• Title/Summary/Keyword: Petrochemical complex area

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Characterization of Atmospheric Dispersion Pattern from Large Sources in Chungnam, Korea (충남지역 대형사업장의 대기오염물질 확산 특성 파악)

  • Choi, Woo Yeong;Park, Min Ha;Jung, Chang Hoon;Kim, Yong Pyo;Lee, Ji Yi
    • Particle and aerosol research
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    • v.17 no.3
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    • pp.55-69
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    • 2021
  • Chungnam region accounts for the largest SOX (22.8%) emission with the second-largest NOX (10.8%) emission in Korea due to the integration of many large industrial sources including a steel mill, coal-fired power plants, and petrochemical complex. Air pollutants emitted by large industrial sources can cause harmful problems to humans and the environment. Thus, it is necessary to understand dispersion patterns of air pollutants from large industrial sources in Chungnam to characterize atmospheric contamination in Chungnam and the surrounding area. In this study, seasonal atmospheric dispersion characteristics for SOX, NOX, and PM2.5 from ten major point sources in Chungnam were evaluated using HYSPLIT 4 model, and their contributions to SO2, NO2 concentrations in the regions near the source areas were estimated. The predictions of the HYSPLIT 4 model show a seasonal different dispersion pattern, in which air pollutants were dispersed toward the southeast in winter while, northeast in summer. In summer, due to weaker wind speed, air pollutants concentrations were higher than in winter, and they were dispersed to the metropolitan area. The local emissions of air pollutants in Taean area had a greater influence on the ambient SO2 and NO2 concentrations at Taean, whereas SOX and NOX emissions from large sources located at Seosan showed relatevely little effect on the ambient ambient SO2 and NO2 concentrations at Seosan.

The Petrochemical and Structural Study on the Charyong Batholith and its Associated Metallic Deposits (차령화강암(車嶺花崗岩) 저반(底盤)과 이에 관련된 금속광상(金屬鑛床)의 암석학적(岩石學的) 및 지질구조적(地質構造的) 연구(硏究))

  • Kim, Ok Joon
    • Economic and Environmental Geology
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    • v.10 no.3
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    • pp.107-117
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    • 1977
  • The Charyong batholith extends northeasterly from the west coast to the west of Wonju in the central parts of Korean Penninsula. The batholith is separated by the metamorphic complex into the northern and the southern granites. and is believed to intrude during the Daebo orogeny of early Jurassic to early Cretaceous age. It constitutes a sort of anticlinorium and the metamorphic complex can be regarded as a huge roof pendant. The modal analysis indicates that the Charyong batholith belongs to a series of adamellite-granodiorte-to-nalite. The oxidation property happened during a magmatic segregation reveals that the batholith shows in general orogenic assimilation trend. The granites of early to middle Jurassic age show orogenic assimilation trend, whereas those of late Jurassic to early Cretaceous age post orogenic noassimilation trend. The fracture system of the whole region is two folds: the fractures having attitute of $N25{\sim}40^{\circ}E$ and $70^{\circ}SE$ are regarded as tension fractures, and those of NS, and 50E to vertical and $N50^{\circ}E$ and $80^{\circ}E$ to vertical as shear fractures. All these facts suggest definitely that the Charyong batholith is the syntectonic intrusives during the Daebo orogeny. The mineral deposits in the area studied are gold-silver deposits in majority which was named by O,J.Kim(1970) as the Chonan metallogenic province. They are sulfides baring quartz veins which were emplaced along the tension and shear fractures originated by the Daebo orogeny.

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Spatial Distribution of Air Pollution in the Ulsan Metropolitan Region (울산지역 대기오염 공간분포)

  • Oh, Inbo;Bang, Jin-Hee;Kim, Soontae;Kim, Eunhye;Hwang, Mi-Kyoung;Kim, Yangho
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.4
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    • pp.394-407
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    • 2016
  • The spatial air pollution distribution of the Ulsan metropolitan region (UMR) was analyzed using monitoring data and high-resolution numerical simulations. A three-year (2011~2014) analysis for the average concentrations from the 13 air quality monitoring sites in the UMR showed that $SO_2$ and $PM_{10}$ levels in industrial regions were much higher than those in other regions, whereas spatial differences of $NO_2$ and CO concentrations were not significant. In particular, elevated $O_3$ concentrations were clearly found at urban sites near petrochemical complex area. Results from high-resolution simulations by CMAQ model performed for four months of 2012 showed large spatial variations in grid-average pollutant concentrations between industrial areas and other areas in the UMR, which displayed significant changes with wind pattern by season. It was noted that the increases of $SO_2$ and $PM_{10}$ levels were limited in costal industrial areas or over the area nearby the sea in all seasons. Modeled $O_3$ concentrations were quite low in industrial areas and main urban roads with large $NO_x$ emissions. However, the model presented that all pollutant concentrations were significantly increased in the urban residential areas near the industrial complexes in summer season with increase of southerly wind.

