• Title/Summary/Keyword: Petroleum product

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Synthesis of Methyl Alcohol and Alternative Gases for Petroleum by Thermochemical Gasification of Waste Lignocellulosic Materials (II) - Thermochemical Conversion of Sawdust, Ricestraw and Ricehusk Using Alkali Salts as Catalyst by Pressurized Reactor (목질(木質) 폐재(廢材)의 열(熱)-화학적(化學的) 방법에 의한 메틸알콜과 대체(代替)에너지 가스의 합성(合成) (II) - 가압하(加壓下)에 알칼리염을 촉매로 사용한 톱밥, 볏짚 그리고 왕겨의 열화학적(熱化學的) 분해(分解) -)

  • Lee, Byung-Guen
    • Journal of the Korean Wood Science and Technology
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    • v.14 no.3
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    • pp.43-46
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    • 1986
  • A stainless steel autoclave reactor, which is the property of Pacific Northwest Laboratories(PNL) and located in PNL, was acted for pyrolysis and gasification of sawdust, ricestraw, and ricehusk. The initial reaction temperature of this reactor was 300$^{\circ}C$, and up to 500$^{\circ}C$ to complete pyrolysis and gasification reaction. The maximum exerted pressure on this reactor was 800 psig. In order to examine the effect of catalyst on reaction temperature, $K_2CO_3$, and nickel/alkali carbonate catalyst mixture were also used. The experimental results obtained with this reactor indicated that good yields of methane-rich gas(exceeding 40% methane) can be produced. The product gas mixtures were also identified to be CO. $CO_2$, $C_2H_4$, and $CH_3CHO$ etc. by Gas Chromatography and Mass Spectrometer.

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A Study on the Modified Safety Valve for Vessels of Liquefied Petroleum Gas (LP가스 용기용 안전 밸브 개발에 관한 연구)

  • Rhim Jong-Kuk
    • Journal of the Korean Institute of Gas
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    • v.9 no.2 s.27
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    • pp.38-42
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    • 2005
  • This study introduced concept of safety valve about development of valve for LP gas cylinders. LP gas cylinders are used more because of convenience of use, but a lot of accidents are occurred. Specially, it is used by purpose to injure glossary or others and is sometimes used to a demonstration tool. Korean government was making mandatory to use overuse cutoff valve to reduce accident, but it is real condition that product development is not following. In this study, introduce concept of safety valve that introduce more original safety concept than overuse cutoff valve. This was developed by method that insert module to present use valve and flowing of gas is controlled in state that hose or regulator un-connects to valve. Also, flowing of gas cut-off immediately if hose is cut or occurrence of overuse is produced even if is using normally.

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National Certification Marks and Standardization Trends for Biodegradable, Oxo-biodegradable and Bio based Plastics (생분해, 산화생분해, 바이오 베이스 플라스틱의 세계 주요 국가 인증마크 및 규격기준 동향)

  • You, Young-Sun;Oh, You-Sung;Kim, Un-Su;Choi, Sung-Wook
    • Clean Technology
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    • v.21 no.1
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    • pp.1-11
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    • 2015
  • To address recent environmental pollution, bio plastics such as biodegradable, oxo-biodegradable, and bio-based plastics have attracted much attention in a variety of industrial fields. The critical disadvantages of the weak mechanical strength and expensive product cost were gradually solved by extensive researches. As an alternative for petroleum-based plastics, the bio plastics have been applied to various items. To popularize the bio plastics, certification marks and technical standardization have been developed in the world. This article provide an over view on the recent trend on the commercialization and national certification marks.

Physical Properties of Matrix According to Replacement Ratio using Polysilicon Sludge Based on Light Burned Magnesia (경소마그네시아 기반 폴리실리콘슬러지 치환율에 따른 경화체의 물리적 특성)

