• Title/Summary/Keyword: Permeance Method

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Analysis of Facilitated Olefin Transport Through Polymer Electrolyte Membranes Containing Silver Salts (은염을 포함하는 고분자 전해질 막을 통한 올레핀 촉진수송의 해석)

  • Yong Soo Kang;Dongkyun Ko;Jong Hak Kim;Sung Taik Chung
    • Membrane Journal
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    • v.13 no.4
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    • pp.239-245
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    • 2003
  • The origin of large difference of selectivity of $C_3H_6$ over $C_3H_8$ between pure gas and mixed gas through silver polymer electrolyte membranes is investigated. Firstly, the effect of feed condition on the permeance of mixture gas ($C_3H_6/C_3H^8$) and the separation performance is examined. Upon decrease of the $C_3\;H_6$ concentration, the $C_3H_6$ permeance decreased whereas the permeance of $C_3H_8$ increased, resulting in the decrease of the selectivity of $C_3H_6/C_3H_8/.$ This result is ascribed to the $C_3H_6$-induced plasticization of membranes. Experimental results were validated by means of mathematical modeling, where pressure independent permeabilities were used.

A Pd Doped PVDF Hollow Fibre for the Dissolved Oxygen Removal Process

  • Batbieri G.;Brunetti A.;Scura F.;Lentini F.;Agostino R G.;Kim, M.J.;Formoso V.;Drioli E.;Lee, K.H.
    • Korean Membrane Journal
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    • v.8 no.1
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    • pp.1-12
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    • 2006
  • In semiconductor industries, dissolved oxygen is one of the most undesirable contaminants of ultrapure water. A method for dissolved oxygen removal (DOR) consists in the use of polymeric hollow fibres, loaded with a catalyst and fed with a reducing agent such as hydrogen. In this work, PVDF hollow fibres loaded with Pd were characterized by means of perporometry, scanning electron microscopy (SEM), energy dispersive X-ray (EDX). The hollow fibre analyzed shows a five-layer structure with remarkable morphological differences. An estimation of pore diameters and their distribution was performed giving a mean pore diameter of 100 nm. The permeance and selectivity of the fibres were measured using $H_2,\;N_2,\;O_2$ as single gases, at different operating conditions. An $H_2$ permeance of $37 mmol/m^2s$ was measured and $H_2/O_2$ and $H_2/N_2$ selectivities of ca. 3 were obtained. $H_2$ permeance was 1/3 when a water stream flows in the shell side. Catalytic fibrebehaviour was simulated using a mathematical model for a loop membrane reactor, considering only $O_2$ and $H_2$ diffusive transport inside the membrane and their catalytic reaction. Dimensionless parameters such as the Thiele modulus are employed to describe the system behaviour. The model agrees well with the experimental reaction data.

A Study on the Permeance Through Polymer Membranes and Selectivity of $CH_4/N_2$ (폴리이미드와 폴리이써설폰 분리막을 이용한 $CH_4/N_2$의 투과선택도 특성)

  • Park, Bo-Ryoung;Kim, Dae-Hoon;Lee, Gang-Woo;Hwang, Taek-Sung;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.498-504
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    • 2011
  • In this research, hollow fiber membranes were used in order to investigate to permeation and selectivity of the $CH_4$ and $N_2$. Polyimide and polyethersulfone hollow fiber membrane were prepared by the dry-wet phase inversion method and the module was manufactured by fabricating fibers after surface coating with silicone elastomer. The scanning electron microscopy (SEM) studies showed that the produced fibers typically had an asymmetric structure. The permeance of $CH_4$ and $N_2$ were increased with pressure and temperature. However, the selectivity was decreased with increasing temperature. The permeances of $CH_4$ and $N_2$ were decreased with increasing the air gap and the effect of post-treatment on membrane showed the increase in permeance up to 3.2~7.0 times.

