• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.68-72
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• 2013

Until a recent day, degradation of PEMFC MEA (membrane and electrode assembly) has been studied, separated with membrane degradation and electrode degradation, respectively. But membrane and electrode were degraded coincidentally at real PEMFC operation condition. During simultaneous degradation, there was interaction between membrane degradation and electrode degradation. The effect of electrode degradation on membrane degradation was studied in this work. We compared membrane degradation after electrode degradation and membrane degradation without electrode degradation. I-V performance, hydrogen crossover current, fluoride emission rate (FER), impedance and TEM were measured after and before degradation of MEA. Electrode degradation reduced active area of Pt catalyst, and then radical/$H_2O_2$ evolution rate decreased on Pt. Decrease of radical/$H_2O_2$ reduced the velocity of membrane degradation.

• Journal of Korean Society for Quality Management
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• v.34 no.3
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• pp.19-30
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• 2006

For highly reliable products, it is difficult to assess the lifetime of the products with traditional life tests. Accordingly, a recent approach is to observe the performance degradation of product during the test rather than regular failure time. This study compares performances of three methods(i.e. the approximation, analytical and numerical methods) to estimate the parameters and quantiles of the lifetime when the time-to-failure distribution follows Weibull and lognormal distributions under a random coefficient degradation rate model. Numerical experiments are also conducted to investigate the effects of model error such as measurements in a random coefficient model.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2008.04a
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• pp.593-598
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• 2008

In the present study, degradation characteristics of pumps in nuclear power plants were investigated to provide the information of degradation mechanism and stressors. The failure records of pumps for the periods 2000 to 2006 on INPO(Institute of Nuclear Power Operations) EPIX(Equipment Performance and Information Exchange System) DB were reviewed. The 1,834 failure records reveal that the critical areas of pump failures are bearing, mechanical seal, gasket/o-ring, shaft, impeller, coupling and packing. Based on the failure rate of critical areas, the important degradation mechanism and stressors were determined. Additionally, the relationship between degradation mechanism and stressors such as wear was examined. Finally, the monitoring parameters related to degradation and stressors were discussed for the future development of degradation evaluation and prognosis technology of pumps.

• Tribology and Lubricants
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• v.17 no.3
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• pp.171-178
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• 2001

In order to elucidate the lubricating mechanism of polyolester base oils [POEs], the wear characteristics of 27 kinds of polyolester base oils including mixed POEs were investigated. Their wear results were discussed in terms of the effect of molecular structure on wear performance and compared with those of mineral oil. In addition, the adsorption ability of POEs to reduced iron and their hydrolysis rates were measured and the effect of their molecular structures on the adsorptivity and hydrolysis rate of POEs was discussed, respectively. Finally, the lubricating mechanism anlyzed from these results of wear characteristics, adsorptivity and hydrolysis rate was proposed. That is to say, POEs are firstly adsorbed to friction surface and decomposed by hydrolysis or thermal degradation. Fatty acids obtained by degradation of POEs form adsorption film on friction surface. The larger become cohesive ability among fatty acid molecules in the adsorption film, the better gets the wear performance of POEs.

• Proceedings of the IEEK Conference
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• 2006.06a
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• pp.749-750
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• 2006

TFRC is an equation-based rate control scheme originally developed for video transmission over wired networks. When applied to the wireless networks, it suffers from performance degradation. In this thesis, we propose an end-to-end loss discrimination algorithm to improve the performance of TFRC over wireless networks. The proposed WLD-TFRC scheme combines Spike and WLD(Wireless Loss Discount) algorithms to discriminate wireless loss from congestion loss, and to discount feedback loss event rate. Experimental results show that WLD-TFRC outperforms the original TFRC and effectively reduce the degradation of the video quality caused by the wireless link status.

