch rate than borosilicate. On the other hand, the etching rate of calcium aluminosilicate glass (CAS) was measured to be similar to that of sintered alumina while yttrium aluminosilicate glass (YAS) showed the lowest etch rate. Such different etch rates by mixture plasma as a function of glass compositions was dependent on whether or not fluoride compounds were formed on glass and sublimated in high vacuum. Especially, in view that $CaF_2$ and $YF_3$ with high sublimation points were formed on the surface of CAS and YAS glasses, both CAS and YAS glasses were considered to be a good candidate for protective coating materials on the damaged polycrystalline ceramics parts in semi-conductor and display processes.

Effect of CuO on the Optical and Structural Properties of Phosphate Glass for Near-Infrard Filter (근적외선 필터용 인산계 유리의 광학적 특성 및 구조적 특성에 미치는 CuO 의 영향)

  • Kim, Seong-Il;Hwang, Jong-Hee;Lim, Tae-Young;Kim, Jin-Ho;Kim, Young-Ho;Lee, Jong-Hwa;Choi, Deuk-Kyun
    • Korean Journal of Materials Research
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    • v.19 no.12
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    • pp.657-660
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    • 2009
  • Optical characteristics and structural changes depending on CuO content in phosphate glasses that are used in near-infrared (near-IR) filters were investigated. With phosphate glasses that contain 1-9 mol% CuO, changes in optical transmittance, optical absorption, and color coordinate were measured with a UV-VIS spectrophotometer. An XPS (X-ray photoelectron spectroscopy) analysis was performed to determine valence of copper ion that influences optical characteristics in near-IR filter glasses. Structural changes in glasses depending on CuO content were also analyzed by FT-IR (Fourier transform infrared) and Raman spectrophotometers. From the UV-VIS spectrophotometer results, strong absorption peaks at 220 & 900 nm were found and transmittance was decreased. The color coordinates of the glasses were shifted to the green color direction with CuO addition for increasing absorption of long wavelength range spectra, in spite of the amount of $Cu^{2+}$, which gives a blue color to glasses, and which was increased in XPS results. Also, structural de-polymerization of glasses with CuO addition were found by FT-IR and Raman results.

P2O5-ZnO-SiO2-R2O Glass Frit Materials for Hermetic Sealing of Dye-Sensitized Solar Cells

  • Lee, Hansol;Lee, Choon Yeob;Hwang, Jae Kwun;Chung, Woon Jin
    • Journal of the Korean Ceramic Society
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    • v.54 no.5
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    • pp.400-405
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    • 2017
  • $P_2O_5-ZnO-SiO_2-R_2O$ glasses were synthesized as a sealing material for large scale dye-sensitized solar cells (DSSC). Compositional effects of $P_2O_5$ and ZnO were examined by varying their contents. Their viscosity and glass stability at sintering temperatures of less than $550^{\circ}C$ were examined by flow button test. Glass transition temperature and structural change upon compositional change were investigated. Chemical stability against electrolyte was also examined by immersing the glasses in the electrolyte for 72 h at $85^{\circ}C$.

Investigation on the lasing characteristics of an $Ar^+$ laser-pumped Nd:glass laser ($Ar^+$ 레이저로 펌핑되는 Nd:glass 레이저의 발진특성)

  • 이종무;강응철;남창희
    • Korean Journal of Optics and Photonics
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    • v.3 no.4
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    • pp.222-226
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    • 1992
  • The lasing characteristics of a Nd:phosphate glass laser pumped by 514 nm of an $Ar^{+}$ laser has been investigated. The oscillator consists of a Nd:glass gain medium set at Brewster angle, and two concave mirrors, and a flat mirror with a reflectance of 98%. The $Ar^{+}$ laser pumping beam is focused longitudinally at the beam waist of laser mode for efficient pumping. The pumping beam is chopped at 100 Hz to reduce the heat loading to prevent the thermal damage of the gain medium by the latent heat from the absorbed pumping beam. The maximum laser output power of 70 mW at 1.5 W pumping and the threshold input power of 520 mW have been obtained.

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Synthesis of P2O5-V2O5-ZnO Glass Frit for Laser Sealing of OLED by the Addition of Filler (필러 첨가에 의한 OLED의 레이저 실링용 P2O5-V2O5-ZnO 유리프릿의 제조)

  • Bang, Jae-Chul
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.9
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    • pp.571-576
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    • 2015
  • In this study, we developed a lead-free $P_2O_5-V_2O_5-ZnO$ glass frit for sealing OLED using laser irradiation. The frit satisfied the characteristics required for laser sealing such as low glass transition temperature, low coefficient of thermal expansion (CTE), high water-resistance, and high absorption at the wavelength of the laser beam. Ceramic fillers were added to the glass frit in order to further reduce and match its CTE with that of the commercial glass substrate. The addition of Zirconium Tungsten Phosphate (ZWP) to the frit yielded the most desirable results, reducing the CTE to $45.4{\times}10^{-7}/^{\circ}C$, which is very close to that of the glass substrate ($44.0{\times}10^{-7}/^{\circ}C$). Successful formation of a solid sealing layer was observed by optical and scanning electron microscopy.