Switched Reluctance Motor Design and Analysis with LabView Program (LabView를 이용한 Switched Reluctance Motor 설계기술 개발)

  • Shin, Pan-Seok;Otaduy, Pedro J.
    • Proceedings of the KIEE Conference
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    • 2001.10a
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    • pp.21-23
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    • 2001
  • A design and analysis program is proposed for switched reluctance motor using an analytical method and a CAD program LabVIEW. The algorithm uses conventional permeance method, in which flux linkages, inductances and torques are calculated numerically. In order to analyze a dynamic characteristics of the motor, voltage control scheme is fallen and a single pulse operation is applied. 2 SRM models are analyzed under the given specifications and constraints. The results compared with measured data.

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Effect of Non-ionic Additive on Morphology and Gas Permeation Properties of Polysulfone Hollow Fiber Membrane (비이온계 첨가제에 의한 폴리술폰계 중공사 막의 모폴로지 조절과 기체투과 특성)

  • Lee, Hye Jin;Koh, Mi Jin;Kim, Duek Ju;Nam, Sang Yong
    • Membrane Journal
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    • v.22 no.3
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    • pp.224-233
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    • 2012
  • To improve permeation performance of gas separation membrane, polysulfone hollow fiber membrane was prepared by wet-dry phase inversion method using Triton X-100 as non-ionic additive. And variation of gas permeation behavior by additive was investigated. Various spinning conditions such as air gap, concentration of polymer, dope tank temperature were controlled and these effects were studied. The morphology and gas permeation property of hollow fiber membranes were investigated using scanning electron microscope (SEM) and bubble flow meter respectively. We confirmed that the membranes added with Triton X-100 had a smooth external skin at various air gap length conditions. The macrovoids of these hollow fiber membranes were more developed with increase of air-gap from 4 to 90 cm and that induced higher permeance. The permeance of polysulfone membranes has the higher value at comparatively lower concentration polymer (30 wt% polysulfone) and lower concentration of additive (15 wt% Triton X-100). When temperature in dope tank was controlled, the membranes prepared at $100^{\circ}C$ showed low permeance because of volatilization of additive and solvent.

Feasibility Study of Employing a Catalytic Membrane Reactor for a Pressurized CO2 and Purified H2 Production in a Water Gas Shift Reaction

  • Lim, Hankwon
    • Clean Technology
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    • v.20 no.4
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    • pp.425-432
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    • 2014
  • The effect of two important parameters of a catalytic membrane reactor (CMR), hydrogen selectivity and hydrogen permeance, coupled with an Ar sweep flow and an operating pressure on the performance of a water gas shift reaction in a CMR has been extensively studied using a one-dimensional reactor model and reaction kinetics. As an alternative pre-combustion $CO_2$ capture method, the feasibility of capturing a pressurized and concentrated $CO_2$ in a retentate (a shell side of a CMR) and separating a purified $H_2$ in a permeate (a tube side of a CMR) simultaneously in a CMR was examined and a guideline for a hydrogen permeance, a hydrogen selectivity, an Ar sweep flow rate, and an operating pressure to achieve a simultaneous capture of a concentrate $CO_2$ in a retentate and production of a purified $H_2$ in a permeate is presented. For example, with an operating pressure of 8 atm and Ar sweep gas for rate of $6.7{\times}10^{-4}mols^{-1}$, a concentrated $CO_2$ in a retentate (~90%) and a purified $H_2$ in a permeate (~100%) was simultaneously obtained in a CMR fitted with a membrane with hydrogen permeance of $1{\times}10^{-8}molm^{-2}s^{-1}Pa^{-1}$ and a hydrogen selectivity of 10000.

