• 제목/요약/키워드: Phase variation

검색결과 2,040건 처리시간 0.029초

HPLC에 의한 목초액 중의 유기산, 페놀 및 벤조피렌의 분석법 개발 (HPLC Analysis of Organic Acids, Phenol, and Benzopyrene in Wood Vinegar)

  • 이계원;김아람;조재수
    • 약학회지
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    • 제52권1호
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    • pp.12-19
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    • 2008
  • The organic acids (formic acid, acetic acid and propionic acid), phenol and benzopyrene in wood vinegar were determine by HPLC. An $Atlantis^{TM}dC_{18}$ column with a acetonitrile: 0.1% phosphoric acid (5: 95, organic acids), acetonitrile: water (10 : 90, phenol), 100% acetonitrile (benzopyrene) as a mobile phase was used. Retention time of acetic acid, formic acid, propionic acid, phenol and benzopyrene was 4.77, 3.73, 9.08, 30.97 and 6.10 min, respectively. The calibration curves of organic acids, phenol, benzopyrene were linear over the concentration range of $30{\sim}500,\;60{\sim}1000$, and $3{\sim}50\;{\mu}g/ml$ with correlation coefficient of above 0.999. The limit of detection (LOD) and limit of quantitation (LOQ) of acetic acid, formic acid, propionic acid, phenol, and benzopyrene was 1.71 and 5.19, 1.11 and 3.35, 4.87 and 14.74, 6.45 and 19.55, 0.08 and $0.24\;{\mu}g/ml$, respectively. The coefficients of variation for intra- and inter-day assay were $0.21{\sim}4.14$ and $0.07{\sim}1.19%$, respectively and the precision was $95{\sim}115%$. From this study, we suggest that HPLC is suitable method for the determination of organics in wood vinegar and could be applied to quality control of wood vinegar.

지진파에 의해 발생하는 ULF 전자기장 변동 (ULF electromagnetic variation associated with seismic wave)

  • 이희순;이춘기;권병두;양준모;오석훈;송윤호;이태종
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2005년도 공동학술대회 논문집
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    • pp.197-202
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    • 2005
  • 최근 제주도에서 실시된 자기지전류(Magnetotelluric) 탐사 자료에서 일본의 Kii 반도 남동쪽 해상에서 발생한 지진활동과 관련된 전자기 현상이 관측되었으며, 이러한 동지진 전자기장 신호의 특성과 메카니즘을 분석하였다. 전파속도, 파워 스펙트럼의 특성, 지진 기록과의 비교, MT 임피던스의 변화, 타원분극 방향 등의 분석으로부터 전자기장 변동이 지진파 전파 과정에서 측점 주변에서 유도된 전자기장으로 판단되며, 측점 주변의 지전기 및 수리지질학적 구조에 의해 전자기장 변동이 크게 좌우됨을 알 수 있다. 전기역학적 효과의 간단한 고찰을 통해 관측된 전자기장의 크기가 이론적 근사와 유사함을 알 수 있었으며 전자기장의 파워가 가속도 파워와 밀접히 관련되어있음을 알 수 있으나 측점에 따라 전자기장의 크기와 방향이 크게 차이가 나는 것은 설명하기 위해서는 전기역학적 메카니즘 이외의 효과를 고려할 필요가 있다.

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질화규소 세라믹의 레이저 예열선삭에 관한 연구 (III) - SSN 및 HIPSN의 예열선삭시 절삭력 및 공구수명의 특성 - (A Study on Laser Assisted Machining for Silicon Nitride Ceramics (III) - Variation of the Main Cutting Force and Life of Cutting Tool by LAM of SSN and HIPSN -)

  • 김종도;이수진;강태영;서정;이제훈
    • Journal of Welding and Joining
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    • 제28권6호
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    • pp.35-39
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    • 2010
  • Generally, ceramic material is very difficult to machine due to high strength and hardness. However, ceramic material can be machined at high temperature by plastic flow as metallic material due to the deterioration of the grain boundary glassy phase. Recently, a new method was developed to execute cutting process with CBN cutting tool by local heating of surface with laser. There are various parameters in LAM because it is a complex process with laser treatment and machining. During laser assisted machining, high power results in reducing of cutting force and increasing tool life, but excessive power brings oxidation of the surface. The effect of laser power, feed rate, cutting depth and etc. were investigated on the life of cutting tool. Chips were observed to find out suitable machining conditions. Chips of SSN had more flow-types than HIPSN. It means SSN is easier to machining. The life of cutting tool was increased with increasing laser power and decreasing feed rate and cutting depth.

