• Title/Summary/Keyword: Phase Diagram

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Evaluation for Al/Cu bonding by liquefaction after solid phase diffusion in the air

  • Kawakami, Hiroshi;Suzuki, Jippei;Fujiwara, Masanori;Nakajima, Junya;Kimura, Keiko
    • Proceedings of the KWS Conference
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    • 2005.06a
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    • pp.393-395
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    • 2005
  • The bonding for Aluminum and Copper in the air is investigated in this study. This bonding method does not include the special process of removing aluminum oxide films. In case of this bending, each metal Is heated at bonding temperature where is above eutectic temperature of Al-Cu system and below melting point of Aluminum. The liquefaction around the bonding surface occurs after the diffusion at solid state of each metal. This phenomenon is predicted by the temperature range above eutectic temperature of Al-Cu equilibrium phase diagram.

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열유도 상분리를 이용한 폴리프로필렌 다공막의 제조

  • 김성수;황정림;김재진;김은영
    • Proceedings of the Membrane Society of Korea Conference
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    • 1991.10a
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    • pp.27-28
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    • 1991
  • 열유도 상분리법 (Thermally-Induced Phase Separation, TIPS)에 의하여 미세 다공성 중공사막을 제조하였다. 막소재로는 폴리프로필렌(PP)을, 회석제로는 천연산 대두유(soybean oil), 올레인산(oleic acid), 리놀레인산(linoleic acid) 등을 사용하였다. 각 system 별로 DSC를 사용하여 열분석을 하여 분당 10$\circ$C 의 냉각속도에서 phase diagram을 얻었다. 그림 1에서 보인 바와 같이 각 system 모두 monotectic composition 이하에서 수평한 결정화 곡선을 나타내고 있으며, 이는 액체-액체 상분리 system의 특징이다. Monotectic composition은 PP/대두유 system의 경우 PP중량비로 65%, PP/올레인산 system의 경우 60%, PP/리놀레 인산 system의 경우 75%였으며, polymer가 PP로 고정된 상태에서 회석제의 극성(polarity)이 증가함에 따라 monotectic PP composition이 증가하는 경향을 나타내고 있다.

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High-Strength Mg-PSZ of Fine Grains Containing TiC Particles

  • Joon Hyuk Jang;Jaehyung Lee
    • The Korean Journal of Ceramics
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    • v.1 no.4
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    • pp.214-218
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    • 1995
  • Partially stabilized zironia with magnesia (Mg-PSZ) is known as one of the toughest monolithic ceramics. However, the very large grain sizes obtained after sintering at a high solution-heat treatment temperature in the cubic region of the phase diagram limit the strength of this material rather modest. In this study fine-grained Mg-PSZ materials were fabricated by adding TiC particles as a dispersed phase. Samples were hot-pressed at $1750^{\circ}C$ and then annealed at $1420^{\circ}C$ for various times. Grain growth was retarded severely by the TiC particles resulting in grain sizes smaller by more than one order of magnitude than those of PSZ without TiC. The fine-grained microstructure lead to doubly-increased fracture strength while maintaining the same level of high fracture toughness as that of conventional Mg-PSZ without TiC particles.

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Estimation of Flash Points of Flammable Liquid Mixtures with Non-flammable Liquids (난연성액체에 따른 가연성 액체혼합물의 인화점 추산)

  • 이수경;엄종호;하동명;이성민
    • Journal of the Korean Society of Safety
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    • v.7 no.3
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    • pp.53-59
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    • 1992
  • A general theory is developed which enables closed-cup flash points of mixtures of flammable and non-flammable liquid to be estimated from a knowledge of a certain properties of flammability diagram by thermodynamic method. The estimated equations is shown the effect of both the flame inhibiting properties of the vapor of the non-flammable component and the relative volatility of that component. The vapor phase flame inhibition effect results in a even greater elevation of flash points than the rotative volatility of that component. Especially in cases of similar vapor phase flame inhibition of the non-flammable component, the rotative volatility is affected greater elevation of flash points(extinguishing effect).

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MICROSTRUCTURE AND ELECTROCHEMICAL CHARACTERISTICS OF ELECTRODEPOSITED Zn-Ni ALLOY COATINGS

  • Short, N.R.;Hui, Wen-Hua;Dennis, J.K.
    • Journal of Surface Science and Engineering
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    • v.32 no.3
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    • pp.281-288
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    • 1999
  • Electrodeposited Zn-Ni alloy coatings are of particular interest for improving the corrosion resistance of steel in a number of enviornments. Of particular interest is the relationship between composition, structure and corrosion rate. This paper firstly reviews the literature regarding composition-structure relationships of Zn-Ni electrodeposits and compares them with the equilibrium phase diagram. Secondly, research was carried out on a wide range of coatings which were produced in the laboratory and their structure and corrosion rates determined. It was found that unambiguous identification of phases from XRD data can be difficult. Maximum corrosion resistance of deposits is obtained at 12-13% Ni, with a $\gamma$ phase structure and predomination of (600) and (411) reflections. Compatibility is important with regard to chromate conversion coatings.

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New Unsupervised Classification Technique for Polarimetric SAR Images

  • Oh, Yi-Sok;Lee, Kyung-Yup;Jang, Ge-Ba
    • Korean Journal of Remote Sensing
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    • v.25 no.3
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    • pp.255-261
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    • 2009
  • A new polarimetric SAR image classification technique based on the degree of polarization (DoP) and the co-polarized phase-difference (CPD) is presented in this paper. Since the DoP and the CPD of a scattered wave provide information on the randomness of the scattering and the type of scattering mechanisms, at first, the statistics of the DoP and CPD are examined with measured polarimetric SAR image data. Then, a DoP-CPD diagram with appropriate boundaries between six different classes is developed based on the SAR image. The classification technique is verified using the JPL AirSAR and ALOS PALSAR polarimetric data. The technique may have capability to classify an SAR image into six major classes; a bare surface, a village, a crown-layer short vegetation canopy, a trunk-layer short vegetation canopy, a crown-layer forest, and a trunk-dominated forest.