Preparation and Characterization of Organic Solvent Reverse Osmosis (OSRO) Membranes Using Polyketone (PK) Supports (폴리케톤(PK) 지지체를 이용한 유기용매 역삼투(OSRO) 분리막의 제조 및 특성 평가)

  • Seoungwoo Kim;Seunghee Hong;Hee Min Park;Yong Taek Lee
    • Membrane Journal
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    • v.34 no.4
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    • pp.205-215
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    • 2024
  • The purpose of this paper was to preparation of organic solvent reverse osmosis (OSRO) membrane using a polyketone (PK) support. The PK support was prepared by non-solvent induced phase separation (NIPS) method, and a polyamide layer was interfacially polymerized on the PK support to fabricate OSRO membrane in the form of thin-film composite (TFC). After that, the surface and cross-sectional morphology of the OSRO membrane were analyzed, and the surface chemical structure of the membrane was analyzed. The water permeance and salt rejection of the OSRO membrane were about 1.28 LMH/bar and 99.0% respectively. The polyamide layer of the OSRO membrane was very stable during 1 day of organic solvent immersion, and the single organic solvent permeance trend was consistent with the organic solvent nanofiltration (OSN) membrane permeance model. The MWCO of the OSRO membrane is 240 g/mol in MeOH. The permeance and separation factor of the OSRO membrane for MeOH-toluene mixture were 200% and 60% higher than those of the commercial OSN membranes respectively.

Cogging Torque and Acoustic Noise Reduction in High Torque BLDC Motors by Teeth Pairings (고정자 잇날 페어링을 이용한 고출력 토크 BLDC 전동기의 코깅 토크 및 소음 저감)

  • Lee, Sang-Min;Hwang, Sang-Mun
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.48 no.3
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    • pp.97-103
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    • 1999
  • This paper investigates reduction of acoustic noise and cogging torque in a BLDC motor with larger stator slot open width. Using energy method, cogging torque is analytically determined with airgap MMF function and airgap permeance function and confirmed by FEM analysis. It shows that the cogging torque is firstly governed by NL GNL BNL with the fundamental period of NL, where NL is the least common multiple of the number of slots and the number of poles, GNL, airgap permeance function and BNL, airgap MMF function. It also shows that there exist several tooth width which minimizes the cogging torque, for the motors that smaller slot open width or stator teeth notching is not available. And it proposes a teeth pairing with two different tooth width which can effectively eliminate the cogging torque and thus the acoustic noise. Experimental results show that the proposed teeth pairing reduces the cogging torque by 85% and the acoustic noise by 3.1dB.

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Formulation, Measurement and Analysis for the Static Thrust of LPM (LPM의 정추력 정량화 및 측정 분석)

  • Kim D.H.;Bae D.K.;Kim K.H.;Park H.S.
    • Proceedings of the KIPE Conference
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    • 2003.07a
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    • pp.304-307
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    • 2003
  • Usually, the thrust of a Linear Pulse Motor(LPM) is calculated by magnetic equivalent circuit modelling method. Analytical thrust deviation exists to calculating magnetic flux density by using Permeance Modelling Method, Finite Element Method, and Velocity Electric Motive Force method. For calculating accuracy thrust by using these every method, tire thrust is calculated and compared by Lorentz Force method, Magnetic coenergy Method, and Maxwell correspondence forte Method. And that becomes Important factor at the comparison of each capacity and parameter of motor. So this study wants to compare and analyze measurement data and calculating data of the static thrust of LPM. and then we can get more accuracy method, calculating the static thrust of LPM.

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The Static Thrust Calculation of a Hybrid Type Double-sided Linear Pulse Motor (Hybrid 형 양측식LPM의 정추력 계산)

  • 조윤현;이재봉
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.43 no.5
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    • pp.753-760
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    • 1994
  • This paper proposes a new method to compute the static thrust of a hybrid-type LPM by the coenergy method, which can be applied to a nonlinear programming of the optimization techniques for the optimal design. In the process of the computation, the magnetic nonlinearities of the permanent magnet, the primary and the secondary core are interpolated by the cubic spline method. And then, the equivalent magnetic circuit including the airgap reluctance which is a function of the displacement is modelled by the permeance method. The static thrust which is a derivative of the coenergy is computed by the Newton Raphson method at each displacement. To verify this proposed method, the results of the compjutation are compaction with those of the experiment obtained from the DLPM with 2 phase and 4 poles.