Factors Affecting Agrobacterium tumefaciens-mediated Transformation of Panax ginseng C.A. Meyer

  • Kim, Ok-Tae;Jung, Su-Jin;Bang, Kyong-Hwan;Kim, Young-Chang;Shin, Yu-Su;Sung, Jung-Sook;Park, Chun-Geon;Seong, Nak-Sul;Cha, Seon-Woo;Park, Hee-Woon
    • 한국약용작물학회지
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    • 제15권2호
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    • pp.100-104
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    • 2007
  • A protocol for the production of transgenic Panax ginseng C.A. Meyer was established via Agrobacterium tumefaciens-mediated genetic transformation of direct somatic embryos. A number of conditions related to the co-cultivation were tested with respect to maximizing transformation efficiency. The results showed that pH of the co-cultivation medium (5.7), the bacterial growth phase (optical density; $OD_{600}$ = 0.8), co-cultivation period (3 days), and acetosyringone concentration $(100\;{\mu}M)$ had positive effects on transformation. Selected plantlets were cultured on the medium at an elevated hygromycin level(30 mg/l). Integration of the transgenes into the P. ginseng nuclear genome was confirmed by PCR analysis using hpt primers and by Southern hybridization using hpt-specific probe. The transgenic plantlets were obtained after 3-month cultivation and did not show any detectable variation in morphology or growth characteristics compared to wild-type plants.

An analysis on the Earth geoid surface variation effect for use of the tilt sensor in celestial navigation system

  • Suk, Byong-Suk;Yoon, Jae-Cheol;Lyou, Joon
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2005년도 ICCAS
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    • pp.1867-1870
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    • 2005
  • The celestial navigation is one of alternatives to GPS system and can be used as a backup of GPS. In the celestial navigation system using more than two star trackers, the vehicle's ground position can be solved based on the star trackers' attitude information if the vehicle's local vertical or horizontal angle is given. In order to determine accurate ground position of flight vehicle, the high accurate local vertical angle measurement is one of the most important factors for navigation performance. In this paper, the Earth geophysical deflection was analyzed in the assumption of using the modern electrolyte tilt sensor as a local vertical sensor for celestial navigation system. According to the tilt sensor principle, the sensor measures the tilt angle from gravity direction which depends on the Earth geoid surface at a given position. In order to determine the local vertical angle from tilt sensor measurement, the relationship between the direction of gravity and the direction of the Earth center should be analyzed. Using a precision orbit determination software which includes the JGM-3 Earth geoid model, the direction of the Earth center and the direction of gravity are extracted and analyzed. Appling vector inner product and cross product to the both extracted vectors, the magnitude and phase of deflection angle between the direction of gravity and the direction of the Earth center are achieved successfully. And the result shows that the angle differences vary as a function of latitude and altitude. The maximum 0.094$^{circ}$angle difference occurs at 45$^{circ}$latitude in case of 1000 Km altitude condition.

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지리정보시스템을 이용한 소하천유역의 홍수유출 해석 (Flood Runoff Analysis of Small River Basin using Geographic Information System)

  • 이연길;박성천;이관수
    • 한국지리정보학회지
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    • 제6권1호
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    • pp.24-36
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    • 2003
  • 효율적인 수자원의 계획과 관리를 위해서 필요한 유출량 산정에 적용되어지는 많은 강우-유출모형들은 유역의 특성을 나타내는 지형인자와 매개변수 등과 같은 입력자료가 필요하게 되어 실제 적용단계에 있어 많은 어려움을 내포하고 있다. 따라서 본 연구에서는 이와 같은 문제점을 보완하고자 지리정보시스템(GIS)을 적용하여 입력자료를 생성할 수 있는 환경과 GIS와 강우-유출모형과의 연계를 통하여 시간에 따른 유출량의 변화를 나타내는 수문곡선을 해석할 수 있는 환경을 구축하고자 하였다. 입력자료 구축을 위한 GIS 소프트웨어로는 ArcView를 이용하였으며, 대상유역의 수문곡선을 해석하기 위해서 ln ($a/T_0tan{\beta}$)이라는 지형지수를 적용하는 TOPMODEL를 이용하였다. 또한, 대상유역의 유출량 산정에 이용한 강우-유출모형의 적용성을 평가하기 위하여 과거의 강우자료 중에서 단순호우사상과 복합호우사상을 선별하여 모형에 적용하였다.

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바이러스 감염에 대한 면역반응 (Immune Responses to Viral Infection)

  • 황응수;박정규;차창용
    • IMMUNE NETWORK
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    • 제4권2호
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    • pp.73-80
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    • 2004
  • Viruses are obligate intracellular parasites which cause infection by invading and replicating within cells. The immune system has mechanisms which can attack the virus in extracellular and intracellular phase of life cycle, and which involve both non-specific and specific effectors. The survival of viruses depends on the survival of their hosts, and therefore the immune system and viruses have evolved together. Immune responses to viral infection may be variable depending on the site of infection, the mechanism of cell-to-cell spread of virus, physiology of the host, host genetic variation, and environmental condition. Viral infection of cells directly stimulates the production of interferons and they induce antiviral state in the surrounding cells. Complement system is also involved in the elimination of viruses and establishes the first line of defence with other non-specific immunity. During the course of viral infection, antibody is most effective at an early stage, especially before the virus enters its target cells. The virus- specific cytotoxic T lymphocytes are the principal effector cells in clearing established viral infections. But many viruses have resistant mechanism to host immune responses in every step of viral infection to cells. Some viruses have immune evasion mechanism and establish latency or persistency indefinitely. Furthermore antibodies to some viruses can enhance the disease by the second infection. Immune responses to viral infection are very different from those to bacterial infection.