  • Kim, Yong-Gu;Kim., Dae-Yeon;Shin, Jin-Hyun;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.143-144
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    • 2019
  • Recently, environmental pollution related to global warming is on the rise. Meanwhile, renewable energy is a representative example of many efforts to develop eco-friendly energy to solve the depletion of natural resources and the depletion of petroleum resources in conjunction with global warming. Among them, photovoltaic power generation is increasing the subsidies for the government to increase the production of photovoltaic electricity of the general public, showing a high growth rate. However, polysilicon, which is a raw material of the photovoltaic panel, generates waste called polysilicon sludge in the manufacturing process. In order to produce 1 ton of polysilicon, about 2 tons of waste polysilicon sludge is generated. In 2012, polysilicon sludge was generated at 78,000 tons, with an average of about 220 tons per day. The sludge generated due to insufficient treatment of polysilicon sludge is currently solidified and is processed by landfilling. Therefore, in this study, polysilicone sludge is used as the concept of admixture, and the physical properties of the matrix according to the polysilicon sludge replacement ratio based on light burned magnesia is determined.

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Ignition and flame propagation in hydrogen-air layers from a geological nuclear waste repository: A preliminary study

  • Ryu, Je Ir;Woo, Seung Min;Lee, Manseok;Yoon, Hyun Chul
    • Nuclear Engineering and Technology
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    • v.54 no.1
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    • pp.130-137
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    • 2022
  • In the geological repository of radioactive nuclear waste, anaerobic corrosion can generate hydrogen, and may conservatively lead to the production of hydrogen-air layer. The accumulated hydrogen may cause a hazardous flame propagation resulting from any potential ignition sources. This study numerically investigates the processes of ignition and flame propagation in the layered mixture. Simple geometry was chosen to represent the geological repository, and reactive flow simulations were performed with different ignition power, energy, and locations. The simulation results revealed the effects of power and energy of ignition source, which were also analyzed theoretically. The mechanism of layered flame propagation was suggested, which includes three stages: propagation into the hydrogen area, downward propagation due to the product gas, and horizontal propagation along the top wall. To investigate the effect of the ignition source location, simulations with eight different positions were performed, and the boundary of hazardous ignition area was identified. The simulation results were also explained through scaling analysis. This study evaluates the potential risk of the accumulated hydrogen in geological repository, and illustrates the layered flame propagation in related ignition scenarios.

An analysis on the International Construction Market and the Business Performance of Top Contractors after the Global Financial Crisis

  • Sung, Yookyung;Choi, Seok-In
    • International conference on construction engineering and project management
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    • 2015.10a
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    • pp.736-737
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    • 2015
  • In these days, international construction market including construction companies has much grown due to globalization and economic boom in the mid 2000's. The size of international construction market, measured with overseas revenue of 225 construction firms, has expanded 2.7 times from 2003 to 2008 according to the ENR. However, after the global financial crisis of 2008 it has faced condition of low growth. In this research, major changes of international construction market and top contractors have been studied. In this study, changes of international construction market have been analyzed in the aspect of region and product including general buildings, transportation, petroleum, etc. Then, in order to find the changes of top contractors which obtained good accomplishment, business performance of companies have been examined by the compound annual growth rate, profit margin and international revenue by comparing the data before 2008 and after. The purpose of the study is to understand major changes of international construction market. Also, strategy changes of top contractors against market stagnation, profit depreciation, high competition have been inferred through the study. The result of the study would contribute to analyzing the strategies of construction companies in international market.

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토양 및 지하수 Investigation 과 Remediation에 대한 현장적용

