• Title/Summary/Keyword: Phase Inversion

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Compensation Characteristics or Distorted WDM Channel dependence on Variation of Fiber Dispersion (광섬유 분산 변동에 따른 왜곡된 WDM 채널의 보상 특성)

  • Lee, Seong-Real
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.29 no.7A
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    • pp.719-726
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    • 2004
  • In this paper, compensation characteristics of distorted WDM channel due to both chromatic dispersion and self phase modulation (SPM) is numerically investigated under the assumptions of non-uniformly distributed fiber dispersion, in order to inspect the application of mid-span spectral inversion (MSSI) to any exact transmission links. The MSSI is compensation method used in this approach. This method has an optical phase conjugator (OPC) placed in mid-way of total transmission length to compensate distorted WDM channels. It is confirmed that MSSI will become applicable to long-haul WDM systems by controlling input light power of transmission channels, when the averaged dispersion of both fiber sections with respect OPC was varied and distributed unequally each other. Applying MSSI to long-haul WDM system, it is possible to remove all in-line compensator, consequently it will be expected to reducing system cost.

Morphology of Membrane of Acrylic Polymers by Wet Phase Inversion Method (습식 상 역전 방법으로 제조한 아크릴계 고분자 막의 모폴로지)

  • Choi Seung-Eun;Park Han-Soo;Lee Kwang-Hee
    • Polymer(Korea)
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    • v.30 no.2
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    • pp.108-111
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    • 2006
  • In this work, the effect of the hydrophobicity of acrylic polymers on the membrane morphology was investigated. The membranes were prepared with poly(methyl methacrylate) (PMMA), poly(ethyl methacrylate) (PEMA), poly (butyl methacrylate) (PBMA), poly(isobutyl methacrylate), and their blends using the wet phase inversion method. PMMA and PEMA having a relatively less hydrophobicity formed the channel-like structure, whereas PBMA and PIBMA having more hydrophobic units formed the finger-like structure. These morphological changes were attributed to differences in the solidification process of the polymer-rich phase determine d by the polymer/solvent/nonsolvent ternary phase diagram. The membrane structures of the blends were controlled by the main component of their blends.

Vitrification Phenomena in Polysulfone/NMP/water system (폴리술폰/NMP/물 계의 고화 현상에 관한 연구)

  • Kim, Je-Young;Kanamori, Toshiyuki;Lee, Hwan-Kwang;Baik, Ki-Jun;Kim, Sung-Chul
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.53-55
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    • 1998
  • 1. INTRODUCTION : Since the knowledge of vitrification phenomena can lead to a better understanding of the mechanism of membrane formation, it is desirable to include vitrification line into the phase diagrams. While the final morphology obtained during phase inversion depends upon the kinetics as well as the thermodynamics of the phase separation, the equilibrium phase diagram and vitrification line for amorphous polymers are still a good tool for controlling the morphology and interpreting the membrane structure.

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Development of Real-time Monitoring Device ($\textrm{JELLI}^{TM}$ chip) for Phase Inversion of Emulsions Under Shear Flow (전단응력 하에서 에멀젼 상 변이의 실시간 측정을 위한 전기 유변학적 연구)

  • 백승재;이영진;남윤정;김진한;김한곤;강학희
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.1
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    • pp.59-62
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    • 2004
  • To know what happens to the internal structure of emulsions under high shear flow is very important for cosmetic product development because it is highly relevant to the physical degradation of emulsions during the application upon the skin. Here, in order to investigate the response of emulsions against the external shear forces, we designed a new device, .JELLI$^{TM}$ (Joint Electro-rheometer for Liquid-Liquid Inversion) chip, for the measurement of electrical and rheological properties of emulsions under shear flow. By using this device, we examined the real-time changes in conductivities of oil-in-water (O/W) and water-in-oil (W/O) emulsions on the artificial skin during large deformation under shear flow. In this study, O/W and W/O emulsions having various volumes were prepared. After emulsions were homogeneously applied on the artificial skin, the electrical resistance and viscosity changes were monitored under steady shear flow. In case of O/W emulsions, the resistance increased as a function of time. The resistance showed more dramatic increase as the increase of the internal oil phase. It was also found that the viscosity change was proportional to the resistance variation. This phenomenon might be caused by decreased resisting forces against the shear flow because of the breakdown of the internal phase.the internal phase.

PREPARATION OF ASYMMETRIC POLYIMIDE MEMBRANTES BY THE PHASE INVERSION PROCESS

  • Nakane, Takashi;Yanagishita, Hiroshi
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.10a
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    • pp.7-12
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    • 1993
  • Preparation of asymmetric polyimide membranes by the phase inversion process was investigated to develop ultrafiltration, reverse osmosis and pervaporation membranes for organic solutions, using a commercially available solvent-soluble polymaide. The influences of the various factors such as the composition of a cast solution, casting conditions, gelating solutions and others on membrane structure and performance were studied in detail, and it was made clear that a wide variety of asymmetric polyimide membranes ranging from UF to RO for organic solutions could be prepared from the aromatic polyimide used. It was also found that the chemical stability and separation performance of the asymmetric polyimide membranes could be improved by annealing in a liquid or a vacuum at above 200$\circ$. The membrane annealed at 300$\circ$ in a vacuum exhibited the separation factor $\alpha(H_2O/EtOH)$ of 900 with the flux of 1.0 kg/$m^2\cdot h$ at 60$\circ$C for an aqueous ethanol solution of 95 vol%.

