• Title/Summary/Keyword: Phase Effect

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Fracture Behaviour of PSZ Composite (부분 안정화 지르코니아의 파괴거동)

  • Kim, Hwan;Lim, Eung-Keuk;Koh, Jeong-Kyu;Hwang, Kyu-Hong
    • Journal of the Korean Ceramic Society
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    • v.21 no.3
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    • pp.239-244
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    • 1984
  • The effect of tetragonal $ZrO_2$ phase on the mechanical behavior in 7 mole% calcia partially stabilized zirconia has been studied. The $ZrO_2$ powder containg 7 mole% CaO prepared by Hot Petroleum Drying Method calcined at 80$0^{\circ}C$ for 1 hour was nearly 100% tetragonal but as the calcining temperature increased certain amount of monoclinic phase appeared. The sintered specimen at 1$700^{\circ}C$ for 5 hours was aged at 130$0^{\circ}C$ for 0, 24, 48, 72 hours. X-ray diffraction data showed that in the aged specimen monoclinic tetragonal and cubic phase coexisted. The Kc value of aged specimen for 48 hr was about 4.5MN/m3/2 much greater than unaged sample. But aged for 72 hr the KiC value was decreased. The increasing of toughness in PSZ is based on the Stress-Induced Phase Transformation that is metastable tetra-gonal $ZrO_2$ changes t stable monoclinic phase within the stress field of crack and the mechanical fracture energy absorption is occured But in this case due to certain amount of tetragonal phase transformed to monoclinic phase during cooling the microcrack effect by transformation also considered. Trerefore both Stress-Induced Phase Transformation and inclusion induced microcracking effect contrbute to the increase of fracture toughness of 7 mole% CaO-$ZrO_2$ containing monoclinic and tetragnola phase simulataneously.

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Effect of Sophora Subprostrata Fractions on Focal Ischemic Brain Damage Induced by Middle Cerebral Artery Occlusion in Rats(I) (광두근(廣豆根) 분획물이 중대뇌동맥폐쇄(中大腦動脈閉鎖)에 의한 뇌허혈손상에 미치는 효과(I) - 행동평가를 기준으로)

  • Choi, Moon-Seok;Kim, Youn-Sub
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.19 no.3
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    • pp.760-764
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    • 2005
  • This research was performed to investigate protective effect of Sophora Subprostrata fractions against focal ischemic brain damage after middle cerebral artery(MCA) occlusion. Rats were divided into six groups: MCA-occluded group(Control); each administered groups with Sophora Subprostrata total phase(Total), Sophora Subprostrata Aqueous phase (Aqueous), Sophora Subprostrata BuOH phase(BuOH), and Sophora Subprostrata Alkaloid phase(Alkaloid) after MCA-occlusion; sham-operated group(Sham). The right MCA was occluded by A poly-L-lysine coated 4-0 nylon suture thread through the internal carotid artery permanently. Sophora Subprostrata and fractions were administered orally(5mg/ml) for 7 days after MCA-occlusion. The behavior of ischemic rats were examined at 24 hours, 3, 5 and 7 days after MCA-occlusion from the views of 4 different aspects: posture & balance tests(4 subtests), reflex tests(6 subtests), muscle-tone tests(3 subtests), and foot-fault test. The results showed that 1) in muscle tone test, Sophora Subprostrata total phase only increased reduced muscle tone function from 3 to 7 days, 2) in reflex test, Sophora Subprostrata total and Aqueous phase increased fast recovery from 24 hours and 3 days, 3) in posture & balance test, Sophora Subprostrata total and Aqueous phase increased fast recovery from 24 hours, and Sophora Subprostrata BuOH and Alkaloid phase increased posture & balance function from 3 days, but 4) in motor function test, Sophora Subprostrata did not show effective recovery compared with control group. In conclusion, Sophora Subprostrata has protective effects against brain damage at the early stage of focal cerebral ischemia. Sophora Subprostrata total and Aqueous phase produced more pronounced protective effect against focal ischemic brain damage.

