• Journal of Korean Society for Atmospheric Environment
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• 제21권E2호
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• pp.57-65
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• 2005

An experimental study was performed on the decomposition of gaseous ammonia and two selected volatile organic compounds (VOCs: toluene and acetone) in a combined nonthermal plasma reactor with corona and glow discharges. A lab pilot scale reactor (206 liter) equipped with a high electric power pack was used to determine the decomposition efficiency in relation with the inlet concentration and applied voltage. Three different types of discharging electrode such as wired rack, wire strings for corona discharge, and thin plate for glow discharge were put in order in the reactor. While decomposition of ammonia decreased with an increase in the initial concentration, acetone showed an opposite result. In the case of toluene however no explicit tendency was found in toluene and aceton. Negative discharge resulted in high decomposition efficiency than the positive one for all gases. A better removal of gas phase element could be achieved when fume dust were present simultaneously.

• Bulletin of the Korean Chemical Society
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• 제11권4호
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• pp.343-347
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• 1990

A thermal decomposition of the tert-butoxy radical has been studied in the gas phase over the pressure range of 1-200 torr at $413_{\circ}K$ using di-tert-butyl peroxide + trimethylsilane mixtures. The relative rate constants were obtained by studying the competitive reactions between tert-butoxy radical decomposition 4(t-BuO·→ CH_3COCH_3 + CH_3·)$ and hydrogen abstraction reaction from trimethylsilane $(t-BuO·+ HSi(CH_3)_3 → t-BuOH + Si(CH_3)_3)·).$ The conventional RRKM calculations were carried out to compare the observed fall-off behavior of the decomposition rate constant $({\kappa}_d)$ with the theoretical predictions using reasonable values of input parameters. In all cases the calculated half-rate pressure $(P_{1/2})$ were significantly higher than those observed. The failure of RRKM to reproduce the fall-off behavior led us to suggest that not all of vibrational modes contribute to excitation (leading to decomposition) on the same time scale.

• 정보처리학회논문지B
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• 제19B권1호
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• pp.63-76
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• 2012

본 논문에서는 통계기반의 복합명사 분해 방법과 어휘의미망(U-WIN)과 사전 뜻풀이에서 추출한 의미관계 정보를 이용하는 한국어 복합명사 의미 태깅 시스템을 제안한다. 본 시스템은 크게 복합명사 분해, 의미제약, 그리고 의미 태깅의 세 가지 부분으로 이루어진다. 분해과정은 세종말뭉치에서 추출한 위치별명사 빈도를 사용하여 최적의 구성 명사 분해 후보를 선정하고 의미제약을 위한 구성 명사 재분해와 외래어 복원의 과정을 수행한다. 의미범위 제약과정은 유사도 비교의 계산량을 줄이고 정확도를 높이기 위해 원어 정보와 Naive Bayes Classifier를 이용해 가능한 경우 구성 명사의 의미를 선 제약한다. 의미 분석 및 태깅 과정에서는 bigram 구성 명사의 각 의미 유사도를 구하고 하나의 체인을 만들어가며 태깅을 수행한다. 본 시스템의 성능 평가를 위해 표준국어대사전에서 추출한 3음절 이상의 40,717개의 복합명사를 대상으로 의미 태깅된 테스트 셋을 구축하였다. 이를 이용한 실험에서 99.26%의 분해 정확도를 보였으며, 95.38%의 의미 분석 정확도를 보였다.

• 한국항공우주학회지
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• 제37권6호
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• pp.537-544
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• 2009

본 논문에서는 안정성 영역 판별법(stability area) 기반 발사체의 자세제어기 이득결정과정에 대한 내용을 기술하였다. 안정성 영역 판별법은 D-Decomposition 기법으로부터 정의되는 것으로 본 논문에서는 D-Decomposition 기본 이론과 이로부터 산출된 발사체의 자세 안정성 영역을 도시하고, 적용 예로써 일반적인 발사체의 1단 추력 비행구간에서 자세제어기 설계과정을 제시하였다. 제어이득 결정을 위해서 중첩된 안정성 영역을 바탕으로 시스템 파라미터 불확실성을 고려 안정성 영역 경계(stability area boundary)를 설정하고, 선정된 제어이득을 발사체 선형모델에 적용, 자세 안정성 분석 수행 결과를 나타냈다.

• 대한수학회지
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• 제58권2호
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• pp.451-471
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• 2021

First, we define phase tropical hypersurfaces in terms of a degeneration data of smooth complex algebraic hypersurfaces in (ℂ∗)n. Next, we prove that complex hyperplanes are homeomorphic to their degeneration called phase tropical hyperplanes. More generally, using Mikhalkin's decomposition into pairs-of-pants of smooth algebraic hypersurfaces, we show that a phase tropical hypersurface with smooth tropicalization is naturally a topological manifold. Moreover, we prove that a phase tropical hypersurface is naturally homeomorphic to a symplectic manifold.

