• Title/Summary/Keyword: Phase evolution

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Microstructural Evolution in CuCrFeNi, CuCrFeNiMn, and CuCrFeNiMnAl High Entropy Alloys

  • Hyun, Jae Ik;Kong, Kyeong Ho;Kim, Kang Cheol;Kim, Won Tae;Kim, Do Hyang
    • Applied Microscopy
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    • v.45 no.1
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    • pp.9-15
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    • 2015
  • In the present study, microstructural evolution in CuCrFeNi, CuCrFeNiMn, and CuCrFeNiMnAl alloys has been investigated. The as-cast CuCrFeNi alloy consists of a single fcc phase with the lattice parameter of 0.358 nm, while the as-cast CuCrFeNiMn alloy consists of (bcc+fcc1+fcc2) phases with lattice parameters of 0.287 nm, 0.366 nm, and 0.361 nm. The heat treatment of the cast CuCrFeNiMn alloy results in the different type of microstructure depending on the heat treatment temperature. At $900^{\circ}C$ a new thermodynamically stable phase appears instead of the bcc solid solution phase, while at $1,000^{\circ}C$, the heat treated microstructure is almost same as that in the as-cast state. The addition of Al in CuCrFeNiMn alloy changes the constituent phases from (fcc1+fcc2+bcc) to (bcc1+bcc2).

Evolution of grains to relieve additional compressive stress developed in Al-Mg alloy films during thermal annealing (Al-Mg 합금 박막의 압축응력 완화를 위한 어닐링 공정상의 입자 발달)

  • Lee, Jun-Seong;Yang, Ji-Hun;Jeong, Jae-In;Jeong, Yong-Hwa;Gwak, Yeong-Jin;Kim, Sang-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.47-51
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    • 2014
  • In this work, a possible mechanism for grain evolution in Al-Mg alloy films during thermal annealing is suggested on the basis of the phase transition and the related residual stress. Al-Mg alloy films with compositions of 14.0 and 18.0 wt% Mg content were deposited on cold-rolled steel substrates by the direct current co-sputtering method using Al and Mg targets. After the deposition, the samples were thermally annealed at $400^{\circ}C$ for 10 min. The featureless, dense cross-sectional microstructure of the as-deposited films turned into a grainy microstructure after the thermal annealing. According to the residual stress evaluated by using the $XRD-sin2{\psi}$ technique and the phase analysis by XRD, it is likely that grains were created in order to relieve the additional accumulation of residual stress originating from the phase transition from face-centered cubic Al (${\alpha}$) to Al3Mg2 (${\beta}$) and Mg (${\delta}$) phases, suggesting interplay between the microstructure and residual stress.

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Influence of Phase Evolution and Texture on the Corrosion Resistance of Nitrogen Ion Implanted STS 316L Stainless Steel (질소 이온이 주입된 STS 316L 스테인리스 강에서의 상변화와 집합조직이 내식성에 미치는 영향)

  • Jun, Shinhee;Kong, Young-Min
    • Korean Journal of Materials Research
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    • v.25 no.6
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    • pp.293-299
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    • 2015
  • In this study, nitrogen ions were implanted into STS 316L austenitic stainless steel by plasma immersion ion implantation (PIII) to improve the corrosion resistance. The implantation of nitrogen ions was performed with bias voltages of -5, -10, -15, and -20 kV. The implantation time was 240 min and the implantation temperature was kept at room temperature. With nitrogen implantation, the corrosion resistance of 316 L improved in comparison with that of the bare steel. The effects of nitrogen ion implantation on the electrochemical corrosion behavior of the specimen were investigated by the potentiodynamic polarization test, which was conducted in a 0.5 M $H_2SO_4$ solution at $70^{\circ}C$. The phase evolution and texture caused by the nitrogen ion implantation were analyzed by an X-ray diffractometer. It was demonstrated that the samples implanted at lower bias voltages, i.e., 5 kV and 10 kV, showed an expanded austenite phase, ${\gamma}_N$, and strong (111) texture morphology. Those samples exhibited a better corrosion resistance.

Identification of crystal variants in shape-memory alloys using molecular dynamics simulations

  • Wu, Jo-Fan;Yang, Chia-Wei;Tsou, Nien-Ti;Chen, Chuin-Shan
    • Coupled systems mechanics
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    • v.6 no.1
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    • pp.41-54
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    • 2017
  • Shape-memory alloys (SMA) have interesting behaviors and important mechanical properties due to the solid-solid phase transformation. These phenomena are dominated by the evolution of microstructures. In recent years, the microstructures in SMAs have been studied extensively and modeled using molecular dynamics (MD) simulations. However, it remains difficult to identify the crystal variants in the simulation results, which consist of large numbers of atoms. In the present work, a method is developed to identify the austenite phase and the monoclinic martensite crystal variants in MD results. The transformation matrix of each lattice is calculated to determine the corresponding crystal variant. Evolution of the volume fraction of the crystal variants and the microstructure in Ni-Ti SMAs under thermal and mechanical boundary conditions are examined. The method is validated by comparing MD-simulated interface normals with theoretical solutions. In addition, the results show that, in certain cases, the interatomic potential used in the current study leads to inconsistent monoclinic lattices compared with crystallographic theory. Thus, a specific modification is applied and the applicability of the potential is discussed.