Effect of Polar Components on Phase Inversion Temperatures in Systems Containing Nonionic Surfactants and Nonpolar Oils (비이온성 계면활성제, 비극성 오일을 포함한 계에서의 극성 성분의 Phase Inversion Temperature에 대한 영향)

  • Lim, Jong-Choo;Mori, Fuyuhiko
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.274-284
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    • 1994
  • Phase Inversion Temperature (PIT) measurements showed that the addition of polar components such as oleyl alcohol and oleic acid to the system comprising n-dodecylpentaoxyethylene monoether ($C_{12}E_5$), nonpolar oil (n-hexadecane) and water produced large reductions in the PIT. The PIT was lowered as the additive-to-surfactant ratio in the surfactant films in the microemulsion phase was increased. Another dramatic effect of additive was the manner in which it affects the volume of the microemulsion phase at the PIT of the oil and water solubilization characteristics. Microemulsion phase volume was increased rapidly with decreasing PIT, i.e., with increasing amounts of additive in the system. Also with a decrease in PIT, the solubilization parameters of both oil and water in the microemulsion phase were strikingly increased. Even though soil removal data were not available for the conditions where our results obtained, PIT measurement seems a useful starting point for estimating conditions when middle-phase microemulsion formation and its associated high solubilization of oil can be expected.

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Effect of χ Phase on the Impact Toughness of 25Cr-7Ni-4Mo Super Duplex Stainless Steel (25Cr-7Ni-4Mo 수퍼 2상 스테인리스강의 충격인성에 미치는 χ의 영향)

  • Kang, C.Y.;Han, H.S.;Lee, S.H.;Han, T.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.25 no.2
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    • pp.74-79
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    • 2012
  • This study has been carried out to investigate the precipitation behavior of ${\chi}$ phase and effect of ${\chi}$ phase precipitation on the impact toughness of 25%Cr-7%Ni-4%Mo super duplex stainless steel. It was proved that the ${\chi}$ phase was a intermetallic compound, which represented the higher chromium and molybdenum concentration than the matrix phases, and also showed the higher molybdenum concentration than the ${\sigma}$ phase. The ${\chi}$ phase was precipitated at the interface between ferrite and austenite or inside the ferrite matrix in the early stage of aging. The number of ${\chi}$ phase precipitates increased with increasing aging time, however, after showing the maximum value, the number was decreased due to the gradual transformation of ${\chi}$ phase into ${\sigma}$-phase. Aging ferrite phase was decomposed by the $r^2$ phase and ${\sigma}$-phase. Impact toughness rapidly decreased with time in the initial stage of aging at ${\chi}$ phase start to precipitate. Thus, the impact toughness was greatly influence for the precipitation of ${\chi}$ phase.

Effect of Modulation Frequency of Power Amplifier on IMD Cancellation Performance of Predistortion Linearizer (RF 전치 왜곡된 전력 증폭기의 변조 주파수가 혼변조 개선량에 미치는 영향)

  • 최진철;조경준;김상희;김종현;이병제;김남영;이종철
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.14 no.5
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    • pp.450-457
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    • 2003
  • In this paper, we studied the effect of asymmetrical 3rd order IMD of power amplifier due to changes in modulation frequency on IMD cancellation performance. The phase extraction method for determining asymmetric rate for phase distortion of IMD is proposed and the phase difference between lower and upper 3rd order IMD is measured by this method. The phase compensation circuit to decrease the phase difference is also designed and fabricated. From the measurement results using the phase compensation circuit applied to 5 W RF power amplifier fur PCS applications, the 3rd order IMD cancellation performance can be achieved up to 2-tone spacing 1.5 MHz (phase difference within 10$^{\circ}$).