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Selective Adsorption of a Symmetrie Theophylline Imprinted Membrane Prepare by a Wet Phase Inversion Method (습식 상 전이법으로 제조된 Theophylline 각인 대칭 막의 선택적 흡착)

  • 박중곤;오창엽;서정일
    • KSBB Journal
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    • v.17 no.2
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    • pp.207-211
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    • 2002
  • The theophylline imprinted membrane was prepared by a wet phase inversion method. Theophylline was implanted during copolymerization of acrylonitrile with acrylic acid or implanted in the dimethyl sulfoxide solution containing10 wt% copolymer, p(AN-co-AA). Rolling the glass plate, on which the copolymer solution was cast, in water removed the sponge layer and thus made the membrane symmetric. The adsorption selectivity of the membrane toward template molecule was increased with the coagulation temperature of the membrane and the initial concentration of the theophylline and caffeine mixture.

Selective Separations Using Molecularly Imprinted Membranes (분자 각인 막의 선택적 분리)

  • Lee, Jeong-Woo;Park, Joong-Kon
    • KSBB Journal
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    • v.20 no.3
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    • pp.133-141
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    • 2005
  • This review presents the preparation, transport mechanism and application of molecularly imprinted membranes (MIM). Molecular imprinting has now been established as a technique which allows the creation of tailor-made binding sites for many classes of compounds. MIM have some advantages; a high capacity due to a large surface area, faster transport of substrate molecules and faster equilibrium of binding cavities compared to molecularly imprinted particles. MIM were prepared by covalent and non-covalent chemical bonding systems, by interactions between functional monomer and template. MIM can be prepared by in-situ polymerization, wet phase inversion, dry phase inversion, and surface imprinting method. MIM can continuously separate mixtures based on facilitated or retarded diffusion of the template. MIM can change their permeability in the presence of templates. MIM have a potential to be used to separate chiral compounds and materials with similar structures. However the application of MIM by the chemical industries is still in its infancy stages.

Design and Applications of Molecularly Imprinted Polymers for Selective Separations (선택적 분리를 위한 분자 각인 고분자의 설계 및 응용)

  • 정수환;오창엽;서정일;박중곤
    • KSBB Journal
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    • v.16 no.2
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    • pp.115-122
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    • 2001
  • Molecular imprinting has now been established as a technique which allows the creation of tailor-made binding sites for many classes of compounds. MIPs were prepared by covalent and non-covalent chemical bonding systems, by interactions between functional monomer and template. The shape of MIP is divided to particle and membrane. MIP membranes can be prepared by surface imprinting, in-situ polymerization, wet phase inversion and the dry phase inversion method. MIPs have been mainly used for analytical separation and biosensor systems to separate and detect chiral compounds and materials with similar structures. However the application of MIP by the chemical industries is still in its infancy stages. This review summarizes the preparative characteristics and applications of MIP with respect to chiral separations and biosensors.

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Decaying/Expanding Distribution of RDPS in the Half Section of a Dispersion-Managed Optical Link Combined with Mid-Span Spectral Inversion

  • Lee, Seong-Real
    • Journal of information and communication convergence engineering
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    • v.17 no.4
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    • pp.227-233
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    • 2019
  • In long-haul optical communication system consisting of standard single-mode fiber spans and fiber amplifiers, such as the erbium-doped fiber amplifier, performance is deteriorated by signal distortion due to chromatic dispersion and nonlinearity of the fiber. A combination of dispersion management and optical phase conjugation is an effective technique to compensate for the distortion. In an optical link configured by this combination, a dispersion map mainly affects the compensation of the distorted optical signals. This paper proposes new dispersion maps configured by the decaying or expanding distribution of residual dispersion per span (RDPS) in a dispersion-managed link combined with a midway optical phase conjugator. The effect of the proposed dispersion maps on the compensation for distorted 24 channel × 40 Gbps wavelength-division multiplexed signals was assessed through numerical simulation. It was confirmed that all the proposed dispersion maps are most appropriate for the compensation and, furthermore, for the flexibility of link configuration than conventional links.

Dispersion-Managed Link Configured with Repetitively Shaped Dispersion Maps and Embedded with Mid-span Spectral Inversion

  • Chung, Jae-Pil;Lee, Seong-Real
    • Journal of information and communication convergence engineering
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    • v.20 no.4
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    • pp.235-241
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    • 2022
  • A dispersion map was proposed to improve the compensation effect of a distorted WDM (wavelength division multiplexed) channel in a dispersion-managed link coupled with optical phase conjugation. The dispersion map is an origin-symmetric structure around the optical phase conjugator in the middle of the transmission path. In addition, the dispersion map has a form in which a constant dispersion accumulation pattern is repeated regularly. Through simulation, we confirmed that the application of the origin-symmetric dispersion map with a repetitively shaped configuration was more effective in compensating for the distorted WDM channel than in the dispersion-managed link with a conventional dispersion map. In addition, we confirmed that the compensation effect could be increased when the cumulative dispersion distribution of the origin-symmetric distribution map had a positive value in the first half section and a negative value in the second half section. Further, we observed that as the number of repeated dispersion accumulation patterns increased, the residual dispersion per span should also be increased.