Prediction of Leachate Migration from Waste Disposal Site to Underground LPG Storage Facility and Review of Contamination Control Method by Numerical Simulations (수치모의를 통한 지하 LPG 저장시설에 인접한 폐기물매립지에서의 침출수이동 예측 및 제어공법 검토)

  • 한일영;서일원;오경택
    • Journal of the Korean Society of Groundwater Environment
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    • v.3 no.2
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    • pp.51-59
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    • 1996
  • In case waste disposal site is to be constructed close to the underground facilities such as LPG storage cavern which is completely maintained by groundwater pressure, it is generally requested that the possibility on leachate contamination of cavern area be reviewed and the countermeasure, if it is estimated cavern area is severely affected by leachate, be taken into consideration. Prediction was performed and leachate control plan was made using by analytical and the numerical analysis on the leachate migration which is likely to happen at the area between the proposed waste disposal site and the underground LPG storage cavern located at the U petrochemical complex. Analytical solutions were obtained by the conservative mass advection-diffusion equation and the effect of advection and dispersion factor on the leachate migration was reviewed through peclet number calculation and the functional relationship between the factors and leachate transport velocity was established, which leads to enable us to predict the leachate transport velocity without difficulties when different parameters (factors) are used for analytical solution. Numerical solutions were obtained by FEM using AQUA2D which is for the simulation of groundwater flow and contaminant transport. 3-D discrete fracture models were simulated and fracture flow analysis was performed and feasibility study on the water-curtain system was conducted through the fracture connectivity analysis in rock mass. As results of those analyses, it was interpreted that the leachate would trespass on the LPG storage cavern area in 30 years from the proposed wate disposal site and the vertical water-curtain system was effective mathod for the prevention of leachate's migration further into the cavern area.

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Research on the Prevention of Major Industrial Accident By Integrated Risk Management System (중대산업사고 예방을 위한 종합위험관리체제(IRMS) 구축에 관한 연구)

  • Kwon, Hyuck-Myun;Seong, Dae-Hyun;Kim, Jae-Hyun;Yim, Dae-Sik;Kim, Gi-Young;Pyeon, Mu-Wook;Moon, Il;Ko, Jae-Wook;Lee, Young-Soon;Yoon, En-Sup
    • Journal of the Korean Society of Safety
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    • v.18 no.3
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    • pp.88-93
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    • 2003
  • The Process Safety Management (PSM) by the Law of Industry, Safety and Health has been performed for preventing major accidents of chemical plants since 1996. In terms of preventing chemical accidents more precisely, it is essential to develop a tool for quantitative risk assessment. For this, KOSHA (Korea Occupational Safety and Health Agency) developed an Integrated Risk Management System (IRMS). The system is designed to assimilate data on chemical plant hazards from external database, to integrate these data with location information(topographic and demographic), and to make them user-friendly accessible. The system consists of several main functions: display of five major Korean petrochemical complex layout display of equipment layout with its information utilizing the external database, zonation of the hazard effected area with consequence analyses, the most probable accident scenario generation, accident/incident database and calculation of frequency of accident using equipment reliability database, etc. The highlight of IRMS is to provide the risk contours using GIS(Geographical Information System) technology. IRMS is intended to manage hazardous installation more systematically and effectively, to reduce the number of accident remarkably, further minimizing production loss in the plant. The system is now under application to about 500 PSM sites as well as and emergency authorities in Korea by KOSHA (Korea Occupational Safety and Health Agency)

Intrusive Phases and Igneous Pricesses in the Yeongju Batholith (영주저반의 관입상과 화성과정)

