• Title/Summary/Keyword: Peroxide Value

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Studies on Antoxidative Action of Garlic Components Isolated from Garlic(Allium Stivum, L) Part III : Effects of water soluble fractions from steamed garlic on inhibition of lipoperoxide formation. (마늘성분의 산화방지작용에 대한 연구 - 제 3 보 가열수용성분의 과산화지질 생성억제효과에 미치는 영향 -)

  • 전희정
    • Journal of the Korean Home Economics Association
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    • v.24 no.4
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    • pp.87-92
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    • 1986
  • In Order to study antioxidative action of water soluble fractions which had been steamed according to time as 15, 30, 60 and 120 minutes, they were compared through the inhibitory effect of lipoperoxide formation by TBA, peroxide value and induction time for the first period of lipoperoxide formation. Results are obtained as follows: 1. In vivo experiment with TBA value, water soluble fractions showed aninhibitory effect of lipoperoxide formation. 2. Comparing with the inhibitory effect of lipoperoxide formation with TBA value in vivo, water soluble fractions which had been steamed for 30 and 60 minutes and those from fresh garlic proved effective in the blood by intraperitoneal administration. But in the liver all of water soluble fractions showed distinctive effect as in the case of fresh garlic. 3. Effect of water soluble fractions which had been steamed for 15, 30 and 60 minutes showed a distinctive effect, water soluble fraction which had been steamed for 120 minutes and that from fresh garlic also showed effective in the blood as compared with control. 4. In oral administration, water soluble fraction of fresh garlic was the most effective in the liver. 5. In vitro experiment with peroxide value, water soluble fractions which had been steamed for 60 and 120 minutes were effective, all of water soluble fractions from steamed garlic were more effective than fresh garlic. 6. In Examining the induction time for the first period of lipoperoxide formation in vitro, water soluble fractions steamed for 30, 60 and 120 minutes were effective. Other fractions were also more effective than control.

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Changes of Lipids in Whole Soybean and Soy Flour during Storage (대두(大豆) 및 대두분(大豆粉) 저장중 지방질의 변화)

  • Chang, Young-Sang;Cho, Kyung-Yeon;Chang, Hak-Gil
    • Korean Journal of Food Science and Technology
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    • v.19 no.4
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    • pp.305-310
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    • 1987
  • Whole soybean and soy flour were stored under two humidifies (65% and 85% RH) at $25^{\circ}C$ for 90 days to investigate the oxidation of total lipids. It was found that acid value and peroxide value of total lipids extracted from whole soybean and soy flour increased in proportion with the storage period. The change was more pronounced for soy flour stored at 85% RH. The increase of acid value and peroxide value was retarded by using the OPP/Al/PE film as packing material and the change of fatty acid was also reduced for whole soybean and soy flour. As for the change of fatty acid composition, polyunsaturated fatty acids such as linoleic and linolenic acid decreased while saturated fatty acid content increased in proportion with the storage period.

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An Application of Surface Plasmon Resonance to Evaluation of Quality Parameters of Soybean Oil during Frying

  • Gil, Bo-Gim;Chang, Young-Ki;Cho, Yong-Jin
    • Food Science and Biotechnology
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    • v.15 no.3
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    • pp.404-408
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    • 2006
  • Feasibility of surface plasmon resonance (SPR) method to evaluate soybean frying oil quality was evaluated. Free fatty acid value, p-anisidine value, conjugated dienoic acid content, conjugated trienoic acid content, peroxide value, iodine value, total polar compound (TPC), ratio of unsaturated fatty acid to saturated fatty acid, refractive index, dielectric constant, smoking point, and L, a, and b of Hunter color system were selected as parameters related to conventional evaluation of soybean frying oil quality. SPR scale mapped with conventional quality parameters well described free fatty acid value, conjugated dienoic acid content, dielectric constant, TPC, and b of Hunter color system, as shown by correlation and linear regression analyses.

Fenton Process for Treatment of Contaminated Groundwater

  • Jung, Oh-Jin;Park, Chil-Nam
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.10 no.S_4
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    • pp.165-172
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    • 2001
  • We investigated the optimal experimental conditions and reaction kinetics for the decompositions of PCE, TCE, naphthalene, and chloroform using conventional Fenton oxidation process. Additionally, the influence of pH on the decompositions of PCE was also evaluated. The results indicated that the optimal pH value was around 3. The dosage of Fenton's reagent and the molar ratio of hydrogen peroxide to ferrous ion for an approximately complete decomposition was found to depend on the properties of the organic compound. Due to their unsaturated structures, the results show that PCE, TCE, and naphthalene could be all effectively decomposed by Fenton's reagent oxidation. Their unsaturated structures could be mostly destoyed within first 1-2 minutes at a low dosage with an certain molar ratio of hydrogen peroxide to ferrous ion. However the saturated compound such as chloroform was more difficult to decompose even with a relatively high dosage of Fenton's reagent.