  • Wallner, Heinz
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.44-63
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    • 2000
  • Situated close to Heathrow Airport, and adjacent to the M4 and M25 Motorways, the site at Axis Park is considered a prime location for business in the UK. In consequnce two of the UK's major property development companies, MEPC and Redrew Homes sought the expertise of Intergeo to remediate the contaminated former industrial site prior to its development. Industrial use of the twenty-six hectare site, started in 1936, when Hawker Aircraft commence aircraft manufacture. In 1963 the Firestone Tyre and Rubber Company purchased part of the site. Ford commenced vehicle production at the site in the mid-1970's and production was continued by Iveco Ford from 1986 to the plant's decommissioning in 1997. Geologically the site is underlain by sand and gravel, deposited in prehistory by the River Thames, with London Clay at around 6m depth. The level of groundwater fluctuates seasonally at around 2.5m depth, moving slowly southwest towards local streams and watercourses. A phased investigation of the site was undertaken, which culminated in the extensive site investigation undertaken by Intergeo in 1998. In total 50 boreholes, 90 probeholes and 60 trial pits were used to investigate the site and around 4000 solid and 1300 liquid samples were tested in the laboratory for chemical substances. The investigations identified total petroleum hydrocarbons in the soil up to 25, 000mg/kg. Diesel oil, with some lubricating oil were the main components. Volatile organic compounds were identified in the groundwater in excess of 10mg/l. Specific substances included trichloromethane, trichloromethane and tetrachloroethene. Both the oil and volatile compounds were widely spread across the site, The specific substances identified could be traced back to industrial processes used at one or other dates in the sites history Slightly elevated levels of toxic metals and polycyclic aromatic hydrocarbons were also identified locally. Prior to remediation of the site and throughout its progress, extensive liaison with the regulatory authorities and the client's professional representatives was required. In addition to meetings, numerous technical documents detailing methods and health and safety issues were required in order to comply with UK environmental and safety legislation. After initially considering a range of options to undertake remediation, the following three main techniques were selected: ex-situ bioremediation of hydrocarbon contaminated soils, skimming of free floating hydrocarbon product from the water surface at wells and excavations and air stripping of volatile organic compounds from groundwater recovered from wells. The achievements were as follows: 1) 350, 000m3 of soil was excavated and 112, 000m3 of sand and gravel was processed to remove gravel and cobble sized particles; 2) 53, 000m3 of hydrocarbon contaminated soil was bioremediated in windrows ; 3) 7000m3 of groundwater was processed by skimming to remove free floating Product; 4) 196, 000m3 of groundwater was Processed by air stripping to remove volatile organic compounds. Only 1000m3 of soil left the site for disposal in licensed waste facilities Given the costs of disposal in the UK, the selected methods represented a considerable cost saving to the Clients. All other soil was engineered back into the ground to a precise geotechnical specification. The following objective levels were achieved across the site 1) By a Risk Based Corrective Action (RBCA) methodology it was demonstrated that soil with less that 1000mg/kg total petroleum hydrocarbons did not pose a hazard to health or water resources and therefore, could remain insitu; 2) Soils destined for the residential areas of the site were remediated to 250mg/kg total petroleum hydrocarbons; in the industrial areas 500mg/kg was proven acceptable. 3) Hydrocarbons in groundwater were remediated to below the Dutch Intervegtion Level of 0.6mg/1; 4) Volatile organic compounds/BTEX group substances were reduced to below the Dutch Intervention Levels; 5) Polycyclic aromatic hydrocarbons and metals were below Inter-departmental Committee for the Redevelopment of Contaminated Land guideline levels for intended enduse. In order to verify the qualify of the work 1500 chemical test results were submitted for the purpose of validation. Quality assurance checks were undertaken by independent consultants and at an independent laboratory selected by Intergeo. Long term monitoring of water quality was undertaken for a period of one year after remediation work had been completed. Both the regulatory authorities and Clients representatives endorsed the quality of remediation now completed at the site. Subsequent to completion of the remediation work Redrew Homes constructed a prestige housing development. The properties at "Belvedere Place" retailed at premium prices. On the MEPC site the Post Office, amongst others, has located a major sorting office for the London area. Exceptionally high standards of remediation, control and documentation were a requirement for the work undertaken here.aken here.

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Antioxidant Activity and Inhibitory Effect on Oxidative DNA Damage of Ethyl Acetate Fractions Extracted from Cone of Red Pine (Pinus densiflora) (솔방울 에틸아세테이트 분획물의 항산화 및 산화적 DNA 손상 억제 활성)

