• Journal of Korean Society of Environmental Engineers
• /
• v.28 no.7
• /
• pp.721-730
• /
• 2006

The effects of compost amendment on the removal of petroleum hydrocarbons and the activities of microorganisms in soil ecosystem have been studied in bioremediation of diesel contaminated soil. The relation between biological activities and removal of petroleun hydrocarbon was determined by ATP(Adenisine Triphosphate), n-alkanes and TPH concentration analysis. After 80 days of bioremediation, the removal of TPH in soil amended with compost increased more than 10% compared with control soil which was tilled in the same condition without compost addition. The biodegradations of n-alkanes having 12 to 20 moles of carbon were distinctive. As the soil was contaminated with more diesel, the ATP has decreased rapidly. When the TPH amounted to 80,000 mg diesel/kg, the ATP decreased to 4 ng/g from initial concentration of 65 ng/g. While the ATP in the compost amended soil increased to 112 ng/g after tilling for 6 days, the ATP in the control increased to merely 36 ng/g after tilling for 14 days. Also while the control soil showed a lag time in ATP increase, the compost amended soil did not show that but showed a rapid ATP increase within a short time. The patterns of changes in ATP concentration were similar to those in daily removals of TPH with time difference of about 7 days.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.22 no.5
• /
• pp.116-125
• /
• 2014

Pyrolysis oil (PO), derived from biomass through fast pyrolysis process have the potential to displace significant amounts of petroleum fuels. The PO derived from wood has been regarded as an alternative fuel to be used in diesel engines. However, the use of PO in a diesel engine is very limited due to its poor properties like low energy density, low cetane number, high acidity and high viscosity of PO. Therefore, one of the easiest way to adopt PO to diesel engine without modifications is blended with other fuels that have high centane number. However, PO that has high amount of polar chemicals is immiscible with non polar hydrocarbons of diesel or biodiesel. Thus, to stabilize a homogeneous phase of diesel/biodiesel-PO blends, a proper surfactant should be used. Nevertheless, PO which was produced from different biomass type have varied characteristics and this complicates the selection of a suitable additive for a specific PO-diesel emulsion. In this regard, a more simple approach such as the use of a co-solvent like ethanol or butanol to induce a more stable phase of the PO-diesel mixture could be a promising alternative. In this study, a diesel engine operated with diesel/biodiesel-PO-butanol blends was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine were examined under the engine loads of IMEP 0.2 ~ 0.8MPa.

• KSBB Journal
• /
• v.16 no.6
• /
• pp.632-637
• /
• 2001

The cells obtained from diesel contaminated site were tested for diesel degradation by culturing them on the culture medium that contained diesel as the only carbon source. Two strains that grew well in the culture media were separated: one formed white colony and another strain formed yellow colony. When they were cultured together, much higher diesel degradation was obtained compares to that of individual cell culture. Mixed culture of white and yellow colony forming strains grew well with 1%(v/v) diesel and the addition of growth nutrients increased the diesel degradation. Additional nitrogen source was efficient for higher diesel degradation (over 90%) when it was compared with that without nitrogen source. When mixed culture of white and yellow colony forming cells were applied to the soil column system contaminated by diesel, 30 mL/min of air flow rate was found to be sufficient to degrade diesel oil. The diesel degradation did not increase noticeably at higher flow rate. The addition of nitrogen source resulted in the increase in diesel degradability.

• Journal of the Korean Society of Combustion
• /
• v.4 no.2
• /
• pp.43-50
• /
• 1999

Liquefied petroleum gas (LPG) has been used as motor fuel due to its low emissions and low cost. The fuel feeding system has been improved with stringent requirement for exhaust emissions. LPG carburetion system was first introduced, then the system has been changed to a precisely controlled gas injection system, but this gas feeding system has a limitation on improving power output. In order to improve an engine performance, a multi-point port injection system was introduced recently, and a liquid direct injection system into a cylinder was suggested as a next generation system to maximize a fuel economy as well as a power. This study addresses the analysis of the LPG spray from diesel injectors. The spray images are visualized and compared with diesel sprays in a wide injection pressure range. The photographs show much wider dispersion of LPG sprays.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.14 no.3
• /
• pp.150-156
• /
• 2006

Recently, the tightening of available crude oil supplies has resulted in the development of intense consciousness for saving fuels. At the same time, some research programs have been launched to secure substitute energy sources for petroleum-derived fuels, and to reduce unhealthy products, such as CO, HC, NOx and smoke. To keep up with these trends in society, the regulation affecting diesel smoke may be greatly strengthened in a short time. In not too distant future, LPG and LNG are the most hopeful substitute fuels for automobile and truck uses. This paper discusses how to use such gaseous fuels in a diesel engine, and how to find out introducing these fuels affect the engine performance.