• 한국세라믹학회지
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• 제34권9호
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• pp.949-956
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• 1997

With the increase of ZnO content, burnability of raw materials was improved and the formation of clinker minerals was accellerated. When ZnO was added 1wt%, the clinkering temperature was decreased about 30~5$0^{\circ}C$. As an increase of ZnO added, aluminate phase was decreased and ferrite phase was increased. When ZnO was added more than 3.0wt.%, the new phases, such as ZnO.Al2O3 and ZnO.Fe2O3 were formed. In the excess of amount of ZnO added, the decomposition of alite phase was intensed and the lamella structure in belite could not be observed due to the decomposition.

• 한국광물학회지
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• 제12권1호
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• pp.11-22
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• 1999

Thermal behavior of dickite was studied by thermal analysis, X-ray diffraction analysis, electron microprobe analysis, and scanning electron microscopy, Dickite has an endothermic peak at about$ 650^{\circ}C$ and an exothermic one at $960^{\circ}C$ in the differential thermal analysis. The endothermic reaction is assigned to the decomposition of dickite to meta-dickite. Hydroxyl radicals are removed from dickite structure by the reaction, resulting in the weight loss about 10.5~14.5% and appearance of a 14$\AA$ phase different from other kaolin minerals. The reaction slowly proceed in the range of $200^{\circ}C$. As the completion of decomposition, aciclular mullite forms at the expense of meta-dickite plates with random crystallographic relationship. Mullites have diverse silica versus alumina ratio. The exothermic reaction without weight loss seems to be due to the formation of spinel and amorphous silica. The spinel phase shows cryptocrystalline globular morphology accompanying a little amount of silica. From spinel phase shows cryptocrystalling globular morphology accompanying a little amount of silica. From this work, it is suggested that mullite is formed from meta-dickite much lower temperature than the reported one in the previous works.

• 한국세라믹학회지
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• 제27권6호
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• pp.707-712
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• 1990

The basic zirconium sulfate was prepared from ZrOCl2.8H2O and H2SO4 in the 9$0^{\circ}C$ aqueous solution. The pH and amount of unreacted zirconium in the solution that reacton had completed was 0.2 and 10%. As the pH was increased to 1.4 by NH4OH theresulting precipitates were the mixtures of the basic zirconium sulfate and the zirconium hydroxide although the precipitates were recovered completely. The thermal decomposition behavior of this sample has been examined by thermal analysis(TG-DTA), X-ray diffraction study, infrared spectroscopy and sulfur analysis. As a result, it was found that the precipitates have perfectly been decomposed at 85$0^{\circ}C$ accompanying to the release of a molecule of water below 25$0^{\circ}C$ and 85% sulfate at about $600^{\circ}C$. The thermally decomlposed products were initially amorphous phase, which were become metastable tetragonal phase with increment of temperature and finally transformed to the stable monoclinic phase at 100$0^{\circ}C$.

• Journal of Ecology and Environment
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• 제34권4호
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• pp.401-410
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• 2011

We assayed the effects of simulated acid rain on the mass loss, $CO_2$ evolution, dehydrogenase activity, and microbial biomass-C of decomposing Sorbus alnifolia leaf litter at the microcosm. The dilute sulfuric acid solution composed the simulated acid rain, and the microcosm decomposition experiment was performed at 23$^{\circ}C$ and 40% humidity. During the early decomposition stage, decomposition rate of S. alnifolia leaf litter, and microbial biomass, $CO_2$ evolution and dehydrogenase activity were inhibited at a lower pH; however, during the late decomposition stage, these characteristics were not affected by pH level. The fungal component of the microbial community was conspicuous at lower pH levels and at the late decomposition stage. Conversely, the bacterial community was most evident during the initial decomposition phase and was especially dominant at higher pH levels. These changes in microbial community structure resulting from changes in microcosm acidity suggest that pH is an important aspect in the maintenance of the decomposition process. Litter decomposition exhibited a positive, linear relationship with both microbial respiration and microbial biomass. Fungal biomass exhibited a significant, positive relationship with $CO_2$ evolution from the decaying litter. Acid rain had a significant effect on microbial biomass and microbial community structure according to acid tolerance of each microbial species. Fungal biomass and decomposition activities were not only more important at a low pH than at a high pH but also fungal activity, such as $CO_2$ evolution, was closely related with litter decomposition rate.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2002년도 추계학술발표강연 및 논문개요집
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• pp.34-34
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• 2002