  • 황상구
    • Economic and Environmental Geology
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    • v.32 no.6
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    • pp.669-688
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    • 1999
  • The Yeongju granitoid batholith is a plutonic complex of huge area (1180km2) intruding the metamorphic rocks of the Yeongnam massif. The batholith, which is divided into fivelithofacies, consists of three separate plutons. The oldest Buseok pluton comprises four lithofacies: hornblende biotite tonalite, porphyrotoc biotite granodiorite, equigranular biotite grandiorite and biotite granite. The middle Chunyang pluton has been called as Chunyang granite that ranges in compostion from granodiorite to granite. The youngest Jangsu pluton is intrusions that has lithofacies of two mica granite. The contact between Buseok pluton and the rest two plutons shows obvious intrusive relations, but relation between the Chunyang and the Jangsu pluton is far away, so gives no indication of relative ages. Changes in nextures and micristructures, as well as in the mineral contents, take place between rock types og the plutons. only the Buseok pluton shows faliations of two type: magmatic foliation and regional mylonal foliation. K-Ar age deteminations fall into 171.7$\pm$3.2~162.3$\pm$3.1 Ma in the Buseok pluton, 153.9$\pm$2.9 Ma in the Chunyang pluton and 145.3$\pm$2.7 Ma in the jangsu Pluton. The batholith presents three separate intrusive phases which range in composition from tonalite to granite to granite. Each intrusive phase apperars to have been intruded in a pulse from an underlying, differentiating magma. The petrochemical data showthat three plutons are within the diagnostic range for continental arc orogenic tectonic setting, whereas Jangsu pluton approaches postorogenic setting. The data suggest that three plutons are calc-aclkalline series, and that temporal compositional variations change progerssively from tonalite through grandiorite to granite between the intrusive phases. so we consider that the magmas for all the phases were probably derived from a differentiation by fractional crystallization of a parental magma. The tonalite magma of the Buseok phase was tapped was tapped from a chamber deep in the crust, and then would have to rise at a rapid rate to its final level of emplacement. The tonalite magma in the chamber was gradually enolved through granodiorite magma into granite magma by fractional crystallization. The magmas of the younger phases were respectively tapped with temporal interval from a evolved magma of the chamber that rose into a shallower lever in the crust, and rose to their present level of emplacement.

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Prediction of Inhalation Exposure to Benzene by Activity Stage Using a Caltox Model at the Daesan Petrochemical Complex in South Korea (CalTOX 모델을 이용한 대산 석유화학단지의 활동단계에 따른 벤젠 흡입 노출평가)

  • Lee, Jinheon;Lee, Minwoo;Park, Changyong;Park, Sanghyun;Song, Youngho;Kim, Ok;Shin, Jihun
    • Journal of Environmental Health Sciences
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    • v.48 no.3
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    • pp.151-158
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    • 2022
  • Background: Chemical emissions in the environment have rapidly increased with the accelerated industrialization taking place in recent decades. Residents of industrial complexes are concerned about the health risks posed by chemical exposure. Objectives: This study was performed to suggest modeling methods that take into account multimedia and multi-pathways in human exposure and risk assessment. Methods: The concentration of benzene emitted at industrial complexes in Daesan, South Korea and the exposure of local residents was estimated using the Caltox model. The amount of human exposure based on inhalation rate was stochastically predicted for various activity stages such as resting, normal walking, and fast walking. Results: The coefficient of determination (R2) for the CalTOX model efficiency was 0.9676 and the root-mean-square error (RMSE) was 0.0035, indicating good agreement between predictions and measurements. However, the efficiency index (EI) appeared to be a negative value at -1094.4997. This can be explained as the atmospheric concentration being calculated only from the emissions from industrial facilities in the study area. In the human exposure assessment, the higher the inhalation rate percentile value, the higher the inhalation rate and lifetime average daily dose (LADD) at each activity step. Conclusions: Prediction using the Caltox model might be appropriate for comparing with actual measurements. The LADD of females was higher ratio with an increase in inhalation rate than those of males. This finding would imply that females may be more susceptible to benzene as their inhalation rate increases.

Application of Regional Landslide Susceptibility, Possibility, and Risk Assessment Techniques Using GIS (GIS를 이용한 광역적 산사태 취약성, 가능성, 위험성 평가 기법 적용)

  • 이사로
    • Economic and Environmental Geology
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    • v.34 no.4
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    • pp.385-394
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    • 2001
  • There are serious damage of people and properties every year due to landslides that are occurred by heavy rain. Because these phenomena repeat and the heavy rain is not an atmospheric anomaly, the counter plan becomes necessary. The study area, Ulsan, is one of the seven metropolitan, and largest cities of Korea and has many large facilities such as petrochemical complex and factories of automobile and shipbuilding. So it is necessary assess the landslide hazard potential. In the study. the three steps of landslide hazard assessment techniques such as susceptibility, possibility, and risk were performed to the study area using GIS. For the analyses, the topographic, geologic, soil, forest, meteorological, and population and facility spatial database were constructed. Landslide susceptibility representing how susceptible to a given area was assessed by overlay of the slope, aspect, curvature of topography from the topographic DB, type, material, drainage and effective thickness of soil from the soil DB, lype age, diameter and density from forest DB and land use. Then landslide possibility representing how possible to landslide was assessed by overlay of the susceptibility and rainfall frequency map, Finally, landslide risk representing how dangerous to people and facility was assessed by overlay of the possibil. ity and the population and facility density maps The assessment results can be used to urban and land use plan for landslide hazard prevention.