  • Jang, Tae Won;Nam, Su Hwan;Park, Jae Ho
    • Korean Journal of Plant Resources
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    • v.29 no.2
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    • pp.163-170
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    • 2016
  • Antioxidant activity and inhibitory effect on oxidative DNA damage of ethyl acetate fractions extracted from Cone of Red Pine (Pinus densiflora) were investigated to find utilization of Cone, by-product of Red Pine, thrown out after berry shatter, as a new natural plant resource. Cone from P. densiflora was extracted with methanol (MeOH) and separated to petroleum ether, ethyl acetate and water fraction. Among them, ethyl acetate fraction was used. The antioxidant activity was conducted by the 1,1-diphenyl-2-picryl hydrazyl (DPPH) radical, 2, 2'-Azino-bis (3-ethylbenzothiazoline-6 sulfonic acid) diammonium salt (ABTS) radical scavenging assay, Fe2+ chelating assay and reducing power assay. The inhibitory effect on oxidative DNA damage was determined by DNA cleavage assay using φX-174 RF I plasmid. The results of DPPH and ABTS radical scavenging activity at 200 ㎍/㎖ of extracts were 86.50% and 95.80% respectively, which were similar figures compared with L-ascorbic acid as control. Fe2+ chelating activity was 77.96% and reducing power was 0.77 at 200 ㎍/㎖. Total phenolic component was 27.29±0.3 ㎎/g and Vitamin C content was 1.84±0.1 ㎎/g. Also ethyl acetate fraction from Cone has inhibitory effect, using φX-174 RF I plasmid on DNA cleavage assay. In conclusion, Cone, by-product of P. densiflora, showed high antioxidant activity and inhibitory effect on oxidative DNA damage. Therefore this study suggests Cone, useless by-product, can be developed as a new natural plant resource with lots of utilization such as an effective antioxidant, natural medicine, food, cosmetics and so on.

A Study about Water Footprint Evaluation of Industrial Sectors (국내 산업들의 물 발자국 산정에 관한 연구)

  • Kim, Junbeum;Kang, Hun;Park, Kihak
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.6
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    • pp.400-406
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    • 2013
  • Water footprint means the direct and indirect water resource amount used for the life cycle of different goods, services and industries. In this study, the direct and indirect water resource consumption in industrial sectors were calculated by using water footprint evaluation method. As a result, agriculture and marine product industry takes part of 93% of whole water resource amount, showing the greatest amount of basic unit of water coefficient (637 $m^3/won$) following by petroleum and cool products industry of about 13 $m^3/won$. In the agriculture and marine product industry, the direct water consumption was only 25 billion $m^3$ compared to the indirect water, which is 130 billion $m^3$. The next highest industry was chemical product industry, which consists of 2 billion $m^3$ of the direct water and 4.5 billion $m^3$ of the indirect water consumption. In case of industries which have high direct water, it would be more effective to reduce amount of water related to the industry than to reduce water in actual process. This water footprint of each industry and evaluation method will be useful tool and method for development of national water management policy and regulation.

Decomposition of Daesan Port's Exports: Neighbor Spatial Effect (대산항 수출변동의 요인별 분해: 근린공간효과를 중심으로)

  • Mo, Soo-Won;Park, Jeong-Hwan;Lee, Kwang-Bae
    • Journal of Korea Port Economic Association
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    • v.34 no.4
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    • pp.1-16
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    • 2018
  • The standard shift-share analysis decomposes a region's sectoral growth into three components: national, industry-mix, and regional-shift effects. Nevertheless, the three components of the traditional shift-share are not related to the behavior of the regional economies that are neighbors of the region under analysis. We incorporate a spatial structure within this basic formulation, and consider spatial interaction in the decomposition analysis. Daesan Port's export grew steadily at an annualized average rate of 4.0% during 2011-2017, and its rank, in terms of export performance, was 13 in 2010; this rose to 6 in 2016, then declined slightly to 7 in 2017 before reaching 6 as of June, 2018. However, not all ports have a similar growth path. The Onsan Port's share declined from 27.4% in 2011 to 21.0% to 2017, whereas the share of petroleum product exports of Daesan Port increased rapidly, from approximately 8.5% in 2011 to 16.0% in 2017. The standard shift-share analysis shows that petroleum products and basic petrochemicals have a positive regional in dustry-mix effect, but petrochemistry materials and synthetic resins have a negative sign, indicating that the former's exports grow faster than national export, while the increase of the latter's export is slower than national one. The spatial shift-share model indicates that for both petroleum products and basic petrochemicals, Incheon and Ulsan Ports have a positive value for the neighbor-nation regional shift effect and a positive value for the region-neighbor regional shift effect. This paper also shows that Yeosu Port for petroleum products; Ulsan Port for basic petrochemicals; Ulsan, Onsan and Yeosu Ports for petrochemistry materials; and Ulsan, Busan, and Incheon Ports for synthetic resins have a positive value for the neighbor-nation regional shift effect but a negative value for the region-neighbor regional shift effect.