• Korean Journal of Materials Research
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• v.16 no.1
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• pp.50-57
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• 2006

Phase mixtures of Titanium boride, nitride, and carbide powder were produced by the reduction of a mixture of titanium and boron oxides with carbon via a gas-solid phase reaction. Boron oxides produce a vapour phase or decompose to a metal sub-oxide gaseous species when reduced at elevated temperature. The mechanism of BO sub-oxide gas formation from $B_2O_3$ and its subsequent reduction to titanium diboride for the production of uniform size hexagonal platelets is explained. These gaseous phases are critical for the formation of boride, nitride and carbide ceramics. For the production of ceramic phase composite microstructures, the nitrogen partial pressure was the most critical factor. Some calculated equilibrium phase fields has been verified experimentally. The theoretical approach therefore identifies conditions for the formation of phase mixtures. The thermodynamic and kinetic factors that govern the phase constituents are also discussed.

• Nuclear Engineering and Technology
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• v.51 no.3
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• pp.761-768
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• 2019

Understanding the phenomena of formation of single drops is necessary to understand the hydrodynamics in solvent extraction equipment which are used for separation of nuclear materials. In this work, the phenomena of aqueous phase and organic phase drop formation at submerged nozzles are compared by conducting experiments with 30%TBP (v/v) in dodecane as the organic phase and nitric acid as the aqueous phase. Two different nozzles and three different nitric acid concentrations are used. For each nozzle and nitric acid concentration, velocity of the dispersed phase is varied. Drops of aqueous phase formed at downward oriented nozzles submerged in organic phase are observed to be smaller than the drops of organic phase formed at upward oriented nozzles submerged in aqueous phase. Correlations to estimate drop diameter are proposed.

• Nuclear Engineering and Technology
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• v.52 no.3
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• pp.610-613
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• 2020

Specimens of austenitic stainless steel were irradiated with 6 MeV Xe ions to two doses of 7 and 15 dpa at room temperature and 300 ℃ respectively. Then partial irradiated specimens were subsequently thermally annealed at 550 ℃. Irradiation-induced BCC-phase formation and magnetism were analyzed by grazing incidence X-ray diffraction (GIXRD) and vibrating sample magnetometer (VSM). It has been shown that irradiation damage level, irradiation temperature and annealing temperature have significant effect on BCC-phase formation. This BCC-phase changes the magnetic behavior of austenitic stainless steel. The stress relief and compositional changes in matrix are the driving forces for BCC-phase formation in austenitic stainless steel during ion irradiation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.04a
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• pp.17-20
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• 2002

The effects of relatively low lead content (0.2~0.3) on the 2223 phase formation and transport property of Bi-2223/Ag tapes have been investigated. The results show that lead contents have great impact on the phase assemblage of precursors, subsequently, on the phase formation and transport property of silver sheathed BSCCO-2223 tapes. Powders containing Pb=0.25 and Pb=0.3 resulted in the nearly identical $J_c$ values in fully processed tapes, but leaded to significant difference on the phase formation process. For the case of Pb=0.2, both low conversion fraction of 2212 to 2223 and low $J_c$ value were obtained in final reacted tape, which was probably due to lack of enough liquid phase to facilitate the phase transformation.

• Journal of the Semiconductor & Display Technology
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• v.7 no.2
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• pp.1-5
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• 2008

Silicide formation process and the formation sequence were investigated in this study. It was postulated that the formation of the second silicide phase involves glass formation between the first silicide phase and Si given that a thin metal film is deposited on a Si substrate. The concentration of glass was assumed to be located where the free energy of the liquid alloy with respect to the first nucleated compound and solid Si (${\Delta}$G') is most negative. It was also mentioned that the glass concentration is close to the composition of the second phase in order to achieve the maximum energy degradation. It was shown that the minimum ${\Delta}$G' concentration can be estimated by interpolating the portion of the liquidus where the liquid alloy is in equilibrium with the two solid constituents, namely the first compound phase and Si, thereby forming a hypothetical eutectic.

• Journal of the Korean Ceramic Society
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• v.30 no.9
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• pp.723-730
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• 1993

The mechanism of formation of perovskite phase and the dielectric properties of PZMN[Pb(Zn, Mg)1/3Nb2/3O3] ceramics were examined using two different types of the columbite precursors, (Mg, Zn)Nb2O6 (MZN) and MgNb2O6＋ZnNb2O6 (MN＋ZN). The formatin of perovskite phase in PbO＋MN＋ZN system is characterized by an initial rapid formation of Mg-rich perovskite phase, followed by a sluggish formation of Zn-rich perovskite phase. On the other hand, thepyrochlore/perovskite transformation in the PbO＋MZN system proceeded uniformly with a spatial homogeneity. The degree of diffuseness of the rhombohedral/cubic phase transitionis higher in the PbO＋MN＋ZN system than in the PbO＋MZN specimen, indicating a broadened compositional distributjion of the B-site catons (Nb+5, Zn+2, Mg+2) in the PbO＋MN＋ZN system.

