• Title/Summary/Keyword: Permeate

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Evaluation of Ultrafiltration Membrane Using Gel Permeation Chromatography (GPC를 이용한 한외여과막의 평가)

  • 정건용;정동진;김천호;신현수;민병렬;김래현
    • Membrane Journal
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    • v.13 no.2
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    • pp.81-87
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    • 2003
  • The permeation experiments f3r the aqueous dextran solutions of which the molecular weights were distributed between several thousands and million daltons were carried out using the dead-end cell system equipped with sheet membrane to determine the molecular weight cut-off (MWCO) of ultrafiltration membranes. The dextran rejections with respect to molecular weight were obtained by GPC analysis of feed and permeate solutions, then the MWCO was decided as the dextran molecular weight corresponding to the 90% rejection. The MWCO of PBTK membrane manufactured by Millipore was varied between 63,000 and 68,000 daltons as the pressure increased from 0.5 to 2.0 bar. However, the MWCO of PBQK(Millipore) and UE 1812(Saehan) under the above operating pressure increased to 3.5 and 4.3 times, respectively. Also, the MWCO of PBTK increased to 25% as the membrane permeation increased from 10 to 40% of the feed solution.

Modelling of starch industry wastewater microfiltration parameters by neural network

  • Jokic, Aleksandar I.;Seres, Laslo L.;Milovic, Nemanja R.;Seres, Zita I.;Maravic, Nikola R.;Saranovic, Zana;Dokic, Ljubica P.
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.115-121
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    • 2018
  • Artificial neural network (ANN) simulation is used to predict the dynamic change of permeate flux during wheat starch industry wastewater microfiltration with and without static turbulence promoter. The experimental program spans range of a sedimentation times from 2 to 4 h, for feed flow rates 50 to 150 L/h, at transmembrane pressures covering the range of $1{\times}10^5$ to $3{\times}10^5Pa$. ANN predictions of the wastewater microfiltration are compared with experimental results obtained using two different set of microfiltration experiments, with and without static turbulence promoter. The effects of the training algorithm, neural network architectures on the ANN performance are discussed. For the most of the cases considered, the ANN proved to be an adequate interpolation tool, where an excellent prediction was obtained using automated Bayesian regularization as training algorithm. The optimal ANN architecture was determined as 4-10-1 with hyperbolic tangent sigmoid transfer function transfer function for hidden and output layers. The error distributions of data revealed that experimental results are in very good agreement with computed ones with only 2% data points had absolute relative error greater than 20% for the microfiltration without static turbulence promoter whereas for the microfiltration with static turbulence promoter it was 1%. The contribution of filtration time variable to flux values provided by ANNs was determined in an important level at the range of 52-66% due to increased membrane fouling by the time. In the case of microfiltration with static turbulence promoter, relative importance of transmembrane pressure and feed flow rate increased for about 30%.

Research Trend on ZIF-8 Membranes for Propylene Separation (프로필렌 분리를 위한 ZIF-8 분리막의 연구 동향)

  • Kim, Jinsoo;Othman, Mohd Roslee
    • Membrane Journal
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    • v.29 no.2
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    • pp.67-79
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    • 2019
  • High purity propylene (propene) is an octane-enhancing chemical and also feedstock to industrially important chemicals. Purification of propylene from propane mixture is technologically and financially challenging because of their close boiling points. ZIF-8 membrane has been increasingly researched due to its great potential to separate propylene from propane effectively by molecular sieving. The increasing interest in ZIF-8 membranes lies in the so called "gate opening" effect. The gate opening effect enlarges the membrane pores and preferentially allows propylene to permeate through the membrane pores, while retaining the larger and heavier propane molecules in the feed stream in order to effect high propylene separation from propylene/propane mixture. In this paper, the widely accepted methods of ZIF-8 membrane preparation and parameters affecting propylene permeation and selectivity in ZIF-8 membrane are identified and reviewed.

Preparation of highly hydrophobic PVDF hollow fiber composite membrane with lotus leaf-like surface and its desalination properties

