• Title/Summary/Keyword: Permeate

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Study on the Separation of CO2 from Flue Gas Using Polysulfone Hollow Fiber Membrane (폴리설폰 중공사막을 이용한 연소 배기가스 중 이산화탄소 분리에 관한 연구)

  • Kim, Seongcheon;Chun, Jeonghyeon;Chun, Youngnam
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.2
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    • pp.147-152
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    • 2014
  • In this research, polysulfone hollow fiber membrane was used to recover $CO_2$ which is one of greenhouse gases from flue gas stream being emitted after the combustion of fossil fuels. The prerequisite requirement is to design the membrane process producing high-purity $CO_2$ from flue gas. For separation of $CO_2$, a membrane module and flue gas containing 10% carbon dioxide was used. The effects of operating conditions such as pressure, temperature, feed gas composition and multi-stage membrane on separation performance were examined at various stage cuts. Higher operating pressure and temperature increased carbon dioxide concentration and recovery ratio in permeate. Recovery ratio and separation efficiency increased if a higher content of $CO_2$ injection gas composition. Three-stage membrane system was producing a 95% $CO_2$ with 90% recovery from flue gas. The separation efficiency of three-stage membrane system was higher than one-stage system.

Ultrafiltration of Soybean Cooking Water for the Production of Soy-oligosaccharides (대두올리고당 생산을 위한 대두침출액의 한외여과)

  • Mok, Chul-Kyoon;Ku, Kyung-Hyung;Park, Dong-June;Kim, Nam-Soo;Sohn, Heon-Soo
    • Korean Journal of Food Science and Technology
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    • v.27 no.2
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    • pp.181-184
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    • 1995
  • Ultrafiltration was applied for the production of soy-oligosaccharides from bean cooking water(BCW), a by-product recovered in soymilk processing. The ultrafiltration of BCW on a membrane of 20,000 cutoff molecular weight recovered most oligosaccharides as permeate with concomitant removal of protein at 40% when volume concentration ratio(VCR) exceeded 5.0. When the VCR exceeded 5.0, membrane rejection value(MRV) for protein started to increase slowly while the MRV for sugar showed a sharp increasing trend showing 6.57% at VCR 5.0 and 19.96% at VCR 10. The optimum VCR based upon the MRV's was 5.0. Maximum recovery of soy-oligosaccharides was, however, obtained at VCR 10.0.

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Antioxidant Effect of Histidine Containing Low Molecular Weight Peptide Isolated from Skipjack Boiled Extract (가다랑어 자숙액에서 분리한 히스티딘 함유 저분자 펩타이드의 항산화 효과)

  • Cheong, Hyo-Sook
    • Korean journal of food and cookery science
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    • v.23 no.2 s.98
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    • pp.221-226
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    • 2007
  • This study was carried out to investigate the optimun conditions for the isolation of low molecular weight peptides containing histidine, and to evaluate the antioxidant effects of skipjack boiled extracts(SBE). The results are summarized as follows : L-histidine contents of the ordinary muscle and dark muscle extracts were $ 83.1{\pm}1.75{\mu}M/g\;and\;11.0{\pm}2.39\;{\mu}M/g$, respectively. The L-histidine level of the dark muscle was much lower than that of ordinary muscle in the SBE. The extracts were treated with alcalase and neutrase under different pH levels, temperatures, and times. The optimum hydrolysis conditions of SBE were pH 7.0 and a $60^{\circ}$C temperature for 2 hr in the batch reactor, which hydrolyzed 63% of the SBE. HPLC analysis showed a removing effect of the ultrafiltration permeate (UFP) to high molecular weight impurities in SBE. SBE and pure carnosine participated as inhibiting agents to, which was confirmed through the autoxidation processing of linoleic acid. UFP treatment improved the inhibiting ability of SBE to the autoxidation of linoleic acid. The reducing power of the UFP-treated ordinary muscle extracts were 10-fold higher than the dark muscle extracts, and 0.7-fold higher than 20 mM pure carnosine. The UFP-treated ordinary muscle extracts had greater reducing power activity than pure carnosine. The scavenging activities on DPPH radical of the different treated-SBE and pure carnosine were also investigated. Scavenging activities of the ordinary and dark muscle extracts and the pure carnosine were 90%, 70%, and 45%, respectively. In summary, Skipjack boiled extracts (SBE) demonstrated that low molecular weight peptides containing histidine are capable of inhibiting lipid oxidation. They also possessed effective abilities as free radical scavengers and reducing agents, and these activities may increase with increasing concentrations.

