• Proceeding of EDISON Challenge
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• 2015.03a
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• pp.138-146
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• 2015

액체 상태의 물질이 매우 급속하게 냉각되면 일반적으로 과냉각액체(supercooled liquid) 상태에 도달한다. 과냉각액체는 더 낮은 온도에서 유리상(glass phase)으로 상전이를 일으킨다고 알려져 있는데, 이때 나타나는 동역학적 불균일성(dynamic heterogeneity)은 상전이를 기술하는데 중요한 역할을 한다. 그러나 일반적인 액체의 상전이를 연구할 때 주로 사용되던 상관함수(correlation function)으로는 이러한 불균일성을 정량적으로 표현하기 어렵기 때문에 동역학적 민감도(dynamic susceptibility)나 multi-time correlation function 등 동역학적 성질(dynamic property)로부터 특징적인 시간 개념 및 거리 개념을 도출하려는 연구가 많이 진행되어 왔다. 본 논문에서는 일반적으로 특징적인 거리 개념을 도출해 내는데 사용되는 4점 밀도 상관함수(four-point density correlation function)인 dynamic susceptibility(${\chi}^4$)가 입자 밀도의 요동(fluctuation)의 상관관계(correlation)가 지속되는 특징적인 시간 개념에 대한 정보 또한 포함하고 있다는 점에 주목하였다. 이에 따라 ${\chi}^4$의 시간에 대한 적분인 ${\tau}_4$를 새롭게 도입하였으며 그 결과로 ${\tau}_4$는 three-time density correlation function으로부터 도출한 ${\tau}_{Dh}$와 같은 축척(scaling)을 가지는 것을 확인하였다. 과냉각액체에 대한 장난감 모형(toy model)의 일종인 "Lennard-Jones potential 하에서 운동하는 서로 다른 두 종류의 입자들"을 연구에 사용하였다.

• Journal of the Korean Electrochemical Society
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• v.10 no.2
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• pp.132-140
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• 2007

The phase-shift method and correlation constants for studying a linear relationship between the behavior ($-{\varphi}\;vs.\;E$) of the phase shift ($0^{\circ}{\leq}-{\varphi}{\leq}90^{\circ}$) for the optimum intermediate frequency and that (${\theta}\;vs.\;E$) of the fractional surface coverage ($1{\geq}\theta{\geq}0$) have been proposed and verified to determine the Langmuir, Frumkin, and Temkin adsorption isotherms (${\theta}\;vs.\;E$) at noble metal/aqueous electrolyte interfaces. At an Ir/0.1 M KOH aqueous electrolyte interface, the Langmuir and Temkin adsorption isotherms (${\theta}\;vs.\;E$), equilibrium constants ($K=3.3{\times}10^{-4}\;mol^{-1}$ for the Langmuir and $K=3.3{\times}10^{-3}{\exp}(-4.6{\theta})\;mol^{-1}$ for the Temkin adsorption isotherm), interaction parameter (g = 4.6 for the Temkin adsorption isotherm), and standard free energies (${\Delta}G_{ads}^0=19.9kJ\;mol^{-1}\;for\;K=3.3{\times}10^{-4}\;mol^{-1}$ and $16.5<{\Delta}G_{\theta}^0<23.3\;kJ\;mol^{-1}\;for\;K=3.3{\times}10^{-3}{\exp}(-4.6{\theta})\;mol^{-1}\;and\;0.2<\theta<0.8$) of H for the cathodic $H_2$ evolution reaction are determined using the phase-shift method and correlation constants. The inhomogeneous and lateral interaction effects on the adsorption of H are negligible. At the intermediate values of ${\theta},\;i.e,\;0.2<{\theta}<0.8$, the Temkin adsorption isotherm (${\theta}\;vs.\;E$) correlating with the Langmuir or the Frumkin adsorption isotherm (${\theta}\;vs.\;E$), and vice versa, is readily determined using the correlation constants. The phase-shift method and correlation constants are accurate and reliable techniques to determine the adsorption isotherms (${\theta}\;vs.\;E$) and related electrode kinetic and thermodynamic parameters(K, g, ${\Delta}G_{ads}^0, {\Delta}G_{\theta}^0$).

• Journal of Radiation Protection and Research
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• v.33 no.1
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• pp.13-20
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• 2008

The flow rate measurements in a multi-phase flow pipeline were evaluated quantitatively by means of a clamp-on sealed radioisotope based on a cross correlation signal processing technique. The flow rates were calculated by a determination of the transit time between two sealed gamma sources by using a cross correlation function following FFT filtering, then corrected with vapor fraction in the pipeline which was measured by the ${\gamma}$-ray attenuation method. The pipeline model was manufactured by acrylic resin(ID. 8 cm, L=3.5 m, t=10 mm), and the multi-phase flow patterns were realized by an injection of compressed $N_2$ gas. Two sealed gamma sources of $^{137}Cs$ (E=0.662 MeV, ${\Gamma}$ $factor=0.326\;R{\cdot}h^{-1}{\cdot}m^2{\cdot}Ci^{-1}$) of 20 mCi and 17 mCi, and radiation detectors of $2"{\times}2"$ NaI(Tl) scintillation counter (Eberline, SP-3) were used for this study. Under the given conditions(the distance between two sources: 4D(D; inner diameter), N/S ratio: $0.12{\sim}0.15$, sampling time ${\Delta}t$: 4msec), the measured flow rates showed the maximum. relative error of 1.7 % when compared to the real ones through the vapor content corrections($6.1\;%{\sim}9.2\;%$). From a subsequent experiment, it was proven that the closer the distance between the two sealed sources is, the more precise the measured flow rates are. Provided additional studies related to the selection of radioisotopes their activity, and an optimization of the experimental geometry are carried out, it is anticipated that a radioisotope application for flow rate measurements can be used as an important tool for monitoring multi-phase facilities belonging to petrochemical and refinery industries and contributes economically in the light of maintenance and control of them.

