• 제목/요약/키워드: Phase transition method

검색결과 489건 처리시간 0.031초

Molecular Dynamics Study on the Structural Phase Transition of Crystalline Silver Iodide

  • Jun Sik Lee;Mee Kyung Song;Mu Shik Jhon
    • Bulletin of the Korean Chemical Society
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    • 제12권5호
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    • pp.490-494
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    • 1991
  • The ${\beta} to {\alpha}$ phase transition in silver iodide is studied with the (N, V, E) and (N, P, T) molecular dynamics (MD) method. In experiments, the phase transition temperature is 420 K. Upon heating of ${\beta}$ form, the iodine ions undergo hcp to bcc transformation and silver ions become mobile. MD simulations for the ${\beta}$ and ${\alpha}$ phases are carried out at several temperatures and the radial distribution functions (rdf) are obtained at those temperatures in the (N, V, E) ensemble. But the phase transition is not found in our calculation. Next the phase transition is studied with the (N, P, T) MD and we find some evidences of phase transition. At 3 Kbars and 2 Kbars the phase transition temperatu re is about 300 K. For 3.55 Kbars, the phase transition is higher (420 K) than the low pressure case. The phase transition temperature is somewhat dependent on the pressure in our calculations.

Ferroelectric Phase Transition of Lead Free (1-x)(Na0.5K0.5)NbO3-xLiNbO3 Ceramics

  • Park, Jong-Ho;Park, Hui-Jin;Choi, Byung-Chun
    • Transactions on Electrical and Electronic Materials
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    • 제13권6호
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    • pp.297-300
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    • 2012
  • Lead-free (1-x)$(Na_{0.5}K_{0.5})NbO_3-xLiNbO_3$, i.e., NKN-LNx (x=0.0, 0.1, 0.2, 0.3, 0.4 mol) was prepared using the conventional solid state reaction method. The effects of LN mixing on the ferroelectric properties of NKN-LNx ceramics were studied using a dielectric constant and P-E (Polarization-electric field) measurements. Ferroelectricity was observed in the composition for x approximately varying between 0.0 and 0.4. Minimum remanent polarization $2P_r=5C/cm^2$ was achieved in the composition for x = 0.2. The ferroelectric phase transition temperature $T_C$ increased with increasing LN content. The ferroelectric phase transition of NKN-LNx ($x{\geq}0.1$) is a second-order phase transition, and that of NKN-LNx ($x{\leq}0.2$) is a first-order phase transition. These results indicate that the ferroelectric phase transition temperature of NKN-LNx change from that of second-order to weak first-order phase transition according to the LN content.

표면상변이의 강인력 의존성 : 점유통계를 이용한 정성적 고찰 (On the strong attractive force dependence of the surface phase transition : Qualitative consideration from the occupation statistics)

  • 김철호
    • 한국결정성장학회지
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    • 제7권4호
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    • pp.573-577
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    • 1997
  • 표면상변이 현상은 표면 흡착입자들 사이에 강력한 인력포텐셜이 존재할 경우 일어나는 것으로 알려져 있다. 본 논문에서는 표면상변이 현상의 강인력 의존성을 간단한 점유통계를 이용하여 고찰하였다. 압력이 임계점에 도달하였을 때 표면 결정화가 급속히 진행되는 상변이 효과가 나타났으며, 온도가 증가함에 따라서 상변이가 일어나는 임계압력은 증가하였다. 이러한 결과는 표면상변이 현상에 대한 정성적 고찰로 사료된다.

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액정박막에서의 2차원 상전이 (Two dimensional Phase Transition of Liquid Crystal Film)

  • 정치섭;;김만원
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1993년도 춘계학술대회 논문집
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    • pp.119-121
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    • 1993
  • Two dimensional phase transition and three dimensional propagation of layer structures of liquid crystal film are investigated by using surface second harmonic generation method. We have found a distinctive first order phase transition between a monolayer phase and a stable 3-layer phase of 8CB liquid crystal film.

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Image registration using Hough transform and Phase correlation in Wavelet domain

  • Summar, Bhuttichai;Chitsobhuk, Orachat;Kasemsiri, Watjanapong
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2005년도 ICCAS
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    • pp.2006-2009
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    • 2005
  • This paper presents a method for registering images using phase correlation technique in fourier domain, hough transform and multi-resolution wavelet. To register images, source and input images are transformed to wavelet domain. An angular transition can be obtained by applying hough transform technique followed by phase correlation. Then we apply phase correlation technique to find x-axis and y-axis transition. We apply wavelet transform to reduce processing time and also use its coefficients as edge information instead of canny detector. With multi-resolution property of wavelet transform, registration time can be greatly reduced. After we get all transition parameters, we transform the input images according to these parameters. Then, we compose and blend all images into a new large image with details of all source images. From our experiment, we can find the accurate transition both x-y translation and angular transition with less error.