Submerged Type Water Purification System using Hollow Fiber Microfiltration Membrane (중공사 정밀여과막을 이용한 상수처리용 일체형 시스템 개발)

  • Jeong, Gyu-Yeong;Kim, Hyeong-Su;Im, Jong-Seong
    • Journal of Korea Water Resources Association
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    • v.32 no.3
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    • pp.311-319
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    • 1999
  • Membrane separation process is considered as an alternative of conventional water purification system using coagulationㆍsedimentation+sand filtration. In this study, it was examined that the application possibility of Hollowfiber Microfiltration membrane for water purification process. A $20m^3/day$ scale pilot plant was used for studying the possibility of long-term operation and the stability of water quality under the optimum conditions, 0.03m/h permeate flux, filtration for 10 minutes, pause for 2 minutes(including air-scrubbing for 30 seconds), obtained by lab-scale experiment. As a result, it was proved stability of pilot plant over one year and filtrate quality(Turbidity. SS etc). Therefore, it was proved that membrane separation process using Hollowfiber Microfiltration membrane can be applied for water purification system

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Numerical Analysis for Separation of Carbon Dioxide by Hollow Fiber Membrane with Cocurrent Flow (병류흐름의 중공사 분리막에 의한 이산화탄소 분리 수치 해석)

  • Lee Yong-Taek;Song In-Ho;Ahn Hyo-Seong;Lee Young-Jin;Jeon Hyun-Soo;Kim Jeong-Hoon;Lee Soo-Bok
    • Membrane Journal
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    • v.16 no.3
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    • pp.204-212
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    • 2006
  • A numerical analysis was carried out for separation of carbon dioxide from carbon dioxide/nitrogen gas mixture by a polyethersulfone hollow fiber membrane which has shown a good stability against plasticization by carbon dioxide and an excellent separation efficiency fur carbon dioxide from its gas mixture. A computer program for carbon dioxide separation was developed using the Compaq Visual Fortran 6.6 software. Governing module equations were thought to be an initial-value problem and the nonlinear ordinary differential equations were simultaneously solved using the Runge-Kutta-Verner fifth-order method. From results of numerical analysis, the carbon dioxide partial pressure of the feed stream, the pressure ratio of the feed side to the permeate side and the feed gas residence time at the inside of a membrane were found to be very important factors to affect the permeation characteristics of carbon dioxide.

Hybrid Water Treatment of Carbon Fiber Ultrafiltration Membrane and Polypropylene Beads Coated Photocatalyst: Effect of Organic Materials in Water Back-flushing (탄소섬유 한외여과막 및 광촉매 코팅 폴리프로필렌 구의 혼성 수처리: 물 역세척 시 유기물의 영향)

  • Park, Jin Yong;Kim, Mi Hyang
    • Membrane Journal
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    • v.22 no.6
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    • pp.415-423
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    • 2012
  • For hybrid water treatment of carbon fiber ultrafiltration and photocatalyst, we used the hybrid module that was composed of photocatalyst packing between tubular membrane outside and module inside. Photocatalyst was PP (polypropylene) bead coated with $TiO_2$ powder by CVD (chemical vapor deposition) process. Water back-flushing of 10 sec was performed per every period of 10 min to minimize membrane fouling for modified solution, which was prepared with humic acid and kaolin. Resistance of membrane fouling ($R_f$) decreased as humic acid concentration changed from 10 mg/L to 2 mg/L, and finally the highest total permeate volume ($V_T$) could be obtained at 2 mg/L, which was the same with the previous results. Then, treatment efficiencies of turbidity and humic acid were above 98.9% and 88.7%, respectively, those did not depend on the humic acid concentration. However, the treatment efficiency of humic acid increased a little as the humic acid concentration increased in the previous results.

Forward Osmosis Membrane to Treat Effluent from Anaerobic Fluidized Bed Bioreactor for Wastewater Reuse Applications (하수재이용을 위한 혐기성 유동상 생물반응기 처리수의 정삼투 여과막의 적용)

  • Kwon, Dae-eun;Kim, Jeonghwan
    • Membrane Journal
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    • v.28 no.3
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    • pp.196-204
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    • 2018
  • The anaerobic fluidized bed bioreactor (AFBR) treating synthetic wastewater to simulate domestic sewage was operated under GAC fluidization to provide high surface area for biofilm formation. Although the AFBR achieves excellent COD removal efficiency due to biological activities, concerns are still made with nutrient such as nitrogen remaining in the effluent produced by AFBR. In this study, forward osmosis membrane was applied to treat the effluent produced by AFBR to investigate removal efficiency of total nitrogen (TN) with respect to the draw solution (DS) such as NaCl and glucose. Permeability of FO membrane increased with increasing DS concentration. About 55% of TN removal efficiency was observed with the FO membrane using 1 M of NaCl of draw solution, but almost complete TN removal efficiency was achieved with 1 M of glucose of draw solution. During 24 h of filtration, there was no permeate flux decline with the FO membrane regardless of draw solution applied.

