• 한국토양비료학회지
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• 제50권3호
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• pp.195-202
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• 2017

The volcanic ash soils from the Jeju province have low available phosphate because of the high phosphate fixing power of the soils. Phosphorus fertilizerwas dressed after cultivating green manure crops and before cultivating potatoes in order to investigate potato yields, the available phosphate contents, and phosphorus balance in the soils. Green manure crops cultivated in this study were hairy vetch alone and hairy vetch and rye. During potato cultivation, four treatments were conducted in the experiments; NF (non fertilizer), P fertilizer ($N-P-K=0-25-0kg\;10a^{-1}$), NK fertilizer ($N-P-K=18-0-19kg\;10a^{-1}$), and NPK fertilizer ($N-P-K=18-25-19kg\;10a^{-1}$). There were no differences in the yields of potato stem and tuber from the cultivation plots of different green manure crops. However, in the plots with single-sown hairy vetch and mixed-sown hairy vetch and rye, the yields of potato stem and tuber were higher in the P fertilizer plot than in NF plot. The yield of tuber among the treatments with mixed-sown hairy vetch and rye was the highest in the NPK fertilizer plot. The available phosphate content in soils initially increased with time in all plots, but began to decrease gradually after Oct. 18. The available phosphate contents were high in the plots for phosphate fertilization, and the difference in available phosphate content between non-phosphorus fertilizer plots and phosphorus fertilizer plots increased with time. In the single-sown hairy vetch and mixed-sown hairy vetch and rye plot, the phosphorus balances in NF plot and NK fertilizer plot were very low, while those in the P fertilizer plot and NPK fertilizer plot were high. In conclusion, available phosphate contents in soil and the potato yields were increased by phosphorus fertilization when potatoes planted after cultivating hairy vetch and rye together, compared to hairy vetch alone.

• Environmental Engineering Research
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• 제17권4호
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• pp.197-203
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• 2012

Phosphorus removal during discharge of wastewater is required to achieve in a very high level because eutrophication occurs even at a very low phosphorus concentration. However, there are limitations in the traditional technologies in the removal of phosphorus at very low concentration, such as at a level lower than 0.1 mg/L. Through a series of experiments, a possible technology which can remove phosphate to a very low level in the final effluent of wastewater was suggested. At first Al, Zn, Ca, Fe, and Mg were exposed to phosphate solution by impregnating them on the surface of activated alumina to select the material which has the highest affinity to phosphate. Kinetic tests and isotherm tests on phosphate solution have been performed on four media, which are Ca-impregnated activated alumina, activated alumina, Ca-impregnated loess ball, and loess ball. Results showed that Ca-impregnated activated alumina has the highest capacity to adsorb phosphate in water. Scanning electron microscope image analysis showed that activated alumina has high void volume, which provides a large surface area for phosphate to be adsorbed. Through a continuous column test of the Ca-impregnated activated alumina it was discovered that about 4,000 bed volumes of wastewater with about 0.2 mg/L of phosphate can be treated down to lower than 0.14 mg/L of concentration.

• 한국가금학회지
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• 제23권4호
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• pp.169-175
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• 1996

An experiment was conducted with male broiler chicks to determine the effect of different dietary phosphorus sources and evaluate the biological availability of phosphorus sources. The biological availability of phosphorus from dicalcium phosphate (DCP) was used as a reference standard (100%) compared to defluorinate phosphate (DFP). DCP and DFP was supplemented to a corn-soy basal diet at levels of 0.05, 0.15, 0.25, 0.35%. Each of 24 pens of 10 male broiler chicks with three replications was used for three weeks. The results indicated that weight gain, feed in-take, feed efficiency, nonphytic phosphorus (NPP) and tibia ash were significantly different among treatments. Dietary supplemental phosphorus of DFP improved weight gain, NPP intake and feed efficiency consistently, whereas supplements of DCP did not show consistent increase. Regression equations was used for the availability of DPP compared with DCP when percent bone ash was a function of total phosphorus in the diet. The percent (%) bone ash of DFP groups compared to that of DCP groups showed a value of 59.98% as a slope ratio. DFP indicated lower biological availability compared to DCP, but it's dietary supplementation tended to increase bone ash and maximize the growth of young broiler chicks.

