• 통상정보연구
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• 제10권3호
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• pp.3-21
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• 2008

This research investigates the strategy for application of E-Trade to SMEs to analyze the economic effect of e-trade. And the influence of the proliferation of e-business and e-trade upon the industrial business conditions, value-chain, and business activities is also analyzed. The subjects of the inquiry are the nationwide petrochemical industries in which small and medium sized companies are in mutual and intimate cooperation. The results show that the business structure of the petrochemical industries are divided into four stages, and, with the introduction of e-business, the value chain is changed by stages. And the change of value-chain explains the transition of the e-business of petrochemical industries including trade business into industrial DB and leads to a variety of the economic effect including the reduction in the trade expense, the change of the production process, and the innovation of trade structure.

• Corrosion Science and Technology
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• 제8권3호
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• pp.119-125
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• 2009

Corrosion assessment has a number of uses but the use considered here is as a precursor to Risk-Based Inspection (RBI) planning. Systematic methods consisting of technical modules of RBI program were used to assess the effect of specific corrosion mechanism on the probability of failure in equipments of petrochemical plants. Especially in part of the damage and corrosion assessment, screening step involved evaluating the combinations of process conditions and construction materials for each equipment item in order to determine which damage mechanisms are potentially active. For general internal corrosion, either API 510 or API 570 was applied as the damage rate in the calculation to determine the remaining life and inspection frequency. In some cases, a measured rate of corrosion may not be available. The technical modules of RBI program employ default values for corrosion, typically derived from published data or from experience with similar processes, for use until inspection results are available. This paper describes the case study of corrosion and damage assessment by using RBI methodology in petrochemical plant. Specifically, this paper reports the methodology and the results of its application to the petrochemical units using the $KGS-RBI^{TM}$ program, developed by the Korea Gas Safety Corporation to suit Korean situation in conformity with API 581 Codes.

• 플랜트 저널
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• 제5권3호
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• pp.50-58
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• 2009

In this paper, the present condition for localization of process pumps and the enhancement method of the localization ratio of process pumps for refinery and chemical plant market were studied. The market of plant industry in the world has grown rapidly since 2000. However, the profit of domestic plant EPC compaies cound not have been increased as much as the market scale because they procured most of equipment from overseas. To make remarkable profit of plant EPC companies in the petrochemical industry, localization of equipments is required. Suitable equipment for localization is process pump applied API 610 standard. An purchased amount of pumps from overseas by domestic plant EPC companies in the last two years were 230 billion won. If process pumps are localized then an profit of plant EPC project will increase.

• 한국물환경학회지
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• 제22권1호
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• pp.59-65
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• 2006

The effluent limitations for individual industry based on the best available technology economically achievable (BAT) have been required to achieve effective regulation. BAT assessment criteria that are suitable for the circumstances of Korean industry were developed in the previous study. The criteria were applied to determine the BAT for petrochemical basic compound manufacturing (PBCM) and plastics and synthetic resins manufacturing (PSRM) industry. Wastewater discharged from the each category contains high concentration of COD and toluene. Eighteen sites were surveyed and wastewater qualities were analyzed. Six and two different technologies were applied to the PBCM and PSRM industry for the end-of-pipe treatment process, respectively. The technology candidates were evaluated in terms of environmental impacts, economically achievability, treatment performance and economical reasonability. As the result, the technology options: typical activated-sludge process + sand filtration + activated carbon adsorption (PBCM) and wet oxidation + chemical precipitation + typical activated-sludge process + chemical precipitation (PSRM) were selected as the BAT for each industry.

• Korean Chemical Engineering Research
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• 제56권2호
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• pp.212-221
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• 2018

Process safety incidents and loss events can be prevented if we identify and adequately take measures on process safety incident precursors in a timely manner. If we look into and take action against the process safety hazard factors causing the incident in the refinery and petrochemical plant, major process safety incidents can be prevented through eliminating or decreasing hazardous factors. We conducted a survey for the major process safety incident precursor to look specifically into the potential process safety hazardous factors of refineries and petrochemical plants in the Yeosu chemical complex. A self-assessment checklist, which was published by Center for Chemical Process Safety "Recognizing catastrophic incident warning signs in the process industry" on major incidents warning sign, was used for the survey. Through this survey, the major process safety incident leading indicators in the process industry were found by process safety management elements, and each site and/or facility can use these leading indicators for activities for process safety incident prevention. In addition, we proposed action items required to eliminate the root cause of those process safety incident leading indicators.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.478-481
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• 2001

The spent petrochemical catalyst used in the manufacturing process of terephthalic-acid contains valuable metals such as cobalt and manganese. To recover these metals, sulfuric acid leaching was performed with hydrogen peroxide as a reducing agent. Low extractions of Mn, Co and Fe were obtained by sulfuric acid leaching without reducing agent. With adding hydrogen peroxide as a reducing agent, the high extraction of these metals could be obtained. Different from general leaching experiment, the extraction rates of metal components were decreased with increasing reaction temperature in this case. Under the optimum condition, the extraction rates of Mn, Co and Fe were 93.0%, 87.0% and 100% respectively.