Dissolution Characteristics of Biphenyl Dimethyl Dicarboxylate from Solid Dispersions and Permeation through Rabbit Deuodenal Mucosa (고체분산체로부터 비페닐디메칠디카르복실레이트의 용출 특성 및 토끼의 십이지장 점막 투과)

  • Hyun, Jean;Chun, In-Koo
    • Journal of Pharmaceutical Investigation
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    • v.24 no.2
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    • pp.57-65
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    • 1994
  • To increase the dissolution rate of practically insoluble biphenyl dimethyl dicarboxylate (DDB), various solid dispersions were prepared with water soluble carriers, such as povidone (PVP K-30), poloxamer 407, sodium deoxycholate (SDC) and polyethylene glycol (PEG) 6000, at drug to carrier ratios of 1:3, 1:5 and 1:10 (w/w) by solvent or fusion method. Dissolution test was performed by the paddle method. The dissolution rate of DDB tablets (25 mg) on market was found to be very low (11.44, 9.02 and 6.42% at pH 1.2, 4.0 and 6.5 after 120 min, respectively). However, dissolution rates of DDB from various solid dispersions were very fast and reached supersaturation within 10 min. DDB-PEG 6000 solid dispersion appeared to be better in enhancing the in vitro dissolution rate than others. Furthermore, the incorporation of DDB and phosphatidylcholine (PC) into ${\beta}-cyclodextrin$ at ratios of 1:2:20, 1:5:20 and 1:10:20 resulted in a 4.9-, 11.2- and 19.6-fold increase in DDB dissolution after 120 min as compared with the pure drug, respectively. This might be attributed to the formation of lipid vesicles which entrapped a certain concentration of DDB during dissolution. On the other hand, the permeation of DDB through rabbit duodenal mucosa was examined using some enhancers such as SDC, sod. glycocholate (SGC) and glycyrrhizic acid ammonium salt (GAA). Only trace amounts of DDB were found to permeate through deuodenal mucosa in the absence of enhancer. SDC was found to markedly decrease the permeation flux of DDB, however, SGC and GAA (5 mM) enhanced the flux of DDB 1.6 and 2.4 times higher as compared with no additive, respectively.

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An Experimental Study on Permeability Characteristics of Blast Furnace Slag Concrete (고로슬래그 콘크리트의 투수특성에 관한 실험적 연구)

  • Paik, Shinwon;Oh, Daeyoung
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.3
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    • pp.9-12
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    • 2013
  • The pavement is generally used on the highways, local loads, roads for bicycle riding and neighborhood living facility such as parking lot, plaza, park and sports facilities. However, the pavement material that is usually used on the most of roads is impermeable asphalt-concrete and cement-concrete. If the pavement material is impermeable, many problems can be happened on the drainage facilities in the rainy season. Additionally, a lot of rainwater on the pavement surface cannot permeate to the underground and flows to the sewage ditch, stream and river, etc. If a lot of rainwater flows at once, the floods can be out along the streams and rivers. So, underground water can be exhausted. Micro organisms cannot live in the underground. Recently, many studies has been conducted to exploit the permeable concrete that has high performance permeability. However, it is required to develop the permeable concrete which has high strength and durability. In this study, permeable and strength tests were performed to investigate the permeable characteristics of porous concrete according to fine aggregate content and substitution ratio of blast furnace slag. In this test, crushed stones with 10~20 mm and sand with 5~10 mm were used as a coarse aggregate and a fine aggregate respectively. The substitution ratio of blast furnace slag to cement weight is 0 %, 15 %, and 30 %. The ratio of fine aggregate to total aggregate is 0 %, 18 %, and 35 %. As a result, permeability coefficient was decreased according to fine aggregate ratio of total aggregate. Compressive strength was also decreased according to substitution ratio of blast furnace slag.

A Study on Transport Characteristics of Hydrochloric Acid in an Anion Exchange Membrane (음이온 교환막에서 염산의 이동특성 연구)

  • 강문성;오석중;문승현
    • Membrane Journal
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    • v.8 no.3
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    • pp.148-156
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    • 1998
  • Diffusion dialysis is a membrane process driven by concentration difference using ion-exchange membranes and has been employed for many years for the acid recovery from acidic waste generated in steel, metal-refining and dectro-plating industries. Theoretically acid flux increases in propomon to the acid concentration difference. At acid concentrations higher than 3 N HCl, however, the acid flux had not increased linearly with the concentration difference. In this paper the effects of acid concentrations on diffusion dialysis for hydrochloric acid recovery and the acid transport mechanism in an anion exchange membrane were studied by membrane sorption tests and diffusion clialysis cell tests. The experimental results showed that the molecular diffusion was a major transport mechanism in a low acid concentration range and the proton leakage through an anion exchange membrane played an important role at higher acid concentrations. Also osmotic water transport and membrane dehydration retarded the transport of protons and caused the permeate flux to decrease.

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