• 한국지구물리탐사학회:학술대회논문집
• /
• 2003.11a
• /
• pp.669-675
• /
• 2003

This paper examines structural breaks and asymmetries of prices of four domestic petroleum products, i.e., gasoline, kerosene, diesel, and bunker-C, following the changes in the pricing policies pertaining to petroleum products in Korea from the government-controlled pricing system to the market pricing system. We use the monthly wholesale market price data for the sample period between July 1988 and December 2001. Using the four methods: the Chow test, the CUSUM/CUSUMQ tests, the Bayesian approach and the Dufour test, the structural behaviors of the petroleum product prices are examined. We found that structural change occurred in all petroleum products, with the exception of Kerosene, at the point of pricing policy change from government-controlled to the spot-price related pricing system. We, also conducted asymmetric analysis using the Borenstein, Cameron, and Gilbert (1997)'s model and found evidences of price asymmetry for all four product types, but in different pattern for each product.

• Journal of the Korean Applied Science and Technology
• /
• v.30 no.1
• /
• pp.35-48
• /
• 2013

Biodiesel is an alternative diesel fuel which can be obtained from the transesterification of vegetable oils, animal fats and waste cooking oil. The objective of this study is to evaluate the properties of biodiesel obtained from different feedstocks (soybean, waste cooking, rapeseed, cottonseed and palm oils). The biodiesel derived from different feedstocks was analyzed for FAME (fatty acid methyl esther) content, kinematic viscosity, flash point, CFPP (cold filter plugging point) and glycerin content. The quality of biodiesel was tested according to the Korean and European standard (EN14214, requirements and test method for biodiesel fuel). The biodiesels derived from soybean, waste cooking, rapeseed and cottonseed oils contain high amount of unsaturated fatty acid, while palm biodiesel is dominated by saturated fatty acid. The fuel properties of biodiesel, such as low temperature performance, kinematic viscosity and oxidation stability are correlated with the FAME composition components in biodiesel.

• Journal of the Korean Applied Science and Technology
• /
• v.35 no.4
• /
• pp.1307-1319
• /
• 2018

As interests in the air pollution increases, many kinds of researches are underway on the reduction of air pollutants. The removal of nitrogen oxides from the emission gas of diesel vehicles using urea solution has shown a great effect. The quality of urea solution is strictly defined by domestic law, but the increase of impurities in urea solution reduces the effect of reducing nitrogen oxides. Therefore, in this study, the change of physical properties of urea solution was analyzed after heating the urea solution for a certain temperature and time. Also, the changes of physical properties of urea solution were analyzed according to kinds of storage container and temperature for storing the urea solution. After heating the urea solution for a certain period of time, the biuret content in urea solution increased and the content of urea decreased. As the urea content decreased, both density and refractive index decreased. In the storage stability test carried out at a constant temperature with iron and PET containers, no change in physical properties was observed.

• Journal of Korean Society of Environmental Engineers
• /
• v.22 no.10
• /
• pp.1825-1832
• /
• 2000

Column experiments were conducted by using soil columns, to investigate feasibility and efficiency of in-situ ozone enhanced remediation for diesel-contaminated soil. The injection of gaseous ozone into soil column revealed the enhanced decomposition of ozone due to the catalytic reaction between ozone and metal (e.g., Fe, Mn etc.) oxides as evidenced by as much as 25 times shorter half-life of ozone in a sand packed column than in a glass beads packed column. Substantial retardation in the transport of and the consumption of ozone were observed in the diesel contaminated field soil and sand packed columns. After 16 hrs ozonation, 80% of the initial mass of diesel (as diesel range organic) concentration of $800{\pm}50mg/kg$, was removed under the conditions of the flow rate of 50mL/min and $6mg-O_3/min$. Whereas, less than 30% of diesel was removed in the case of air injection. Analysis of the residual TPH(total petroleum hydrocarbon) and selected 8 aliphatics of diesel compounds in the inlet and the outlet of the column confirmed that diesel nonselectively reacted with ozone and then shifted to lower carbon numbered molecules. Water content also was found to be an important parameter in employing ozone to the hydrocarbon-contaminated soil.

• Journal of Korea Soil Environment Society
• /
• v.2 no.3
• /
• pp.23-30
• /
• 1997

The purpose of this study was to evaluate effects of solids content and mixing speed in treatment of petroleum hydrocarbon contaminated soils using a slurry-phase bioreactor. Performance results on slurry-phase bioremediation of diesel fuel contaminated soil were generated at the bench-scale level. The fate of TPH(Total Petroleum Hydrocarbon) was evaluated in combination with biological treatment. Abiotic and biotic fate of the TPH were determined using soil not previously exposed to compounds in diesel fuel. The reactor volume for given throughput can be reduced by maximizing the solids content. Applications of 50% and 20% solids content(dry weight basis) were showed a little difference(57.5% : 61.6%) in biological TPH removal rate each other. Mixing and particle suspension are critical to desorption and biological degradation. In this standpoint, this study was performed using two mixing speed. When the reactor was operated at 70rpm, it had a better result in the particle suspension and TPH removal rate than the reactor with mixer rotated at 20rpm. In the reactor applied 20rpm, it was resulted in failure of particle suspension.