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Investigation of the Susceptibility of Arctic Arthrobacter sp. PAMC 25486 to Mutagens (극지미생물 Arthrobacter sp. PAMC 25486의 돌연변이 유발 물질에 대한 감수성 평가)

  • Kim, Sang-geun;Choi, Jong-il;Han, Se Jong
    • Journal of Radiation Industry
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    • v.8 no.2
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    • pp.105-109
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    • 2014
  • This study was conducted to investigate the sensitivity of Arthrobacter sp. PAMC 25486 to various mutagens. ${\gamma}-ray$, UV-ray, Ethyl methane sulfonate (EMS) and hydrogen peroxide ($H_2O_2$) were used as mutagen, and the survival rate of Arthrobacter sp. was measured at various doses of ${\gamma}-ray$ and UV-ray, and concentrations of EMS and $H_2O_2$. Decimal reduction dose ($D_{10}$ value) of Arthrobacter sp. was determined 370 Gy for a gamma irradiation treatment, 0.019 J for a UV ray, 2.5 mM for EMS, and 230 mM for $H_2O_2$. This result will be applied for the development of superior mutant strain of Arctic bacteria producing valuable compounds.

Amperometric Biosensor for Hydrogen Peroxide Determination Based on Black Goat Liver-Tissue and Ferrocene Mediation (흑염소 간-조직과 Ferrocene 매개체를 사용한 과산화수소정량 전류법 바이오센서)

  • Kwon, Hyo-Shik;Park, In-Keun;Kim, Yang-Sug
    • Journal of the Korean Chemical Society
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    • v.48 no.5
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    • pp.491-498
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    • 2004
  • The response characteristics of the bioelectrode developed by the co-immobilization of black goat liver tissue and ferrocene in a carbon paste matrix for the amperometric determination of hydrogen peroxide were evaluated. In the range of electrode potential examined ($-0.3{\sim}+0.0\;V$ vs. Ag/AgCl), the response time was relatively short (t95%=12 s) and it responded in the wide range of pH. The detection limit was 2.25${\times)10^{-6}M$ and a relative standard deviation of the measurements which were repeated 15 times using 1.0${\times}10^{-2 }$M hydrogen peroxide was 1.87%. The bioelectrode sensitivity decreased to 50% of the original value in 19 days of continuous use.

Uncertainty of Peroxide Value Determination in Fat in Follow up Formula (성장기용 조제식에 함유된 유지성분의 과산화물가 측정불확도)

  • Kim, Sung-Han;Kwack, Byung-Man;Ahn, Jang-Hyuk;Kong, Un-Young
    • Korean Journal of Food Science and Technology
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    • v.36 no.6
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    • pp.885-892
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    • 2004
  • Peroxide values (PV) of fat from fallow up formula were determined using redox-potentiometric titration method and standard method, which is based on KI oxidation by hydroperoxides and volumetric titration of liberated iodine, and their uncertainties were compared. Uncertainty sources in measurement, such as sample weight, sodium thiosulfate concentration, and titer, were identified and used as parameters for combined standard uncertainty based on Guide to the expression of uncertainty in measurement and Draft EURACHEM/CITAC Guide. Analytical results and combined standard uncertainties of peroxide values (PV) determined by standard burette and potentiometric titrations were $2.05{\pm}0.17\;and\;1.96{\pm}0.07\;meq/kg$, respectively, suggesting potentiometric titration method is suitable for determining PV of fat with low PV, because uncertainty of PV determination obtained by potentiometric titration was lower than that obtained by burette titration.