Critical earthquake loads for SDOF inelastic structures considering evolution of seismic waves

  • Moustafa, Abbas;Ueno, Kohei;Takewaki, Izuru
    • Earthquakes and Structures
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    • v.1 no.2
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    • pp.147-162
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    • 2010
  • The ground acceleration measured at a point on the earth's surface is composed of several waves that have different phase velocities, arrival times, amplitudes, and frequency contents. For instance, body waves contain primary and secondary waves that have high frequency content and reach the site first. Surface waves are composed of Rayleigh and Love waves that have lower phase velocity, lower frequency content and reach the site next. Some of these waves could be of more damage to the structure depending on their frequency content and associated amplitude. This paper models critical earthquake loads for single-degree-of-freedom (SDOF) inelastic structures considering evolution of the seismic waves in time and frequency. The ground acceleration is represented as combination of seismic waves with different characteristics. Each seismic wave represents the energy of the ground motion in certain frequency band and time interval. The amplitudes and phase angles of these waves are optimized to produce the highest damage in the structure subject to explicit constraints on the energy and the peak ground acceleration and implicit constraints on the frequency content and the arrival time of the seismic waves. The material nonlinearity is modeled using bilinear inelastic law. The study explores also the influence of the properties of the seismic waves on the energy demand and damage state of the structure. Numerical illustrations on modeling critical earthquake excitations for one-storey inelastic frame structures are provided.

Changes in product innovation strategy reflecting industry evolutionary phases and dynamic capabilities in the Korea Wireless Internet industry (산업진화단계와 동태적역량에 따른 제품혁신 전략의 변화: 한국 무선인터넷 산업을 중심으로)

  • Yoo, Jae-Hong;Kim, Byung-Keun
    • Journal of Technology Innovation
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    • v.18 no.2
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    • pp.253-288
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    • 2010
  • Production innovation capabilities are critical to the survival and growth of firms. This paper investigates industrial dynamics and dynamic capabilities of firms by looking at how an industry evolution process influences firms' product innovation strategy and how dynamic capabilities affect firms' product innovation process. Korea Wireless Internet industry shows a full cycle of industry evolution process including introduction phase, growth phase, maturity phase, and decline phase using by dynamic technological and market changes. 7 listed companies in Korea Wireless Internet industry were selected. We have conducted multiple case studies based upon in depth interviews. Empirical results show that different phases of industry evolution influence firms' strategy of product innovation. Dynamic capabilities are also appears to be very important to the survival and growth of a firm.

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DYNAMICAL EVOLUTION OF ROTATING SINGLE-MASS STELLAR CLUSTER

  • ARDI ELIANI;SPURZEM RAINER;MINESHIGE SHIN
    • Journal of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.207-210
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    • 2005
  • We study the influence of rotation on the dynamical evolution of collisional single-mass stellar clusters up to core-collapse by using N-body simulations. Rotating King models which are characterized by dimensionless central potential parameter $W_o$ and the rotation parameter $W_o$ are used as initial models. Our results show that inner shells slowly contract until core-collapse phase is reached, followed by a slow expansion. Angular momentum is transported outward, while the core is rotating even faster than before, as predicted by gravogyro catastrophe theory. We confirm that rotation plays an important role in accelerating the dynamical evolution of stellar cluster, in particular in accelerating the core collapse.

Effect of Initial Orientation and Austenitic Phase on Texture Evolution in Ferritic Stainless Steels (페라이트계 스테인레스강의 집합조직 형성에 미치는 초기 방위 및 오스테나이트사의 영향)

  • 이용득
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.03a
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    • pp.149-152
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    • 1999
  • The effect of initial orientation on the microstructure and texture evolution of two ferritic stainless steels was investigated. the columnar and equiaxed crystal specimens which were prepared from continuous casting slab were hot rolled annealed cold rolled and annealed respectively. The rolling and recrystallization textures at each process stage were examined by orientation distribution function (ODF) and electron back-scattered diffraction (EBSD); The observation showed that the orientation density of the $\alpha$-fibre of hot rolled band of columnar crystal specimen was more pronounced than that of the equaxed one at the center layer. Nevertheless the cold rolled textures of Type 430 steel have demonstrated a rather similar development . Compared to Type 430 steel the development of the $\alpha$-fibre in the center layer of Type 409L steel was much more pronounced. The relation between texture evolution and ridging behaviour has been discussed.

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