Design of Low Update Rate Phase Locked Loops with Application to Carrier Tracking in OFDM Systems

  • Raphaeli Dan;Yaniv Oded
    • Journal of Communications and Networks
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    • v.7 no.3
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    • pp.248-257
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    • 2005
  • In this paper, we develop design procedures for carrier tracking loop for orthogonal frequency division multiplexing (OFDM) systems or other systems of blocked data. In such communication systems, phase error measurements are made infrequent enough to invalidate the traditional loop design methodology which is based on analog loop design. We analyze the degradation in the OFDM schemes caused by the tracking loop and show how the performance is dependent on the rms phase error, where we distinguished between the effect of the variance in the average phase over the symbol and the effect of the phase change over the symbol. We derive the optimal tracking loop including optional delay in the loop caused by processing time. Our solution is general and includes arbitrary phase noise apd additive noise spectrums. In order to guarantee a well behaved solution, we have to check the design against margin constraints subject to uncertainties. In case the optimal loop does not meet the required margin constraints subjected to uncertainties, it is shown how to apply a method taken from control theory to find a controller. Alternatively, if we restrict the solution to first or second order loops, we give a simple loop design procedure which may be sufficient in many cases. Extensions of the method are shown for using both pilot symbols and data symbols in the OFDM receiver for phase tracking. We compare our results to other methods commonly used in OFDM receivers and we show that a large improvement can be gained.

Zero Sequence Impedance of Yg-Yg Three Phase Core Type Transformer (Yg-Yg 3상 내철형 변압기의 영상분 임피던스 분석)

  • Jo, Hyunsik;Cho, Sungwoo;Shin, Changhoon;Cha, Hanju
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.6
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    • pp.940-945
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    • 2016
  • In this paper, zero sequence equivalent circuit of Yg-Yg three phase core-type transformer is analyzed. Many problems by iron core structure of the three phase transformer due to asymmetric three phase lines, which includes line disconnection, ground fault, COS OFF, and unbalanced load are reported in the distribution system. To verify a feasibility of zero sequence impedance of Yg-Yg type three phase transformer, fault current generation in the three phase core and shell-type Yg-Yg transformer is compared by PSCAD/EMTDC when single line ground fault is occurred. As a result, shell-type transformer does not affect the flow of fault current, but core-type transformer generate an adverse effect by the zero sequence impedance. The adverse effect is explained by the zero sequence equivalent circuit of core-type transformer and Yg-Yg type three phase core-type transformer supplies a zero sequence fault current to the distribution system.

Effect of Retinoic Acid and dibutyryl cyclic AMP on G1 Phase Associated Molecules during F9 Embryonic Carcinoma Cell Differentiation (Retinoic acid와 dibutyryl cyclic AMP가 F9 embryonic carcinoma cell 분화 중 G1 Phase 관련 분자에 미치는 영향)

  • 박귀례;김건홍;한순영;이유미;장성재
    • YAKHAK HOEJI
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    • v.43 no.3
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    • pp.378-384
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    • 1999
  • Retinoic acid (RA) and dibutyryl cyclic AMP (dbcAMP) induce the differentiation of the multipotent embryonic carcinoma cell line, F9 cells, into parietal endoderm like cell. The F9 cells are highly proliferative doubling approximately 12 hourse. S Phase is predominant, lasting 10 hours and G2/M phase occupies most of the remaining cycle (2 hours) and G1 phase is nearly non-existent. In this study, we showed the effect of RA and dbcAMPon the cell cycle associated molecules (especially around G1 phase) during F9 cell differentiation. Differentiation of F9 cells was induced by the combined addition of RA ($10^{-7}M$) and dbcAMP (0.5mM), and cells were harvested daily up to 4 days. Flow cytometric analysis showed the prolongation of G1 phase around 30 hours after induction. Western blot analysis revealed that the amount of cyclin D1 and cdk2 were increased at day 4. However, histone H1 kinase activity of cdk2 was decreased. These data strongly suggest that RA and dbcAMP induce the growth arrest of F9 cells at G1 phase by decreasing the activity of cdk2, although they have increased the protein contents of cyclin D1 and cdk2. The reason for the discrepancy between the H1 kinase activity and protein contents are not clear yet.