The Optimum Levels of Alkaline Hydrogen Peroxide Treatment of Rice Straw for Feed (볏짚 사료가치 증진을 위한 알카리성 과산화수소의 적정 처리수준)

  • Choi, Yoon-Hee;Kim, Myeong-Sook;Hong, Jai-Sik
    • Applied Biological Chemistry
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    • v.37 no.5
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    • pp.320-325
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    • 1994
  • These studies were conducted to investigate the chemical composition changes in in vitro digestibility for the improvement of nutritive value of rice straw by alkaline hydrogen peroxide. The content of neutral detergent fiber (NDF), acid detergent fiber (ADF), hemicellulose, cellulose and lignin in rice straw was decreased with higher level of $H_2O_2\;(pH 11.5)$. The content of ADF, cellulose and ash of the rice straw washed after $H_2O_2\;(pH 11.5)$ treatment tended to be increased but NDF, hemicellulose and lignin were decreased with higher concentration of $H_2O_2\;(pH 11.5)$. In the rice straw washed after alkaline hydrogen peroxide treatment the decomposition of cellulose and lignin was effective in $pH\;11.5{\sim}12.5$, in smaller cutting size and $55^{\circ}C$. The in vitro organic matter digestibility was increased with higher $H_2O_2$ concentration and smaller cutting size of rice straw.

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Qualitative Characteristics and Determining Shelf-Life of Milk Beverage Product Supplemented with Coffee Extracts

  • Yoon, Ji-Woo;Ahn, Sung-Il;Kim, Ha-Na;Park, Jun-Hong;Park, Sun-Young;Kim, Jae-Hoon;Oh, Duk-Geun;Jhoo, Jin-Woo;Kim, Gur-Yoo
    • Food Science of Animal Resources
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    • v.37 no.2
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    • pp.305-312
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    • 2017
  • This study was conducted to establish the shelf-life of a milk beverage product supplemented with coffee extracts. Qualitative changes including peroxide value (PV), microorganism content, caffeine content, and sensory evaluation were measured periodically in beverages kept at 10, 20, and $30^{\circ}C$ for 8 wk. Lipid oxidation of the product was measured by peroxide value analysis, and apparent changes were observed during a 4 wk storage period. Caffeine analysis revealed that the changes in caffeine content were negligible during the storage period. Total aerobic bacteria, Escherichia coli, yeast, and mold were not detected in the products during an 8 wk storage period. Sensory evaluation revealed that after 4 wk of storage overall acceptance was less than 3 points on a 5-point scale. In this study, PV was used as an indicator of the shelf-life of the milk beverage product. PV analysis revealed that a value of 20 meq/kg was the end of the shelf-life using the Arrhenius equation and the accelerated shelf-life test (ASLT). Assuming that the beverages are kept at $4^{\circ}C$ during distribution, calculation of when the PV reached the quality limit point (20 meq/kg) was done with the equation ln(PV) = 0.3644X - 2.21834 and, using that equation, $PV=e^{0.3644X-2.21834}$ was calculated. Therefore, 14.3086 wk was determined to be the shelf-life of the milk beverage supplemented with coffee when stored at $4^{\circ}C$.

Effects of Roasting Condition on the Quality Characteristics and Oxidative Stabilities of Rice Germ (볶음 조건이 쌀눈의 품질 특성 및 산화안정성에 미치는 영향)

  • Ko, Soon-Nam;Kim, Chul-Jin;Kim, In-Hwan
    • Korean Journal of Food Science and Technology
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    • v.35 no.3
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    • pp.347-352
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    • 2003
  • In order to compare quality characteristics and oxidative stabilities of rice germs prepared under different roasting conditions, sensory evaluation, color value, tocols (tocopherol+tocotrienol) contents, and peroxide value were investigated. Optimum roasting temperatures for the best acceptability were 20, 10, and 6 min at 170, 180 and 190, respectively. Hunter color a values of rice germ increased as roasting temperature and time increased, whereas L value decreased. Peroxide values of unroasted, and roasted rice germs at $170^{\circ}C$ for 20 min, $180^{\circ}C$ for 10 min, and $190^{\circ}C$ for 6 min were 2.0, and 145.6, 169.5, and 182.9 meq/kg, respectively, after 9 days storage at $60^{\circ}C$. Four tocopherol and three tocotrienol isomers were identified, whereas no ${\beta}$-tocotrienol was detected. The major tocopherol and tocotrienol isomers in rice germ were ${\alpha}$-tocopherol and ${\alpha}$-tocotrienol, respectively. ${\alpha}$-Tocopherol content in roasted rice germ decreased significantly during storage, whereas those of ${\beta}$- and ${\gamma}$-tocopherols slowly decreased. ${\delta}$-Tocopherol had the highest stability among tocopherol isomers in roasted rice germ. Similar trends were observed in tocotrienol isomers.