• 한국연초학회지
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• 제8권2호
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• pp.43-49
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• 1986

Field experiment was conducted to investigate the effect of vinyl mulch on phosphate availability of soil and fertilizer in 1982. Growth of tobacco was more vigorous at each level of phosphate treatment in vinyl mulched than in bare soil. There was significant culture x Phosphorus treatment interaction for the yields of cured tobacco leaves. These results indicated that vinyl mulch was effective to improve phosphate availability of soil and fertilizer. Increase in soil temperature and maintenance of bulk density suitable for Phosphorus diffusion by vinyl mulch were likely to Play major roles on Phosphate availability, but other unknown factors appeared to be involved.

• 한국산림과학회지
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• 제97권2호
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• pp.181-186
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• 2008

Even small changes in phosphorus concentrations in stream water could cause eutrophication because of very low level of phosphorus concentrations in natural waters. I investigated the impact of strip cut and clear cut on phosphorus concentrations in stream water at the Hubbard Brook Experimental Forest and investigated stream water phosphorus concentrations as a function of flow rate and season (as well as cutting history). Mean phosphate concentrations in the control (undisturbed forest) increased $1.9{\mu}g\;L^{-1}\;to\;2.6{\mu}g\;L^{-1}$, while strip cut treatment increased phosphate concentrations in stream water $2.2{\mu}g\;L^{-1}\;to\;3.7{\mu}g\;L^{-1}$ during the same period. There was no significant effect of clear cut treatment on phosphate concentrations in stream water. No relationships were found between discharge rate and phosphate concentrations, but the magnitude of fluctuation were increased during two decades in undisturbed forest: $1-5{\mu}g\;L^{-1}$ from 1963 to 1975 and $1-12{\mu}g\;L^{-1}$ from 1983 to 1995. Based on this study, forest harvests with buffer zone will not make a problem by imported phosphate to cause eutrophication in natural water.

• 한국환경농학회지
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• 제36권3호
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• pp.141-146
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• 2017

BACKGROUND: Phosphorus(P) is a vital factor for rice but excess input of phosphorus fertilizer can cause environmental risk and waste of fertilizer resources. We studied to assess the change of available phosphate, P balance, critical concentration of available phosphate under a rice single system. METHODS AND RESULTS: The changes of available phosphate of paddy soil were examined from long-term fertilization experiment which was started in 1954 at the National Academy of Agricultural Science. The treatments were no phosphate fertilization(No fert., and N), phosphate fertilization(NPK, NPKC, and NPKCLS). The available phosphorus concentrations in treatments without phosphate fertilizer (No fert. and N) were decreased continuously. But, after 47 years, available phosphate content in phosphate fertilizer treatment (NPK, NPKC, and NPKCLS) reached at the highest ($245{\sim}331mg\;kg^{-1}$), showing a tendency to decrease afterward. The mean annual P field balance in these treatments (NPK, NPKC, and NPKCLS) had positive values that varied from 16.6 to $17.5kg\;ha^{-1}year^{-1}$, and ratio of residual P were increased. These showed that phosphate fertilizer in soil were converted into the form of residual phosphorus which was not easily extracted by available phosphate extractant. Also, It was estimated that the critical value of available phosphate for rice cultivation was $120mg\;kg^{-1}$ using Cate-Nelson equation. CONCLUSION: We concluded that no more phosphate fertilizer should be applied in rice single system if soil available phosphate is higher than the critical P value.

• 한국환경과학회지
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• 제16권11호
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• pp.1271-1277
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• 2007

This study was conducted to investigate the ratios of phosphorus release to COD uptake, phosphorus release to nitrate removal, and phosphorus uptake to phosphorus release by DNPAOs(denitrifying phosphate accumulating organisms). In case $I{\sim}IV$, influent 1 were fed with synthetic wastewater with influent 2 $NO_3^--N$ injection to anoxic zone and the case V were fed with municipal wastewater with side stream oxic zone instead of influent 2 $NO_3^--N$ injection. As a result, the ratio of phosphorus release to carbon uptake was increased in accordance with nitrate supply. The DNPAOs simultaneously took up phosphate and removed nitrate from the anoxic reactor. In case $I{\sim}IV$, with above 20 mg/L of sufficient $NO_3^--N$ supply, phosphate was taken up excessively by the DNPAOs in anoxic condition. The large amount of both uptake and release of phosphorus occurred above 20 mg/L of nitrate supply, achieving the ratio of phosphorus uptake to phosphorus release to be 1.05. In case V, phosphate luxury uptake was not occurred in system due to 6.98 mg/L of insufficient $NO_3^--N$ supply and the ratio of phosphorus uptake to phosphorus release was 0.98. Consequently, if nitrate as the electron acceptor was sufficient in anoxic zone, the ratio was found to be high.