• International Journal of Quality Innovation
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• 제7권2호
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• pp.97-124
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• 2006

The purpose of this research is to create an expert risk-based piping system inspection model. The proposed system includes a risk-based piping inspection system and a piping inspection guideline system. The research procedure consists of three parts: the risk-based inspection model, the risk-based piping inspection model, and the piping inspection guideline system model. In this research procedure, a field plant visit is conducted to collect the related domestic information (Taiwan) and foreign standards and regulations for creating a strategic risk-based piping inspection and analysis system in accordance with the piping damage characteristics in the petrochemical industry. In accordance with various piping damage models and damage positions, petrochemical plants provide the optimal piping inspection planning tool for efficient piping risk prediction for enhancing plant operation safety.

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2001년도 전지기술심포지움
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• pp.145-161
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• 2001

Novel characterization of thermal properties of a battery has been introduced by defining its frequency-dependent thermal impedance function. Thermal impedance function can be approximated as a thermal impedance spectrum by analyzing experimental temperature transient which is related to the thermal impedance function through Laplace transformation. In order to obtain temperature transient, a process has been devised to generate external heat pulse with heating wire and to measure the response of battery. This process is used to study several commercial Li-ion batteries of cylindrical type. The thermal impedance measurements have been performed using potentionstat/galvanostate controlled digital signal processor, which is more commonly available than flow-meter usually applied for thermal property measurements. Thermal impedance spectra obtained for batteries produced by different manufactures are found to differ considerably. Comparison of spectra at different states of charge indicates independence of thermal impedance on charging state of battery. It is shown that thermal impedance spectrum can be used to obtain simultaneously thermal capacity and thermal conductivity of battery by non-linear complex least-square fit of the spectrum to thermal impedance model. Obtained data is used to simulate a response of the battery to internal heating during discharge. It is found that temperature inside the battery is by one-third larger that on its surface. This observation has to be considered to prevent damage by overheating.

• 공업화학
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• 제7권6호
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• pp.1204-1208
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• 1996

파라자일렌(p-xylene)을 산화반응시켜 테레프탈산(terephthatic acid)을 제조하는 과정 중에 발생하는 주요 유기불순물을 효과적으로 분석하는 방법을 수립하였다. 이 제조공정 중에 발생하는 유기불순물은 매우 다양하나, 여기에서는 주로 benzoic acid, p-toluic acid, p-tolualdehyde, 4-carboxybenzaldehyde, phthalic acid, isophthalic acid, trimellitic acid와 4-hydroxymethyl benzoic acid 등의 유기불순물을 분석하는데 촛점을 맞추었다. 이 유기물들은 공정 중의 모액이나 고체상태의 테레프탈산 입자에 존재하는데, 이들을 동시에 분석하기 위해 99% bis(trimethylsilyl)trifluoroacetamide와 1% trimethylchlorosilane의 내부표준용액과 pyridine의 혼합용액내에서 trimethylsilylation으로 시료를 전처리하고 gas chromatography를 이용하여 분석한 결과 상기한 유기물이 모두 성공적으로 분리되어 50분 이내에 정량분석할 수 있었다.

• 한국환경과학회지
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• 제5권1호
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• pp.51-59
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• 1996

The purpose of this study was to evaluate the partial oxidation of the biological treatment plant effluents using Fenton's reagent as a pretreatment step prior to a tertiary biological oxidation of these effluents. Fenton's reagent was evaluated as a pretreatment process for inhibitory or refractory organics. Based on the Fenton oxidation system, the petrochemical wastewater treatment plant effluent was shown to have significant improvement in toxicity after oxidation with hydrogen peroxide. For example, at ranee of 42 ∼ 184 mg/L COD of petrochemical plant effluents, the COD removal efficiencies were from 38.2% to 60.1% after reaction with hydrogen peroxide 200 mg/L and Fe2+ 100 mg/L and reaction time was 30 minutes. The total TOC reduction were about 15.8∼22.4% with same test condition and difference between the overall removal rate and BOD/COD ratio after Fenton's oxidation estabilished in the biodegradation and otherwise meets the discharge standard or reuse for cooling tower make-up water.