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Folding Mechanism of WT* Ubiquitin Variant Studied by Stopped-flow Fluorescence Spectroscopy

  • Park, Soon-Ho
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2877-2883
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    • 2010
  • The folding kinetics of $WT^*$ ubiquitin variant with valine to alanine mutation at sequence position 26 (HubWA) was studied by stopped-flow fluorescence spectroscopy. While unfolding kinetics showed a single exponential phase, refolding reaction showed three exponential phases. The semi-logarithmic plot of urea concentration vs. rate constant for the first phase showed v-shape pattern while the second phase showed v-shape with roll-over effect at low urea concentration. The rate constant and the amplitude of the third phase were constant throughout the urea concentrations, suggesting that this phase represents parallel process due to the configurational isomerization. Interestingly, the first and second phases appeared to be coupled since the amplitude of the second phase increased at the expense of the amplitude of the first phase in increasing urea concentrations. This observation together with the roll-over effect in the second folding phase indicates the presence of intermediate state during the folding reaction of HubWA. Quantitative analysis of Hub-WA folding kinetics indicated that this intermediate state is on the folding pathway. Folding kinetics measurement of a mutant HubWA with hydrophobic core residue mutation, Val to Ala at residue position 17, suggested that the intermediate state has significant amount of native interactions, supporting the interpretation that the intermediate is on the folding pathway. It is considered that HubWA is a useful model protein to study the contribution of residues to protein folding process using folding kinetics measurements in conjunction with protein engineering.

The Effect of Spray Dried Plasma, Lactose and Soybean Protein Sources on the Performance of Weaned Pigs

  • Liu, H.;Kim, I.B.;Touchette, K.J.;Newcomb, M.D.;Allee, G.L.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.9
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    • pp.1290-1298
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    • 2001
  • A total of 371 weaned pigs were used in three experiments to evaluate the effects of spray dried plasma (SDP), soybean protein sources, and lactose on growth performance. In Exp. 1, 128 pigs (5.99 kg, $18{\pm}2d$) were used to evaluate the effect of SDP (0 vs 7%), lactose (0 vs 30%), and two soybean protein sources [soybean meal (SBM) and extruded soybean protein concentrate (ESPC)] in phase I (d 0 to 14) diets on pig performance in a $2{\times}2{\times}2$ factorial arrangement. Spray-dried plasma increased phase I ADG (p<0.01) and ADFI (p<0.05) in the SBM diets, but not in the ESPC diets. Lactose improved ADG and gain/feed ratio (G/F) in phase I (p<0.01). In Exp. 2, 144 pigs (5.50 kg, $17{\pm}3d$) were used to evaluate the effect of SDP (0 vs. 3.5%) and three soybean protein sources [SBM, ESPC, and soybean protein concentrate (SPC)] in phase I diets, and the effects of two different phase II (d 14 to 28) diets (simple vs complex) in a $2{\times}3{\times}2$ factorial arrangement of treatments. In phase I, SDP increased ADG (p<0.01) and improved G/F (p<0.05). Pigs fed SBM had the highest ADG and ADFI, with a G/F similar to the pigs fed ESPC. In phase II, pigs fed the complex diet had improved ADG (p<0.01), ADFI (p<0.05), and G/F (p<0.05) compared to the simple diet. In Exp. 3, 99 weaned pigs (5.77 kg, $17{\pm}3$d) were used to evaluate the effect of SBM, ESPC, and ESPC with SDP in the phase I diets. Pigs fed SBM with no blood product in the diet had the lowest ADG (p<0.01), ADFI (p<0.01), and G/F (p<0.05) in the first week of phase I. There were no differences in soybean protein sources fed in phase I diets on overall pig performance. These experiments are indicated that SDP and lactose improve the phase I performance. Soybean meal can be used as the major protein source in phase I diets with SDP.