  • Li, Hongbin;Zi, Xingchen;Shi, Wenying;Qin, Longwei;Zhang, Haixia;Qin, Xiaohong
    • Membrane and Water Treatment
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    • v.10 no.4
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    • pp.287-298
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    • 2019
  • Lotus leaf has a special dual micro and nano surface structure which gives its highly hydrophobic surface characteristics and so-called self cleaning effect. In order to endow PVDF hollow fiber membrane with this special structure and improve the hydrophobicity of membrane surface, PVDF hollow fiber composite membranes was obtained through the immersion coating of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) dilute solution on the outside surface of PVDF support membrane. The prepared PVDF composite membranes were used in the vacuum membrane distillation (VMD) for the desalination. The effects of PVDF-HFP dilute solution concentration in the dope solution and coating time on VMD separation performance was studied. Membranes were characterized by SEM, WCA measurement, porosity, and liquid entry pressure of water. VMD test was carried out using $35g{\cdot}L^{-1}$ NaCl aqueous solution as the feed solution at feed temperature of $30^{\circ}C$ and the permeate pressure of 31.3 kPa. The vapour flux reached a maximum when PVDF-HFP concentration in the dilute solution was 5 wt% and the coating time was kept in the range of 10-60 s. This was attributed to the well configuration of micro-nano rods which was similar with the dual micro-nano structure on the lotus leaf. Compared with the original PVDF membrane, the salt rejection can be well maintained which was greater than 99.99 % meanwhile permeation water conductivity was kept at a low value of $7-9{\mu}S{\cdot}cm^{-1}$ during the continuous testing for 360 h.

A Study on the Relationship between Factors Affecting Soldering Characteristics and Efficiency of Half-cell Soldering Process with Multi-wires (Half-cell 기반 multi-wires 접합 공정에서 접합 특성에 영향을 주는 요인과 효율의 상관관계 연구)

  • Kim, Jae Hun;Son, Hyoung Jin;Kim, Sung Hyun
    • Current Photovoltaic Research
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    • v.7 no.3
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    • pp.65-70
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    • 2019
  • As a demand of higher power photovoltaic modules, shingled, multi-busbar, half-cell, and bifacial techniques are developed. Multi-busbar module has advantage for large amount of light havesting. And, half-cell is high power module for reducing resistive losses and higher shade tolerance. Recently, researches on multi-busbar is focused on reliability according to adhesion and intermetallic compound between Sn-Pb solder and Ag electrode. And half-cell module is researched to comparing with full-sized cell module for structure difference. In this study, we investigated the factors affecting to efficiency and adhesion of multi-wires half-cell module according to wire thickness, solder thickness, and flux. The results of solar simulator and peel test was that peel strength and efficiency of soldered cell is not related. But samples with flux including high solid material showed high efficiency. The results of FE-SEM and EDX line scan on cross-section between wire and Ag electrode for different flux showed thickness of solder joint between wire and Ag electrode is increasing through solid material increasing. Flux including high solid material would affect to solder behavior on Ag electrode. Higher solid material occurred lower growth of IMC layer because solder permeate to sider of wire ribbon than Ag electrode. And it increased fill factor for high efficiency. In soldering process, amount of solid material in flux and solder thickness are the factor related with characteristic of soldered photovoltaic cell.

Considerations to design high-pressure membrane system to produce high quality potable water with lower organic matter concentration (유기물 농도가 낮은 고품질 정수 생산을 위한 고압막여과 공정 설계 시 고려사항)

  • Jeon, Jongmin;Kim, Seong-Su;Seo, Inseok;Kim, Suhan
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.6
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    • pp.473-480
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    • 2020
  • High-pressure membrane system like nanofiltration(NF) and reverse osmosis(RO) was investigated as a part of water treatment processes to produce high quality potable water with low organic matter concentration through membrane module tests and design simulation. River water and sand filtration permeate in Busan D water treatment plant were selected as feed water, and NE4040-90 and RE4040-Fen(Toray Chemical Korea) were used as NF and RO membranes, respectively. Total organic carbon(TOC) concentrations of NF and RO permeates were mostly below 0.5 mg/l and the average TOC removal rates of NF and RO membranes were 93.99% and 94.28%, respectively, which means NF used in this study is competitive with RO in terms of organic matter removal ability. Different from ions rejection tendency, the TOC removal rate increases at higher recovery rates, which is because the portion of higher molecular weight materials in the concentrated raw water with increasing recovery rate increases. Discharge of NF/RO concentrates to rivers may not be acceptable because the increased TDS concentration of the concentrates can harm the river eco-system. Thus, the idea of using NF/RO concentrate as the raw water for industrial water production was introduced. The design simulation results with feed water and membranes used in this work reveal that the raw water guideline can be satisfied if the recovery rate of NF/RO system is designed below 80%.

Application of Pulsed Electric Field Treatment for Scaling Prevention (스케일형성 방지를 위한 펄스 전기장 처리의 적용)

  • Choi, Seung-Pil;Kim, Jong-Oh
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.10
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    • pp.51-56
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    • 2011
  • This study was conducted to investigate the applicability of pulsed electric field (PEF) treatment for the prevention of scaling formation and membrane fouling reduction. To validate the effect of PEF and to identify the mechanism, some experiments with and without PEF treatment were carried out. PEF treatment affected the precipitation of $CaCO_3$ by which $CaCO_3$ particles were actively grown and sedimented. It was confirmed that the calcium ions were decreased as 78% and particle size was grown by PEF treatment. It was also verified that the crystalline structure of $CaCO_3$ was transformed by PEF treatment from Aragonite, which is formed at a high temperature and hard to be removed, to Calcite being stable at room temperature. In PEF treatment, permeate volume and permeation flux were greater than that of without PEF, case while Langelier Index(LI) decreased. From the experiment results, PEF treatment is believed to be an effective method to prevent scaling formation and to mitigate $CaCO_3$ fouling as the pretreatment of membrane filtration.