• 상하수도학회지
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• 제33권4호
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• pp.291-297
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• 2019

Phosphorus is a vital resource for sustaining agriculture and nutrition, but a limited non-renewable resource. Thus, the recovery of phosphorus from waste activated sludge(WAS) was attempted by microwave heating and magnesium ammonium phosphorus(MAP) crystallization. Polyphosphate-accumulating organisms(PAOs) in WAS release phosphate from the cell when they are exposed to high temperature environments. Microwave heating caused phosphorus and ammonia to release from WAS. The amount was increased with increasing temperature, showing that 88.5% of polyphosphate present in the cells were released in the form of phosphate at $80^{\circ}C$. A similar result was also observed in the release of ammonia. On the other hand, both phosphorus and ammonia were crystallized with magnesium, and then was harvested as MAP. Phosphorus recovery rate reached almost 97.8%, but the ammonia was about 13.4%. These results cleary indicate that phosphorus could be recovered from WAS using a physiological trait of PAOs. Heavy metal analyses also show that the MAP crystal is useful and safe as a phosphorus fertilizer.

• Advances in environmental research
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• 제3권2호
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• pp.163-172
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• 2014

Magnetite was chosen as a typical adsorbent to study its phosphate adsorption capacity in water body with low concentration of phosphorus (below $2mg\;PL^{-1}$). Magnetite was collected from Luoyang City, Henan Province, China. In this research, three factors have been studied to describe the adsorption of phosphate on magnetite, which was solution concentration (concentration ranging from 0.1 to $2.5mg\;PL^{-1}$), suspension pH (1 to 13) and temperature (ranging from $10^{\circ}C$ to $40^{\circ}C$). In addition, the modified samples had been characterized with XRD and FE-SEM image. The results show that iron ions contains in magnetite were the main factors of phosphorus removal. The behavior of phosphorus adsorption to substrates could be fitted to both Langmuir and Freundlich isothermal adsorption equations in the low concentration phosphorus water. The theoretical saturated adsorption quantity of magnetite is 0.158 mg/g. pH has great influence on the phosphorus removal of magnetite ore by adsorption. And pH of 3 can receive the best results. While temperature has little effect on it. Magnetite was greatly effective for phosphorus removal in the column experiments, which is a more practical reflection of phosphorous removal combing the adsorption isotherm model and the breakthrough curves. According to the analysis of heavy metals release, the release of heavy metals was very low, they didn't produce the secondary pollution. The mechanism of uptake phosphate is in virtue of chemisorption between phosphate and ferric ion released by magnetite oxidation. The combined investigation of the magnetite showed that it was better substrate for water body with low concentration of phosphorus.

• Environmental Engineering Research
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• 제22권1호
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• pp.12-18
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• 2017

Struvite precipitation has been proven to be an effective method in removing and recovering ammonia nitrogen (N) and phosphate phosphorus (P) from wastewater. In this study, effects of pH, molar ratios and pre-treatment of effluent of anaerobically digested swine wastewater were investigated to improve struvite crystallization. The magnesium : ammonium : phosphate ratio of 1.2 : 1.0 : 1.0 was found to be optimal, yet the molar ratio in the wastewater was 1 : 74.9 : 1.8. From the analysis, the optimum pH was between 8.0 and 9.0 for maximal phosphate P release and from 8.0 to 10.0 for maximal ammonia N and phosphate P removal from real wastewater. Analysis from Visual MINTEQ predicted the pH range of 7-11 for ammonia N and phosphate P removal and recovery as struvite. For pre-treatment, microwave pre-treatment was ineffective for phosphate P release but ultrasound pre-treatment showed up to 77.4% phosphate P release at 1,000 kJ/L of energy dose. Precipitates analysis showed that phosphorus and magnesium in the collected precipitate had almost same values as theoretical values, but the ammonia content was less than the theoretical value.