• Transactions of the Korean Society of Mechanical Engineers
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• v.8 no.1
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• pp.48-56
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• 1984

In order to estimate the fuel rod temperature during the reflooding phase of the PWR LOCA, it is essential to obtain a better understanding of the rewetting mechanism. This paper presents the results of analytical and experimental investigations aimed at analyzing the rewetting phenomena in a heated tube. A two-dimensional solution of the rewetting for a tube is described and used to yield the correlation of the rewetting heat transfer coefficient as the function of flooding rate and inlet subcooling. This correlation prediction is in good agreement with the experimental data.

• Proceedings of the Korea Electromagnetic Engineering Society Conference
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• 2000.11a
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• pp.16-19
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• 2000

We propose a deterministic vector channel simulation model satisfying not only rigorous temporal correlation but also arbitrary spatial correlation using the method of Doppler phase difference sampling. The model is more efficient than the conventional PN filtered Gaussian model with coloring process in evaluating the laboratory performance of mobile communication systems employing adaptive way antennas or space diversity.

• Proceedings of the IEEK Conference
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• 1999.11a
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• pp.609-612
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• 1999

In this paper, we propose wavelet transform image compression method such that an image is decomposed into multiresolutions using biorthogonal wavelet transform with linear phase response property and decomposed subbands are classified by maximum classification gain. The classified data is quantized by allocating bits in accordance with classified class informations within subbands through arbitrary set bit allocation algorithm. And then, quantized data in each subband are entropy coded. The proposed coding method is that the quantized data perform shuffling before entropy coding in order to remove sign bit plane. And the context is assigned by maximum correlation direction for bit plane coding.

• ETRI Journal
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• v.21 no.3
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• pp.1-5
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• 1999

A clock and data recovery circuit with a phase-locked loop for 10 Gb/s optical transmission system was realized in a hybrid IC form. The quadri-correlation architecture is used for frequency-and phase-locked loop. A NRZ-to-PRZ converter and a 360 degree analogue phase shifter are included in the circuit. The jitter characteristics satisfy the recommendations of ITU-T. The capture range of 150 MHz and input voltage sensitivity of 100 mVp-p were showed. The temperature compensation characteristics were tested for the operating temperature from -10 to $60^{\circ}C$ and showed no increase of error. This circuit was adopted for the 10 Gb/s transmission system through a normal single-mode fiber with the length of 400 km and operated successfully.

• Nuclear Engineering and Technology
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• v.52 no.9
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• pp.2047-2053
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• 2020

Single-tube burst tests on hydrogenated Zircaloy-4 nuclear fuel cladding under simulated loss-of-coolant accident are conducted to evaluate the impact of hydrogen on burst parameters. The heating rate and initial pressure are varied from 5 K/s to 150 K/s and 5 bar-80 bar, respectively. The hydrogen concentration in the cladding is in the range of 0-2000 wppm. Burst stress is lower for hydrogenated cladding in α-phase. A significant loss of ductility is observed in α-phase and lower α + β-phase for hydrogenated cladding. However, the burst strain is higher for hydrogenated cladding in β-phase. There is a sigmoidal dependency of rupture area with initial stress and rupture area is larger for hydrogenated cladding. A novel burst stress correlation for hydrogenated Zircaloy-4 cladding has been proposed.

• Natural Product Sciences
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• v.10 no.6
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• pp.262-267
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• 2004

A reversed-phase liquid chromatographic method for decursin and decursinol angelate of Angelicae gigantis Radix, an important crude drug in Korean traditional medicine, was developed and validated. Decursin and decursinol angelate, the structure isomer (pyranocoumarin) each other, are the main organic constituents in Angelicae gigantis Radix. This method was developed using a RP-18 column, UV detector at 280 nm and 50% acetonitrile solution containing 0.01 M sodium dodecyl sulfate and 25 mM sodium dihydrogen phosphate (pH 5.0) as the mobile phase. Various validation parameters were included and evaluated satisfactorily. Linearity was established in range 2-75 mg/ml of decursin and decursinol angelate (correlation coefficient = 0.9997 and 0.9995, respectively). This analytical method showed good accuracy (98.1% and 99.5%, respectively). Precision (repeatability) revealed a relative standard deviation value of 1.71% (decursin) and 3.19% (decursinol angelate). For intermediate precision measure the considered variables were equipment and days. A robustness test showing the influence of deferent counter-ion concentration in mobile phase was also performed.

• Journal of Mechanical Science and Technology
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• v.15 no.12
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• pp.1801-1807
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• 2001

In multiphase flne the bubble size and velocity. To achieve this, one of approaches is to utilize laser phase-Doppler anemometry. However, it was found that the second order refraction has great impact on PDA sizing method when the relative refractive index of media is less than one. In this paper, the problem of second order refraction is investigated and a model of phase-size correlation to eliminate the measurement errors is introduced for bubble sizing. As a result, the model relates the assumption of single scattering mechanism in conventional phase-Doppler anemometry. The results of simulations based on this new model by using Generalized Lorenz Mie Theory (GLMT) are compared with those based on the conventional method. An optimization method for accurately sizing air-bubble in water has been suggested.