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Some Heavy, Metal Concentrations of Seawater and Mytilus coruscus in Ulsan Seaside (울산연안 해수 및 홍합 중의 중금속 함량)

  • Kim, Sun- Bun;Lee, Jong-Young;Jang, Bong-Ki
    • Journal of agricultural medicine and community health
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    • v.21 no.1
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    • pp.85-95
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    • 1996
  • To examine the contamination in Ulsan coastal area, some heavy metal concentrations in sea water and Mytilus coruscus have been measured. Sea water samples were collected on April 6 in 1995 and Mytilus coruscus samples were collected on April 2 in 1995. Total number of sea water samples was 26 and that of Mytilus coruscus was 54. The sites where the samples collected were same in sea water and Mytilus coruscus. The method of analysis was atomic absorption spectrophotometer. The results indicated that the heavy metal concentrations of sea water were varied according to the sampling stations. The concentrations of cadmium, manganese, zinc in sea water collected in the coastal area near Mipo complex were higher than those of other coastal areas, and the concentrations of lead in sea water collected in the coastal area near petrochemical complex were higher than those of others. In general the concentrations of lead, zinc, copper in sea water were proportionate to those in Mytilus coruscus. The mean concentration rates of lead, cadmium, manganese in Mytilus coruscus inhabiting in Ulsan coastal area were similar, 1070, 1370 and 1300, respectively. The concentration rate of mercury was 80, the lowest value of other heavy metals, and that of copper was 6940, the highest value. Consequently it seems to be more desirable to use Mytilus coruscus as a sample to examine the contamination of coastal area than sea water.

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A Study on the Comparison of Areas Near Gunsan according to the Revision of the National Air Pollutant Emissions (CAPSS) in 2020 (국가대기오염물질 배출량(CAPSS)의 2020년 산정 방법 개정에 따른 군산 인근지역 비교에 관한 연구)

  • Sang-Hun Park;Seong-Cheon Kim
    • Journal of Environmental Health Sciences
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    • v.49 no.4
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    • pp.190-200
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    • 2023
  • Background: Gunsan has been constantly affected by pollutants generated by the Saemangeum development and the construction industry since the completion of the Saemangeum seawall on April 27, 2010. However, there are limitations to its study, such as taking into consideration weather conditions, geographical factors, and foreign inflows. Objectives: In this study, we compared the Existing-CAPSS emissions of Gunsan with Recalculated-CAPSS emissions data to analyze the differences in emissions characteristics by year (2016~2019). Methods: Using Existing data on CAPSS emissions (2016~2019) and Recalculated-CAPSS emissions (2016~2019) for Gunsan, which were Recalculated following the improvement of emissions calculations for 2020, we organized CO, NOX, SOX, PM10, VOCS, and NH3 emissions by substance and investigated the differences and characteristics of the Recalculated emissions by year. Results: For Re-CO and Re-PM10, the emission characteristics of CO were examined as energy industry combustion and PM10 emission characteristics were examined as ship cargo from non-road transportation sources, as ship leisure sources were excluded from non-road transportation source emissions. Conclusions: Comparing the emissions of Existing-CAPSS and Recalculated-CAPSS in Gunsan, the emissions of Recalculated-CAPSS by substance decreased by 39.76% for CO, 9.98% for PM10, 5.53% for VOCS, and 9.24% for NH3, while Re-NOX increased by 2.86% and Re-SOX increased by 1.97%. On the other hand, when comparing the emissions characteristics of Existing-CAPSS and Recalculated-CAPSS in Gunsan, Jeonju, and Iksan, the emission characteristics of Re-NOX, Re-SOX, Re-VOCS and Re-NH3 were similar to those of Ex-NOX, Ex-SOX, Ex-VOCS, and Ex-NH3. As such, Gunsan, Iksan, and Jeonju, showed differences in the comparison of different emission characteristics due to the geographical characteristics of the region (population, area, topography, weather factors) and the characteristics of the industrial complex (metal, petrochemical).