• Title/Summary/Keyword: Phenol resin

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Resin Impregnation of Sawdust Board for Making Woodceramics(II) - Effect of Density and Addition Rate of Phenol Formaldehyde Resin - (우드세라믹 제조용 톱밥보드의 수지함침(II) - 밀도 및 페놀수지 첨가량의 영향 -)

  • Oh, Seung Won;Byeon, Hee Seop
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.5
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    • pp.15-22
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    • 2003
  • This study was carried out to investigate the properties of sawdust board impregnated with phenol resin according to the density and resin content of board. The sawdust board were manufactured to target densities of 0.4, 0.5, 0.6, 0.7 g/cm3 and resin content of 5, 10, 15, 20% made from Pinus densiflora S. et Z., Larix. kaemferi C. and Pinus koraiensis S. et Z. The impregnation process were executed in two ways, the application of vacuum pressure then followed by atmospheric pressure, and the application of vacuum pressure with ultrasonic vibration then followed by atmospheric pressure. The density of impregnated sawdust board increased as density and resin content of sawdust board increased, but impregnation rate decreased. The density, impregnation rate, bending strength and brinell hardness of sawdust board in impregnated vacuum pressure with ultrasonic vibration then nonpressure were higher than those of vacuum pressure then nonpressure. In this results, the impregnation rate is increased in vacuum pressure with ultrasonic vibration then nonpressure, it has affected the properties of sawdust board impregnated with phenol resin.

페놀분해 효모 Candida tropicalis PW-51의 분리 및 분해특성

  • Kim, Seong-Bin;Kim, Chi-Kyung;Kim, Hee-Sik;Lee, Chang-Ho;Shin, Ki-Sun;Kwon, Gi-Seok;Yoon, Byung-Dae;Oh, Hee-Mock
    • Microbiology and Biotechnology Letters
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    • v.24 no.6
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    • pp.743-748
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    • 1996
  • For the biological treatment of phenolic resin wastewater containing phenol and formaldehyde, a phenol-degrading yeast was isolated from the papermill sludge, and then identified as Candida tropicalis PW-51 according to morphological, physiological and biochemical properties. The strain was able to degrade high phenol concentrations up to 2,000mg/l within 58 hours in batch cultures. Phenol-degrading efficiency by the strain was maximum at the culture conditions of a final concentration of 9 $\times$ 10$^{6}$ cells/ml, 30$\circ$C and pH 7.0. The mean degradation rate of phenol was highest at 45.5mg/l/h in 1,000mg/l phenol from 500mg/l to 2,000mg/l phenol. Because the enzyme activity of catechol 1,2-dioxygenase increased in the course of degradation of phenol, it seems that this strain degrades phenol via the ortho-cleavage of benzene ring. The isolate C. tropicalis PW-51 could be effectively used for the biological treatment of phenolic resin wastewater.

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The Hazard of Ignition on the Bimetal Type Thermostat Molded by Phenol Resin (페놀수지로 몰딩된 바이메탈식 서모스탯의 발화위험성)

  • Park, Y.G.;Lee, S.H.
    • Journal of Korean Institute of Fire Investigation
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    • v.11 no.1
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    • pp.63-73
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    • 2007
  • In this paper, we discussed the hazard of ignition on the bimetal type thermostat molded by phenol resin with case study and accelerated aging test. We experimented three type thermostats molded by phenol resin which are used on hot/cold water dispenser. On the case study, the thermostat was origin of 6re and dry tracking occurred around it's moveable contactor. On the accelerated aging test, the more thermostat was switched, the more damaged it become. One of the A-type thermostats that is similar type on the case study fired around moveable contactor. We therefore confirmed that the tracking around the moveable contactor of bimetal type thermostat molded by phenol resin could be origin of fire and it is available to reduce of fire that using noncombustible material for molding of bimetal type thermostat.

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Photocatalytic Oxidation for Organic Dye using Phenol Resin-based Carbon-titania Composites

  • Oh, Won-Chun;Na, Yu-Ri
    • Journal of the Korean Ceramic Society
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    • v.45 no.1
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    • pp.36-42
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    • 2008
  • Carbon/$TiO_2$ composite photocatalysts were thermally synthesized with different mixing ratios of anatase to phenol resin through an ethanol solvent dissolving method. The XRD patterns revealed that only anatase phase can be identified for Carbon/$TiO_2$ composites. The diffraction peaks of carbon were not observed, however, due to the low carbon content on the $TiO_2$ surfaces and the low crystallinity of amorphous carbon. The results of chemical elemental analyses of the Carbon/$TiO_2$ composites showed that most of the spectra for these samples gave stronger peaks for carbon and Ti metal than that of any other elements. The BET surface area increases to the maximum value of $488\;m^2/g$ with the area depending on the amount of phenol resin. From the SEM images, small $TiO_2$ particles were homogeneously distributed to a composite cluster with the porosity of phenol resin-based carbon. From the photocatalytic results, the MB degradation should be attributed to the three kinds of synergetic effects, such as photocatalysis, adsorptivity, and electron transfer by light absorption between supporter $TiO_2$ and carbon.