Coal pyrolysis behaviors at supercritical CO2 conditions

  • Hakduck Kim;Jeongmin Choi;Heechang Lim;Juhun Song
    • Advances in Energy Research
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    • v.8 no.4
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    • pp.265-273
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    • 2022
  • In this study, a product gas yield and carbon conversion were measured during the coal pyrolysis. The pyrolysis process occurred under two different atmospheres such as subcritical (45 bar, 10℃) and supercritical CO2 condition (80 bar, 35℃). Under the same pressure (80 bar), the atmosphere temperature increased from 35℃ to 45℃ to further examine temperature effect on the pyrolysis at supercritical CO2 condition. For all three cases, a power input supplied to heating wire placed below coal bed was controlled to make coal bed temperature constant. The phase change of CO2 atmosphere and subsequent pyrolysis behaviors of coal bed were observed using high-resolution camcorder. The pressure and temperature in the reactor were controlled by a CO2 pump and heater. Then, the coal bed was heated by wire heater to proceed the pyrolysis under supercritical CO2 condition.

Phase Relationships and Magnetic Properties of HDDR-treated $Sm_3$(Fe,Co,V)$_{29}$ Alloy

  • Kwon, Hae-Woong
    • Journal of Magnetics
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    • v.6 no.4
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    • pp.122-125
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    • 2001
  • Phase relationships of the HDDR (hydrogenation, disproportionation, desorption and recombination)-treated Sm$_3$(Fe,M)$_{29}$-type alloy with chemical composition of Sm$_{9}$Fe$_{65}$ $Co_{20}$V$_{6}$ were studied by X-ray diffraction (XRD) and by thermomagnetic analysis (TMA). The alloy was disproportionated into a mixture of $SmH_{x}$ and $\alpha$-Fe at high temperature under hydrogen gas. The disproportionated material was recombined into a mixture of Sm-(Fe,M) (M = Co and/or V) and $\alpha$-Fe phases. The structure of the Sm-(Fe,M) phase was dependent upon the recombination conditions, and a detailed phase diagram showing the phase relationships in the HDDR-treated alloy has been established. The Sm-(Fe,M) phase in material recombined above $900^{\circ}C$ had the $Sm_2Fe_{17}$-type structure, and it exhibited the $SmFe_{7}$-type structure when recombined at temperatures ranging from $700^{\circ}C$ to $850^{\circ}C$. Recombination below $650^{\circ}C$ led to the $SmFe_3$-type structure of the Sm-(Fe,M) phase. Curie temperatures of the Sm-(Fe,M) phases in the recombined material were significantly higher than those of the corresponding stoichiometric phases. It was suggested that the chemical composition of the Sm-(Fe,M) phases may be significantly different from that of the corresponding stoichiometric phases. All the HDDR-treated $Sm_{9}Fe_{65}Co_{20}V_{6}$ materials showed the soft magnetic features regardless of the phase constitution.n.

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Investigations of the Phase Behavior of N-dodecanocyl-N-methyl amido polyol carboxyl alkyl ether/N-dodecanocyl-N-alkyl Glucamine/Water System (N-도데카노실-N-메틸 아미도 폴리올 카르복시 알킬 에테르/(N-도데카노실-N-알킬 글루카민)/물계에서의 상거동 관찰)

  • Kang, Yun-Seog;Nam, Ki-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.3
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    • pp.23-28
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    • 1997
  • The phase diagram for the surfactant mixture system of N-dodecanocyl-N-methyl amido polyolcarboxyl alkyl ether(DGC)/N-dodecanocyl-N-alkyl glucamine(DG)/water was studied usingpolarized microscopy, differential scanning calorimetry(DSC) and rheological measurements respectively. Using polarized microscopy, the textures of liquid crystal phases obtained at various surfactantconcentrations were investigated as a function of surfactant concentration and temperature, and phasetransitions between anisotropic liquid crystal phases and isotropic liquid phase were examined usingDSC measurements. Viscoelastic properties of surfactant solutions determined between hexagonal andlamellar liquid crystal phase by rheological measurements were approximately consistent with the resultsobtained by polarized microscopy and DSC. In the study for the phase of DGC/DG(5:5 mol ratio)/water system. It could be found that the hexagonal liquid crystal phase appeared at 25${\sim}$60wt% ofsurfactant, the cubic liquid crystal phase at 50${\sim}$65wt% and the lamellar crystal phase at above 70wt%.

Component-based Convergence Development Method of Software using SETL (SETL을 이용한 소프트웨어의 컴포넌트 기반 융복합 개발 방법)

  • Yoo, Hong-Jun;Yang, Hae-Sool
    • Journal of Digital Convergence
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    • v.13 no.6
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    • pp.165-175
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    • 2015
  • Methods to design programs which implement IT systems have been developed in various forms from flowchart to activity diagram of UML. However, program design tools and methods developed so far have not been efficient comparing to program coding tools and methods. In addition, Program design methods and tools developed until now have been difficult to support the bidirectional conversion between program design and coding, and the improvement of development productivity and maintainability. Therefore, in this study, we propose Convergence Development Method to enable working with wide bandwidth through fusing the program design and coding phase by using SOC and supporting tool named SETL which automatizes the convergence of design and coding. Thus, by using SETL, it is expected that the efficiency gap between the program design and coding phase is reduced, and development productivity and maintainability is increased. key words.