Fe-Ni 인바합금의 자기적성질에 미치는 Mn, Cr 및 Co의 첨가효과 (Effects of Mn, Cr and Co on the Magnetic Properties of Fe-Ni Invar Alloys)

  • 이종현;김희중;강일구;김학신
    • 한국자기학회지
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    • 제3권1호
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    • pp.7-12
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    • 1993
  • 저열팽창재료인 Fe-36%Ni 인바합금을 기본조성으로 하여 제3원소인 Mn, Cr, Co를 0-5wt% 범위에서 소량 첨가하고 자기적성질의 변화를 조사였다. 상온에서 $300^{\circ}C$까지의 온도에 따른 비자화의 변화는 조성에 따라 약간의 차이는 있지만 5wt%Co를 제외하고 상온으로 부터 큐리온도 직 하인 $250^{\circ}C$까지 온도상승에 따라 지바화가 매우 빠르게 감소하고, 첨가원소에 따른 비자화의 온도의존성이 온도의 3/2승항과 2승항을 혼합한 형태로 나타나는 인바합금 특유의 형상을 보인다. 상온에서 첨가원소에 따른 비자화, 큐리온도 및 보자력은 동일 함량으로 치환할 경우에 Co > Cr > Mn 의 순서로 높게 나타나지만, 5wt%Co의 경우에 급증하는 현상은 강자성 $\gamma$상과 반강자성 $\gamma$상이 혼재하는 인바효과가 강자성 $\alpha$ 상이 생성됨에 따라 사라지기 때문이었다.

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동토지반에 대한 역학적 구성모델 (Mechanical Constitutive Model for Frozen Soil)

  • 신호성;김지민;이장근;이승래
    • 한국지반공학회논문집
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    • 제28권5호
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    • pp.85-94
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    • 2012
  • 최근 동결지반의 다양한 문제들에 대한 관심이 증대하면서 동결의 영향을 받는 지반의 거동특성에 관한 이론정립 및 체계적인 연구의 필요성이 제기되고 있다. 기존의 정립된 토질역학 이론과는 달리 동결지반에서 온도의 영향과 간극수의 동결에 의한 상변화는 간극수의 이동, 지반팽창, 작용토압의 급격한 증가 등 여러가지 문제들을 야기한다. 본 논문에서는 비동결-동결 전이 상태에서 연속성을 갖는 새로운 응력변수를 도입하여, 동결 작용을 받는 다공질 재료에 대한 THM 역학적 탄소성 구성모델을 유도하였다. 개발된 구성모델을 1차원 팽창압, 동결토의 삼축압축 강도 그리고 일방향 동결실험에 적용하여 해의 안정성과 구성모델의 적용성에 대하여 논의하였다. 수치해석 결과는 동결토의 복잡한 THM현상들을 효과적으로 묘사할 수 있었으며, 동결의 영향하에 있는 지반구조물의 해석과 설계 및 시공될 구조물의 장기거동예측에 활용될 수 있을 것이다.

폐트럭으로부터 온실가스 HFC-134a의 탈루배출계수와 인벤토리 산정에 대한 연구 (Estimation of Emission Factor (Residual Rate) and Inventory of HFC-134a from Mobile Air Conditioners of Scrap Truck)

  • 김의건;김승도;김혜림;이영표;변석호;이동원
    • 한국환경과학회지
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    • 제22권9호
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    • pp.1105-1113
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    • 2013
  • This paper attempted to estimate the emissions of HFC-134a from scrap truck as a result of measuring the residual quantities of HFC-134a in air conditioner of scrap truck. We measured the residual amounts in the scrap truck of 138 by applying commercial recover for refrigerants. The average residual rate(disposal-phase emission factor) is reported to be $44.3{\pm}3.3%$ within a confidence interval of 95%. Recent year model trucks exhibit the higher residual rates. Little variation, however, is observed in regard to vehicle size. The HFC-134a emission quantity from scrap truck in 2011 is estimated to be 55,908 $tCO_2$-eq that demonstrates 21.4% increase to compare with that in 2007. As the numbers of truck have increased dramatically during the last two decades, the emissions of HFC-134a from scrap truck would increase sharply in the next coming years. HFC-134a is a very high GWP greenhouse gas. therefore have to reduce the emissions from the scrap truck and need to find ways to recycle. The chemical compositions of refrigerants from scrap truck are quite similar to those of new refrigerants, suggesting that the refrigerants from scrap truck could be reused as refrigerant.