A Study of Structure and Thermal Properties of K2O·CaO·P2O5 Glasses (K2O·CaO·P2O5계 유리의 열적특성과 구조분석)

  • Yoon, Young-Jin;Yoon, Tae-Min;Lee, Yong-Soo;Kang, Won-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.2
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    • pp.194-198
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    • 2002
  • Various composition of $K_2O{\cdot}CaO{\cdot}P_2O_5$ glasses were studied by melting process to identify glass forming region. Thermal properties were observed by DSC and TG-DTA, structural properties were investigated by FT-IR and Raman Spectroscopy. The glass transition temperature (Tg) and softening temperature (Ts) were decreased with increasing $K_2O\;and\;P_2O_5$ contents. The basic structural unit of phosphate glasses is the $PO_2\;and\;PO_4^{3-}$ groups to make a cross-link and P-O-P group to form skeleton structure. As CaO content was increased, the P-O-P field strength in these glass was increased and intensity of $PO_2\;and\;PO_4^{3-}$ stretch was decreased.

Selection of Dental Cements (치과용 합착제의 선택)

  • Sung, Moo-Gyung
    • Journal of the Korean Academy of Esthetic Dentistry
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    • v.8 no.1
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    • pp.76-82
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    • 1999
  • Zinc phosphate cement has long been the material of choice for permanent luting of cast restorations, and through many years of use has been considered effective to retain castings. However, cast restorations cemented with this material have been susceptible to secondary caries. Glass ionomer luting agents become available in the late 1970s. These material s, through release of fluoride, show considerable promise as a means of reducing secondary caries. Other favorable traits include significantly less disintegration in vivo than zinc phosphate cements, a film thickness comparable to that of zinc phosphate cement, and adhesion to tooth structure. Compomer materials were created in 1993 as a filling material for deciduous teeth, cervical lesions, and class III cavities. In the meantime, compomer have been developed as chemical hardening cements for cast gold restorations. The aim of this paper is to review the articles on luting cements to help the choice of dental cements.

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Investigation on Structure and Physical Properties of Bioglasses with Various P2O5 Content (P2O5함량에 따른 Bioglass의 구조 분석 및 물성 측정)

  • 임기홍;황진명;김철영
    • Journal of the Korean Ceramic Society
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    • v.26 no.4
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    • pp.559-567
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    • 1989
  • Bioglasses have been known to be as one of the promising biomateials, which can be used for replacing defective hard and soft tissue. There have been many reports on biological results for this type of glass, but no systematic work has carried out on the structures and properties of the bioglass itself. In the present study, the effect of P2O5 in bioglasses on their structures and properties was examined. Infrared and Raman spectroscopy for the glass structural analysis, differential thermal and X-ray diffraction analysis for the crystallization of the bioglass were performed, and several physical properties were measured. When the glasses were heat-treated, Na2O.2CaO.3SiO2 was the major crystalline phase and $\beta$-NaCaPO4 crystal was found for the glass with high P2O5 content. The added P2O5 in the glasses enhanced the polymerization of silicate glass structure and it changed the chain-like glass structure to a sheet-like structure, and some P2O5 may stay as phosphate monomer. With addition of P2O5 in the glass the density of the glasses decreased, but not much changes in their thermal expansion coefficient, softening point and microhardness were observed.

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A STUDY ON THE SHEAR BOND STRENGTH OF LIGHT-CURED GLASS IONOMER CEMENT (광중합형 글래스아이오노머 시멘트의 전단결합강도에 대한 연구)

  • Kim, Hyun-Yang;Tae, Ki-Chul;Kook, Yoon-Ah;Kim, Sang-Cheol
    • The korean journal of orthodontics
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    • v.28 no.5 s.70
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    • pp.689-698
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    • 1998
  • The purpose of this study was to evaluate the shear bond strength of light cured glass ionomer cement to enamel surface which treated with $37\%$ phosphoric acid, $10\%$ polyacrylic acid, $1.23\%$ acidulated phosphate fluoride gel and no etching agent. To compare the shear bond strength of glass ionomer cement, light-cured composite resin and chemically-cured composite resin were empoloyed as controls. Eight experiments groups were composed. 10 specimens of each group were bonded by metal bracket by tested in universal testing machine for shear bond strength, in stereoscope for adhesive remnants index. The data were evaluated statistically by SPSS/PC+. The results were as follows. 1. Among the groups of $37\%$ phosphoric acid treated and dry and bonded with light cured glass ionomer, light cured composite resin, and chemically cured composite resin, the shear bond strength of glass ionomer group showed no significant difference to the others, but the shear bond strength of chemically cured resin showed statistically lower than that of light cured resin (p<0.05). 2. The shear bond strengths of glass ionomer cement to enamel treated group with $1.23\%$ acidulated phosphate fluoride gel and $10\%$ polyacrylic acid and $37\%$ phosphoric acid showed statistically higher than that of no etched enamel group(p<0.U). 3. In the groups of glass ionomer cement, the presence of moisture was not significantly effect to the shear bond strength (p<0.05). 4. After debonding, no etched enamel group showed less residual materials on the enamel surface than the group of enamel etched with $37\%$ Phosphoric acid.

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