The Effect of Changing Molecular Weight of Rosin Modified Phenol Resin on Physical Properties of Litho Printing Inks (Rosin변성 phenol수지의 분자량 변화에 따른 평판인쇄 잉크의 물성변화에 관한 연구)

  • SungBinKim
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.145-157
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    • 1994
  • Litho printing ink vehicles based on rosin modified phenolic are faster drying, have better durability, are harder and glosser and have greater resistance to water than ones based on ester gums. Ink-Water balance and rheological properties are important in litho printing process. These physical properties is concerned with molecular weight of Resin to use vehicle. So this paper was studied about the effects of changing molecular weight of Rosin modified phenolic on surface tension, viscosity, pseudoplasticity and printability of Litho Inks. The results were as follows. 1) The surface tension of model inks depended on the molecular \veight of the resin : Dispersion componnent of ink increase but non dispersion component decrease as molecular weight of Resin increase. 2) Water pick-up of litho ink is more fast balance, using low molecular weight of Resin. 3) Viscosity, Yield value and Newtonian value of model inks increase as molecular weight of Resin increase. 4) The litho ink prepared with the modified phenolic of which molecular weight is about 20000 showed the highest printing density and gloss.

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Adding Effect of TCA-Precipitated Blood Powder to the Phenol Formaldehyde Resin for Plywood (합판용 페놀수지 접착제에 대한 TCA침전 혈액분말의 첨가효과)

  • Lee, Hwa-Hyoung;Lee, Jong-Shin;Jang, Sang-Sik
    • Journal of the Korean Wood Science and Technology
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    • v.24 no.2
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    • pp.15-19
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    • 1996
  • To utilize the waste materials and develope wood adhesive from isolated bloods of slaughtered cow and pig and also to prevent water pollution, simple and rapid method of isolation and purification of plasma proteins from pig bloods with trichloroacetic acid(TCA) treatment was developed. Adding of TCA-precipitated blood powder to the phenol formaldehyde resin(PF) improved dry and wet strength of plywood and resulted in fast hot pressing times.

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Selective Concentration and Determination of Phenol and Chlorophenols by Solid Phase Extraction

  • Jung, Min-Woo;Lee, Dai Woon;Paeng, Ki-Jung
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.535-538
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    • 1995
  • This study employs the variety of mixtures of XAD resin and active carbons as concentration base for solid phase extraction (SPE) which has been widely used to preconcentrate and purify phenol and chlorophenols in determination of environmental water samples. In this study, we employed variety of mixtures of copolymer based XAD-4 resin with active carbons. This cartridges shows advantages of both materials, such as better affinity to phenol by active carbon and better mechanical stabilities from XAD resin. The better enrichment factor, pretreatment time, recoveries and limit of detection (LOD) were achieved by the attempts to pack precolumns with both meterials for preconcentration.

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Properties and Glue Shear Strength of the Water Soluble Urea-Phenol Copolymer Adhesive as a High Temperature Curing Binder for Plywood (합판용(合板用) 고온경화형(高温硬化型) 수용성(水溶性) 요소(尿素)·페놀공축합수지(共縮合樹脂)의 성질(性質)과 그 접착강도(接着強度))

  • Lee, Hwa Hyoung
    • Journal of Korean Society of Forest Science
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    • v.60 no.1
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    • pp.51-57
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    • 1983
  • Properties and glue shear strength of each water soluble rues-phenol copolymer adhesive and phenolic resin adhesive were examined as a high temperature curing binder through the manufacture of plywood made of Kapur veneer. The former has different molar ratio and the latter was made from different catalyst method. The results are summarized as follows: 1) Specific gravities of air dried plywood manufactured from each adhesive ranged from 0.67 to 0.82 and their moisture contents met the K.S. standard 2) In dry and wet shear strength, adhesives with 60 percent of non volatile content showed higher values than those with 50 percent except phenolic resin. Urea-phenol copolymer resin with 20 percent of phenol content exhibited the highest, and that with 70 percent the lowest. Filling effect of wood flour on the bonding strength is great in urea-phenol copolymer resin with more than 50 percent of phenol content, especially significant in 50 percent of non volatile content including alkali catalyst phenolic resin. Alkali and acid catalyst methods were the highest among the adhesive manufacture methods. In wet strength, urea resin belongs to the lowest group. 3) In glue shear strength after boiling and drying test, no method for manufacturing phenolic formaldehyde resin adhesive was stronger than alkali and acid catalyst methods. Phenolic resin made from alkali catalyst method needs a wood flour filler to improve the bonding quality. Urea-phenol copolymer resin with 10 percent of phenol content showed the reasonable water resistance.

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Synthesis of Dodecyl Phenol Novolac Epoxy Resin and Physical Properties of Coatings (Dodecyl phenol novolac 에폭시수지의 합성과 도막물성)

  • Lee, Dong-Chan;Kim, Jin-Wook;Choi, Joong-So
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.4
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    • pp.615-626
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    • 2016
  • In the paper, mild solvent soluble alkyl group modified epoxy resins were prepared via a three-step method; (1) the condensation reaction of dodecyl phenol (DP) and formaldehyde, (2) the crosslinking reaction of dodecyl phnol novolac compound (DPC) and bisphenol A diglycidyl ether, (3) the dodecyl phenol novolac epoxy resins containing fatty acid (DPFA) was prepared by introducing fatty acid to DPC. Equivalent ratios of DP and formaldehyde were 1.25~1.333/1.0. Equivalent ratio of DPC and bisphenol A diglycidyl ether (YD-128) was 1.0/2.0. Reactivity, viscosity, molecular weight, solvent solubility, and physical properties of DPFA were investigated. The result show that as the number of aromatic ring of DPFA increased, viscosity increased and solvent solubility improved. When we test the properties of coatings by blending the synthesized DPFA with a white pigment, DPFAC-5 using triphenylphosphine (TPP) as a ring-open catalyst showed optical performance for drying time, adhesion, hardness, impact resistance, acid resistance and storage stability.