• Proceedings of the KIEE Conference
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• 1991.11a
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• pp.311-315
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• 1991

The formation and transition of 2212 and 2223 phase have been studied in BPSCCO system. The 2212 phase formed in early sintering state reacts on $Ca_2PbO_4,\;Ca_2CuO_3$ and CuO during sintering process and thus produces the 2223 phase. A long sintering period is need to fabricate the superconductor with large volume fraction of 2223 phase. Also, the thin plate-like grains composed of Bi, Sr, Ca and Cu contribute to 2223 phase formation. Though the sample has lower volume fraction of 2223 phase, the critical temperature is measured highly in case of the grain grown to plate-like shape. In this work, the critical temperature of the sample sintered for 264 hr in air was measured 108 K. Microstructure of the sample was varied with condition of heat treatment after sintering process and the sample annealed with $500^{\circ}C$ for 5 hr showed excellent charateristics of 2223 phase formation.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.4
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• pp.412-418
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• 2007

The purpose of this study was to determine the several factors for affecting chlorine disinfection by-products(DBPs) characteristics by reacting chlorine and organic matters in the aquatic phase. The results of this research yield the following specific conclusions: The concentration of trihalomethanes(THMs) was increased with increasing dissolved organic carbon(DOC), and a trend of THMs formation was parabolic with increasing organic matters. Formations of THMs increased straightly for the first 4 hours and the amounts of producted THMs for the 30 minutes were up to $25\sim43%$ in the entire experiment periods(168 hours). When keeping up the concentration of organic matters at constant and changing that of bromide, the quantity of formed THMs did not show distinguished difference with the reaction times. THMs were gradually increased at $4^{\circ}C$ even though a reaction phase was parabolic formation(PF) phase. However, THMs were increased rapidly in the instantaneous formation(IF) phase and then became slowdown in the PF phase between $20\sim35^{\circ}C$. THMs were gradually increased although entering in the PF phase at pH 5. However, THMswere increased rapidly in the IF phase and then became slowdown in the PF phase at pH 7 and pH 9, and these treads were much more clear at pH 9 than at pH 7.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.1
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• pp.40.1-40.1
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• 2019

We utilize times since infall of cluster galaxies obtained from Yonsei Zoom-in Cluster Simulation (YZiCS), the cosmological hydrodynamic N-body simulations, and star formation rates from the SDSS data release 10 to study how quickly late-type galaxies are quenched in the cluster environments. In particular, we confirm that the distributions of both simulated and observed galaxies in phase-space diagrams are comparable and that each location of phase-space can provide the information of times since infall and star formation rates of cluster galaxies. Then, by limiting the location of phase-space of simulated and observed galaxies, we associate their star formation rates at z ~ 0.08 with times since infall using an abundance matching technique that employs the 10 quantiles of each probability distribution. Using a flexible quenching model covering different quenching scenarios, we find the star formation history of satellite galaxies that best reproduces the obtained relationship between time since infall and star formation rate at z ~ 0.08. Based on the derived star formation history, we constrain the quenching timescale (2 - 7 Gyr) with a clear stellar mass trend and confirm that the refined model is consistent with the "delayed-then-rapid" quenching scenario: the constant delayed phase as ~ 2.3 Gyr and the quenching efficiencies (i.e., e-folding timescale) outside and inside clusters as ~ 2 - 4 Gyr (${\propto}M_*^{-1}$) and 0.5 - 1.5 Gyr (${\propto}M_*^{-2}$), Finally, we suggest: (i) ram-pressure is the main driver of quenching of satellite galaxies for the local Universe, (ii) the quenching trend on stellar mass at z > 0.5 indicates other quenching mechanisms as the main driver.

• 한국정보디스플레이학회:학술대회논문집
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• 2004.08a
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• pp.193-197
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• 2004

The effect of the temperature dependence of the smectic layer spacing in the smectic-A (SmA) phase on the formation of defects in the ferroelectric smectic-$C^{\ast}$ ($SmC^{\ast}$) phase is investigated with x-ray scattering technique. The study is based on thin parallel-aligned surface stabilized ferroelectric liquid crystal cells with two different alignment conditions, high pretilt $SiO_x$, alignment and low pretilt polyimide films. It is found that defects observed in the $SmC^{\ast}$ phase have much more profound dependence on the layer changes and chevron formation in the SmA phase than in the $SmC^{\ast}$ phase. We find that thermal layer expansion with decreasing temperature in the SmA phase suppresses the formation of defects observed in the SmC phase.