The Future of Mixed-Reality Media on the Post COVID-19 Era (포스트 코로나 시대 혼합현실 미디어의 전망)

  • Hong, Il-Yang;Lee, Young-Woo
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.25 no.2
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    • pp.240-245
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    • 2021
  • This study aims to focus on realistic content of mixed-reality media, which has emerged as a new alternative due to COVID-19, we need to to investigate relevant cases in order to present the direction and prospect of development in preparation for the post-COVID19 era. Mixed-reality is a kind of media that expands physical abilities and it is widely used as a realistic type of content for education, training, performance, creation, game, and communication with acquaintances. Mixed-reality media will naturally permeate our daily lives like TV and the Internet in the post-COVID19 era. In the future, it will become a realistic content that can feel the five senses of human, which can be used whenever and wherever necessary, and also will become an emotional media that can stimulate human's emotions and enhance happiness. it means that it's not just communication.

IoT-based Smart Switchboard Development for Power Supply of Entertainment Devices (엔터테인먼트 장치의 전원 공급을 위한 IoT 기반의 스마트 배전반 개발)

  • Kang, Yun-Jeong;Lee, Kwang-Jae;Choi, Dong-Oun
    • Journal of Korea Entertainment Industry Association
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    • v.15 no.3
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    • pp.311-321
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    • 2021
  • In this study, a smart switchboard for power supply of entertainment devices was developed for the following purposes. First, the heat generated when the high-temperature and humid air inside is cooled by the thermoelectric module is smoothly discharged to the outside of the switchboard, thereby maximizing the cooling effect. So, it is possible to prevent excessive temperature rise inside the switchboard. Various problems such as condensation inside the switchboard can be prevented by controlling the temperature of the switchboard in which a fire occurs due to excessive heat in summer, removing moisture due to the cooling effect, and generating heat instead of cooling in winter. Second, it is a smart switchboard control system that can reduce the salt that may permeate inside the switchboard. Third, the smart switchboard system is an IoT-controlled switchboard that collects environmental data using a variety of sensors and can remotely control devices through a smartphone, and can be easily used in various fields.

VALIDATION AND UTILIZATION OF THE SKINTEXTM SYSTEM

  • Gordon, V.C.;Realica, B.;Tolstrup, K.;Puls, B.
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.17 no.1
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    • pp.64-80
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    • 1991
  • The SKINTEX Method is based on a two-compartment physico-chemical model which includes a Biomembrane Barrier in compartment one and an organized macromolecular matrix in compartment two. Test samples absorb onto or permeate through the keratin/collagen Biomembrane Barrier and then can interact with the organized macromolecular matrix. Changes in the integrity of the barrier release a dye indicator: Changes in the matrix can alter its transparency. The sum of these two responses is read spectrophotometrically at 470nm. An early investigation of 950 chemicals and formulations in the SKINTEX System produced results which were 89% concordance to in vivo Draize dermal irritation results obtained with 24-hour occluded application of test samples with-out abrasion and standard scoring. Alkaline materials were analyzed in a specialized SKINTEX AMA Protocol. In this early study, the model did not distinguish nonirritant test materials and formulation with PDII(Primary Dermal Irritation Index)in the range from 0 to 1.2, A High Sensitivity Assay Protocol(HSA)was developed to amplify the changes in both compartments of this model and provide more accurate calibration of these changes. A study of 60 low irritation test samples including cosmetics, household products, chemicals and petro-chemicals distinguished nonirritants with PDII $\leq$ 0.7 for 26 of 30 nonirritants. A second protocol was developed to evaluate the SKINTEX model predictability with respect to human irritation. The Human Response Assay (HRA )has been optimized based on differences in penetration and irritation responses in humans and rabbits. An additional 32 test materials with different mechanisms and degrees of dermal toxicity were evaluated by the HRA. These in vitro results were 86% concordant to human patch test results. In order to further evaluate this model, a Standard Chemical Labelling (SCL) Protocol was developed to optimize this system to predict Draize dermal irritation results after a 4-hour application of the test material. In a study of 52 chemicals including acids, bases, solvents, salts, surfactants and preservatives, the SCL results demonstrated 85% concordance to Draize results for a 4-hour application of test samples on non-abraded rabbit skin. The SKINTEX System, including three specialized protocols, provided results which demonstrated good correlation to the endpoint of dermal irritation in man and rabbits at different application times.

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