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Trajectory Optimization for Autonomous Berthing of a Twin-Propeller Twin-Rudder Ship

  • Changyu Lee;Jinwhan Kim
    • 한국해양공학회지
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    • 제37권3호
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    • pp.122-128
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    • 2023
  • Autonomous berthing is a crucial technology for autonomous ships, requiring optimal trajectory planning to prevent collisions and minimize time and control efforts. This paper presents a two-phase, two-point boundary value problem (TPBVP) strategy for creating an optimal berthing trajectory for a twin-propeller, twin-rudder ship with autonomous berthing capabilities. The process is divided into two phases: the approach and the terminal. Tunnel thruster use is limited during the approach but fully employed during the terminal phase. This strategy permits concurrent optimization of the total trajectory duration, individual phase trajectories, and phase transition time. The efficacy of the proposed method is validated through two simulations. The first explores a scenario with phase transition, and the second generates a trajectory relying solely on the approach phase. The results affirm our algorithm's effectiveness in deciding transition necessity, identifying optimal transition timing, and optimizing the trajectory accordingly. The proposed two-phase TPBVP approach holds significant implications for advancements in autonomous ship navigation, enhancing safety and efficiency in berthing operations.

고압하에서 방사광을 이용한 흑연에 대한 연구 (Phase Transition Study on Graphite at Room Temperature)

  • Kim, Young-Ho;Na, Ki-Chang
    • 암석학회지
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    • 제6권2호
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    • pp.88-95
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    • 1997
  • High pressure X-ray diffraction study was carried out on a polycrystalline graphite to investigate the phase transition(s) at room temperature. Energy dispersive X-ray diffraction method was employed using a Mao-Bell type diamond anvil cell with an Wiggler synchrotron Radiation at the National Synchrotron Light Source. Sodium chloride power was used as the internal pressure sensor for the high pressure determinations as well as the pressure medium for quasihydrostatic pressure environment. Graphite transforms into a hexagonal didose not agree with the previously reported observations and this phase persists when pressure is released down to 0.1 MPa. This result dose not agree with the previously reported observations and this discrepancy would be due to the kinetics in phase transition as well as the uniaxially oriented pressure field in the diamond anvil cell.

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근접장 마이크로파 현미경을 이용한 Copper(II)-phthalocyanine의 Phase Transition 연구 (Study of Phase Transition of Copper(II)-phthalocyanine using a Near Field Scanning Microwave Microscope)

  • 박미화;유현준;윤순일;임은주;이기진;차덕준;이용산
    • 한국전기전자재료학회논문지
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    • 제17권6호
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    • pp.641-646
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    • 2004
  • We report the changes of the microwave reflection coefficients S$_{11}$ of copper(II)-phthalocyanine (CuPc) thin films by using a near-field microwave microscope(NSMM) in order to understand the phase transition of CuPc. For a NSMM system, a high-quality microstrip resonator coupled with a dielectric resonator was used. CuPc thin films were prepared on the pre-heated glass substrates using a thermal evaporation method. The reflection coefficients S$_{11}$ of CuPc thin films were changed by the dependence on the substrate pre-heating temperatures. By comparing reflection coefficient S$_{11}$ and crystal structures, we found the phase transition of CuPc thin films from $\alpha$-phase to $\beta$-phase at the substrate heating temperature 200 $^{\circ}C$./TEX>.

Heterologous Expression and Optimized One-Step Separation of Levansucrase via Elastin-like Polypeptides Tagging System

  • Kang, Hye-Jin;Kim, Jin-Hee;Chang, Woo-Jin;Kim, Eung-Soo;Koo, Yoon-Mo
    • Journal of Microbiology and Biotechnology
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    • 제17권11호
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    • pp.1751-1757
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    • 2007
  • Elastin-like polypeptides (ELPs) undergo a reversible inverse phase transition upon a change in temperature. This thermally triggered phase transition allows for a simple and rapid means of purifying a fusion protein. Recovery of ELPs-tagged fusion protein was easily achieved by aggregation, triggered either by raising temperature or by adding salt. In this study, levansucrase has been used as a model enzyme in the development of a simple one-step purification method using ELPs. The levansucrase gene cloned from Pseudomonas aurantiaca S-4380 was tagged with various sizes of ELPs to functionally express and optimize the purification of levansucrase. One of two ELPs, ELP[V-20] or ELP[V-40], was fused at the C-terminus of the levansucrase gene. A levansucrase-ELP fusion protein was expressed in Escherichia coli $DH5{\alpha}$ at $37^{\circ}C$ for 18 h. The molecular masses of levansucrase-ELP[V-20] and levansucrase-ELP[V-40] were determined as 56 kDa and 65 kDa, respectively. The phase transition of levansucrase-ELP[V-20] occurred at $20^{\circ}C$ in 50 mM Tris-Cl (pH 8) buffer with 3 M NaCl added, whereas the phase transition temperature ($T_t$) of levansucrase-ELP[V-40] was $17^{\circ}C$ with 2 M NaCl. Levansucrase was successfully purified using the phase transition characteristics of ELPs, with a recovery yield of higher than 80%, as verified by SDS-PAGE. The specific activity was measured spectrophotometrically to be 173 U/mg and 171 U/mg for levansucrase-ELP[V-20] and levansucrase-ELP[V-40], respectively, implying that the ELP-tagging system provides an efficient one-step separation method for protein purification.