• Membrane Journal
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• v.33 no.3
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• pp.127-136
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• 2023

In this study, the electrochemical performance of a 5-layer fuel cell stack using silica composite membranes as polymer electrolyte membranes was evaluated. It was observed that the flow rate of the fuel gases plays a crucial role in stack performance, particularly being mainly dependent on the flow rate of hydrogen. Increasing the flow rate of oxygen resulted in negligible changes in performance, whereas an increase in the flow rate of hydrogen demonstrated performance improvements. However, this led to an imbalance in the ratio of hydrogen to oxygen flow rates, causing significant degradation in stack performance and durability. A decline in stack performance was also observed over time due to the degradation of stack components. This phenomenon was consistently observed in individual unit cells. Based on these findings, it was emphasized that, in addition to optimizing the performance of each component during stack operation, it is important to optimize design and operating conditions for uniform flow rate control. Lastly, the developed silica composite membrane was assessed to have sufficient performance for application in actual fuel cell systems, exhibiting a performance of over 25 W based on maximum power.

• Korean Chemical Engineering Research
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• v.51 no.3
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• pp.325-329
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• 2013

The membrane and electrode were degraded coincidentally at real PEMFC(Proton Exchange Membrane Fuel Cells) operation condition. But the interaction membrane degradation between electrode degradation has not been studied. The effect of membrane degradation on electrode degradation was studied in this work. We compared electrode degradation after membrane degradation and electrode degradation without membrane degradation. I-V performance, hydrogen crossover current, impedance and TEM were measured after and before degradation of MEA. Membrane degradation enhanced hydrogen crossover, and then Pt particle growth rate was reduced. Increase of hydrogen crossover by membrane degradation reduced the electrode degradation rate.

• Journal of Hydrogen and New Energy
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• v.14 no.4
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• pp.291-297
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• 2003

As an alternative bipolar plate material for polymer electrolyte membrane fuel cell (PEMFC), TiN-coated 316 stainless was evaluated in terms of electrical contact resistance and water contact angle. Performance and lifetime of the TiN-coated 316 bipolar plates were measured in comparison with those of graphite and bare 316 bipolar plates. At a cell voltage of 0.6 V, current density of the single cells using graphite, AISI 316, and TiN/316 bipolar plates was 996, 796, and $896mA/cm^2$, respectively. By coating 316 stainless steel with TiN layer, performance degradation rate determined to be the voltage degradation rate at a cell voltage of 0.6 V was reduced from 2.3 to 0.43 mV/h.

• Korean Chemical Engineering Research
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• v.61 no.1
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• pp.19-25
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• 2023

Although a lot of research and development has been conducted on the performance improvement of PEM (Proton Exchange Membrane) water electrolysis, the research on durability is still in early stage. This study investigated effect of temperature on the water electrolysis durability when driving temperature of the PEM water electrolysis was increased to improve performance. Voltage change, I-V, CV (Cyclic Voltammetry), LSV (Linear Sweep Voltammetry), Impedance, and FER (Fluoride Emission Rate) were measured while driving under a constant current condition in a temperature range of 50~80 ℃. As the operating temperature increased, the degradation rate increased. At 50~65 ℃, the degradation of the IrO₂ electrocatalyst mainly affected the durability of the PEM water electrolysis cell. At 80 ℃, the polymer membrane and electrode degradation proceeded similarly, and the short resistance decreased to 1.0 kΩ·cm² or less, and the performance decreased to about 1/3 of the initial stage after 144 hours of operation due to the shorting phenomenon.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.11 no.5
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• pp.2362-2378
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• 2017

To mitigate the performance degradation caused by performance anomaly, a number of channel assignment algorithms have been proposed for multi-rate wireless mesh networks. However, network conditions have not been fully considered for routing process in these algorithms. In this paper, a joint scheme called Multi-rate Dijkstra's Shortest path - Rate Separated (MDSRS) is proposed, combining routing metrics and channel assignment algorithm. In MDSRS, the routing metric are determined through the synthesized deliberations of link costs and rate matches; then the rate separated channel assignment is operated based on the determined routing metric. In this way, the competitions between high and low rate links are avoided, and performance anomaly problem is settled, and the network capacity is efficiently improved. Theoretical analysis and NS-3 simulation results indicate that, the proposed MDSRS can significantly improve the network throughput, and decrease the average end-to-end delay as well as packet loss probability. Performance improvements could be achieved even in the heavy load network conditions.